Redetermination of 1-benzyl-3-furoyl-1-phenyl-thio-urea

The title compound, C(19)H(16)N(2)O(2)S, was synthesized from furoyl isothio-cyanate and N-benzyl-aniline in dry acetone and the structure redetermined. The structure [Otazo-Sánchez et al. (2001 ▶). J. Chem. Soc. Perkin Trans. 2, pp. 2211-2218] has been re-determined in order to establish the intram...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-02, Vol.65 (Pt 3), p.o648-o648
Main Authors: Estévez-Hernández, O, Corrêa, Rodrigo S, Ellena, J, Duque, J
Format: Article
Language:English
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Organic Papers
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Summary:The title compound, C(19)H(16)N(2)O(2)S, was synthesized from furoyl isothio-cyanate and N-benzyl-aniline in dry acetone and the structure redetermined. The structure [Otazo-Sánchez et al. (2001 ▶). J. Chem. Soc. Perkin Trans. 2, pp. 2211-2218] has been re-determined in order to establish the intramolecular and intermolecular inter-actions. The thio-urea group is in the thio-amide form. The thio-urea group makes a dihedral angle of 29.2 (6)° with the furoyl group. In the crystal structure, mol-ecules are linked by inter-molecular C-H⋯O inter-actions, forming one-dimensional chains along the a axis. An intra-molecular N-H⋯O hydrogen bond is also present.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536808044085