1,3-Bis(4-tert-butyl-benz-yl)-4,5-dihydro-imidazolium chloride monohydrate

In the title compound, C(25)H(35)N(2) (+)·Cl(-)·H(2)O, the imidazolidine ring adopts a twisted conformation, with a pseudo-twofold axis passing through the N-C-N carbon and the opposite C-C bond. The N-C-N fragment of the imidazolidine ring shows some degree of both double- and single-bond character...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-01, Vol.65 (Pt 2), p.o310-o311
Main Authors: Arslan, Hakan, Vanderveer, Don, Yaşar, Sedat, Ozdemir, Ismail, Cetinkaya, Bekir
Format: Article
Language:English
Subjects:
Organic Papers
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Summary:In the title compound, C(25)H(35)N(2) (+)·Cl(-)·H(2)O, the imidazolidine ring adopts a twisted conformation, with a pseudo-twofold axis passing through the N-C-N carbon and the opposite C-C bond. The N-C-N fragment of the imidazolidine ring shows some degree of both double- and single-bond character due to partial electron delocalization. One of the tert-butyl groups is disordered over two conformations with occupancies of 0.714 (8) and 0.286 (8). In the crystal, O-H⋯Cl and C-H⋯O hydrogen bonds help to establish the packing.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536809000452