Ethyl 1-oxo-1,2,3,4-tetra-hydro-9H-carbazole-3-carboxyl-ate

The title compound, C(15)H(15)NO(3), contains a carbazole skeleton with an ethoxy-carbonyl group at the 3 position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.95 (8)°. The cyclo-hexenone ring has an envelope conformation. In the crysta...

Full description

Saved in:
Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2009-06, Vol.65 (Pt 7), p.o1702-o1703
Main Authors: Hökelek, Tuncer, Dal, Hakan, Tercan, Barış, Göçmentürk, Mustafa, Ergün, Yavuz
Format: Article
Language:English
Subjects:
Organic Papers
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page o1703
container_issue Pt 7
container_start_page o1702
container_title Acta crystallographica. Section E, Structure reports online
container_volume 65
creator Hökelek, Tuncer
Dal, Hakan
Tercan, Barış
Göçmentürk, Mustafa
Ergün, Yavuz
description The title compound, C(15)H(15)NO(3), contains a carbazole skeleton with an ethoxy-carbonyl group at the 3 position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.95 (8)°. The cyclo-hexenone ring has an envelope conformation. In the crystal structure, pairs of strong N-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers with R(2) (2)(10) ring motifs. π-π contacts between parallel pyrrole rings [centroid-centroid distance = 3.776 (2) Å] may further stabilize the structure. A weak C-H⋯π inter-action is also observed.
doi_str_mv 10.1107/S160053680902385X
format article
fullrecord <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_2969242</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>867480474</sourcerecordid><originalsourceid>FETCH-LOGICAL-p180t-73691d846f80ad7787b10443486f6e8dce2dc407762acf693e34052c907c04043</originalsourceid><addsrcrecordid>eNpVkEtLAzEUhYMotlZ_gBtx52aiN4_JA0EopVqh4EIFdyHNZOxI2tR5SMdf71Sr1NU9nHv5zuEidErgkhCQV49EAKRMKNBAmUpf9lB_Y-GNt7-je-ioqt4AiJCUHKIeJamiOk376Hpcz9twTnBcR0wSmrCE49rXpcXzNisj1hPsbDmznzF4zL51XLcB29ofo4PchsqfbOcAPd-On0YTPH24ux8Np3hFFNRYMqFJprjIFdhMSiVnBDhnXIlceJU5TzPHQUpBrcuFZp5xSKnTIB1w4GyAbn64q2a28N39sqsXzKosFrZsTbSF-b9ZFnPzGj8M1UJTTjvAxRZQxvfGV7VZFJXzIdilj01llJBcAZebqLPdqL-M34exL_MRavs</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>867480474</pqid></control><display><type>article</type><title>Ethyl 1-oxo-1,2,3,4-tetra-hydro-9H-carbazole-3-carboxyl-ate</title><source>Open Access: PubMed Central</source><creator>Hökelek, Tuncer ; Dal, Hakan ; Tercan, Barış ; Göçmentürk, Mustafa ; Ergün, Yavuz</creator><creatorcontrib>Hökelek, Tuncer ; Dal, Hakan ; Tercan, Barış ; Göçmentürk, Mustafa ; Ergün, Yavuz</creatorcontrib><description>The title compound, C(15)H(15)NO(3), contains a carbazole skeleton with an ethoxy-carbonyl group at the 3 position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.95 (8)°. The cyclo-hexenone ring has an envelope conformation. In the crystal structure, pairs of strong N-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers with R(2) (2)(10) ring motifs. π-π contacts between parallel pyrrole rings [centroid-centroid distance = 3.776 (2) Å] may further stabilize the structure. A weak C-H⋯π inter-action is also observed.</description><identifier>ISSN: 1600-5368</identifier><identifier>EISSN: 1600-5368</identifier><identifier>DOI: 10.1107/S160053680902385X</identifier><identifier>PMID: 21582955</identifier><language>eng</language><publisher>United States: International Union of Crystallography</publisher><subject>Organic Papers</subject><ispartof>Acta crystallographica. Section E, Structure reports online, 2009-06, Vol.65 (Pt 7), p.o1702-o1703</ispartof><rights>Hökelek et al. 2009 2009</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969242/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC2969242/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27924,27925,53791,53793</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21582955$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Hökelek, Tuncer</creatorcontrib><creatorcontrib>Dal, Hakan</creatorcontrib><creatorcontrib>Tercan, Barış</creatorcontrib><creatorcontrib>Göçmentürk, Mustafa</creatorcontrib><creatorcontrib>Ergün, Yavuz</creatorcontrib><title>Ethyl 1-oxo-1,2,3,4-tetra-hydro-9H-carbazole-3-carboxyl-ate</title><title>Acta crystallographica. Section E, Structure reports online</title><addtitle>Acta Crystallogr Sect E Struct Rep Online</addtitle><description>The title compound, C(15)H(15)NO(3), contains a carbazole skeleton with an ethoxy-carbonyl group at the 3 position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.95 (8)°. The cyclo-hexenone ring has an envelope conformation. In the crystal structure, pairs of strong N-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers with R(2) (2)(10) ring motifs. π-π contacts between parallel pyrrole rings [centroid-centroid distance = 3.776 (2) Å] may further stabilize the structure. A weak C-H⋯π inter-action is also observed.