Poly[[μ4-naphthalene-1,4-dicarboxyl­ato-κ4 O:O′:O′′:O′′′-μ2-naphthalene-1,4-dicarboxyl­ato-κ4 O,O′:O′′,O′′′-bis­(2-phenyl-1H-1,3,7,8-tetra­azacyclopenta­[l]phenanthrene-κ2 N 7,N 8)dimanganese(II)] N,N-dimethyl­formamide solvate]

One of the two 1,4-dicarboxyl­ate dianions in the title compound, [Mn 2 (C 12 H 6 O 4 ) 2 (C 19 H 12 N 4 ) 2 ]·C 3 H 7 NO, uses its two carboxyl­ate groups to chelate two N -heterocycle-chelated Mn atoms; the other 1,4-dicarboxyl­ate dianion binds to four such metal centers. The octa­hedrally coordi...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2008-04, Vol.64 (Pt 5), p.m704-m705
Main Authors: Li, Heng-Da, Liu, Yang, Xu, Mao-Liang, Ng, Seik Weng
Format: Article
Language:English
Subjects:
Metal-Organic Papers
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Summary:One of the two 1,4-dicarboxyl­ate dianions in the title compound, [Mn 2 (C 12 H 6 O 4 ) 2 (C 19 H 12 N 4 ) 2 ]·C 3 H 7 NO, uses its two carboxyl­ate groups to chelate two N -heterocycle-chelated Mn atoms; the other 1,4-dicarboxyl­ate dianion binds to four such metal centers. The octa­hedrally coordinated Mn atoms are linked through the two dianions into a layer motif; the dimethyl­formamide mol­ecules occupy the spaces between adjacent layers. Ten C atoms and attached H atoms of one dianion are disordered equally over two positions.
ISSN:1600-5368
DOI:10.1107/S1600536808010787