</description><subject>Organic Papers</subject><issn>1600-5368</issn><issn>1600-5368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2009</creationdate><recordtype>article</recordtype><recordid>eNpVkEtLAzEUhYMotlZ_gBtx52aiN4_JA0EopVqh4EIFdyHNZOxI2tR5SMdf71Sr1NU9nHv5zuEidErgkhCQV49EAKRMKNBAmUpf9lB_Y-GNt7-je-ioqt4AiJCUHKIeJamiOk376Hpcz9twTnBcR0wSmrCE49rXpcXzNisj1hPsbDmznzF4zL51XLcB29ofo4PchsqfbOcAPd-On0YTPH24ux8Np3hFFNRYMqFJprjIFdhMSiVnBDhnXIlceJU5TzPHQUpBrcuFZp5xSKnTIB1w4GyAbn64q2a28N39sqsXzKosFrZsTbSF-b9ZFnPzGj8M1UJTTjvAxRZQxvfGV7VZFJXzIdilj01llJBcAZebqLPdqL-M34exL_MRavs</recordid><startdate>20090627</startdate><enddate>20090627</enddate><creator>Hökelek, Tuncer</creator><creator>Dal, Hakan</creator><creator>Tercan, Barış</creator><creator>Göçmentürk, Mustafa</creator><creator>Ergün, Yavuz</creator><general>International Union of Crystallography</general><scope>NPM</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20090627</creationdate><title>Ethyl 1-oxo-1,2,3,4-tetra-hydro-9H-carbazole-3-carboxyl-ate</title><author>Hökelek, Tuncer ; Dal, Hakan ; Tercan, Barış ; Göçmentürk, Mustafa ; Ergün, Yavuz</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p180t-73691d846f80ad7787b10443486f6e8dce2dc407762acf693e34052c907c04043</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2009</creationdate><topic>Organic Papers</topic><toplevel>online_resources</toplevel><creatorcontrib>Hökelek, Tuncer</creatorcontrib><creatorcontrib>Dal, Hakan</creatorcontrib><creatorcontrib>Tercan, Barış</creatorcontrib><creatorcontrib>Göçmentürk, Mustafa</creatorcontrib><creatorcontrib>Ergün, Yavuz</creatorcontrib><collection>PubMed</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Hökelek, Tuncer</au><au>Dal, Hakan</au><au>Tercan, Barış</au><au>Göçmentürk, Mustafa</au><au>Ergün, Yavuz</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Ethyl 1-oxo-1,2,3,4-tetra-hydro-9H-carbazole-3-carboxyl-ate</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><addtitle>Acta Crystallogr Sect E Struct Rep Online</addtitle><date>2009-06-27</date><risdate>2009</risdate><volume>65</volume><issue>Pt 7</issue><spage>o1702</spage><epage>o1703</epage><pages>o1702-o1703</pages><issn>1600-5368</issn><eissn>1600-5368</eissn><abstract>The title compound, C(15)H(15)NO(3), contains a carbazole skeleton with an ethoxy-carbonyl group at the 3 position. In the indole ring system, the benzene and pyrrole rings are nearly coplanar, forming a dihedral angle of 1.95 (8)°. The cyclo-hexenone ring has an envelope conformation. In the crystal structure, pairs of strong N-H⋯O hydrogen bonds link the mol-ecules into centrosymmetric dimers with R(2) (2)(10) ring motifs. π-π contacts between parallel pyrrole rings [centroid-centroid distance = 3.776 (2) Å] may further stabilize the structure. A weak C-H⋯π inter-action is also observed.</abstract><cop>United States</cop><pub>International Union of Crystallography</pub><pmid>21582955</pmid><doi>10.1107/S160053680902385X</doi><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1600-5368
ispartof Acta crystallographica. Section E, Structure reports online, 2009-06, Vol.65 (Pt 7), p.o1702-o1703
issn 1600-5368
1600-5368
language eng
recordid cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_2969242
source Open Access: PubMed Central
subjects Organic Papers
title Ethyl 1-oxo-1,2,3,4-tetra-hydro-9H-carbazole-3-carboxyl-ate
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-05T15%3A41%3A21IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Ethyl%201-oxo-1,2,3,4-tetra-hydro-9H-carbazole-3-carboxyl-ate&rft.jtitle=Acta%20crystallographica.%20Section%20E,%20Structure%20reports%20online&rft.au=H%C3%B6kelek,%20Tuncer&rft.date=2009-06-27&rft.volume=65&rft.issue=Pt%207&rft.spage=o1702&rft.epage=o1703&rft.pages=o1702-o1703&rft.issn=1600-5368&rft.eissn=1600-5368&rft_id=info:doi/10.1107/S160053680902385X&rft_dat=%3Cproquest_pubme%3E867480474%3C/proquest_pubme%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-p180t-73691d846f80ad7787b10443486f6e8dce2dc407762acf693e34052c907c04043%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=867480474&rft_id=info:pmid/21582955&rfr_iscdi=true