Probing Vibrational Anisotropy with Nuclear Resonance Vibrational Spectroscopy

In‐depth probing: A NRVS single‐crystal study (NRVS=nuclear resonance vibrational spectroscopy) has provided detailed information on the in‐plane modes of nitrosyl iron porphyrinate [Fe(oep)(NO)] (see picture; oep=octaethylporphyrin). The axial nitrosyl ligand controls the direction of the in‐plane...

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Published in:Angewandte Chemie (International ed.) 2010-06, Vol.49 (26), p.4400-4404
Main Authors: Pavlik, Jeffrey W, Barabanschikov, Alexander, Oliver, Allen G, Alp, E. Ercan, Sturhahn, Wolfgang, Zhao, Jiyong, Sage, J. Timothy, Scheidt, W. Robert
Format: Article
Language:English
Subjects:
ANISOTROPY
Coordination Complexes - chemistry
Crystallization
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
IRON COMPLEXES
iron porphyrinates
Magnetic Resonance Spectroscopy
Metalloporphyrins - chemistry
MONOCRYSTALS
Mössbauer spectroscopy
NO complexes
NRVS (nuclear resonance vibrational spectroscopy)
PORPHYRINS
RESONANCE
SPECTROSCOPY
Vibration
VIBRATIONAL STATES
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cited_by cdi_FETCH-LOGICAL-c5288-300a6d62c62c5f5639e86edc459a012d64a99fe58d5c0d3495ae0a8d0e9e25213
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container_issue 26
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container_title Angewandte Chemie (International ed.)
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creator Pavlik, Jeffrey W
Barabanschikov, Alexander
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Alp, E. Ercan
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Sage, J. Timothy
Scheidt, W. Robert
description In‐depth probing: A NRVS single‐crystal study (NRVS=nuclear resonance vibrational spectroscopy) has provided detailed information on the in‐plane modes of nitrosyl iron porphyrinate [Fe(oep)(NO)] (see picture; oep=octaethylporphyrin). The axial nitrosyl ligand controls the direction of the in‐plane iron motion.
doi_str_mv 10.1002/anie.201000928
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source Wiley-Blackwell Read & Publish Collection
subjects ANISOTROPY
Coordination Complexes - chemistry
Crystallization
INORGANIC, ORGANIC, PHYSICAL AND ANALYTICAL CHEMISTRY
IRON COMPLEXES
iron porphyrinates
Magnetic Resonance Spectroscopy
Metalloporphyrins - chemistry
MONOCRYSTALS
Mössbauer spectroscopy
NO complexes
NRVS (nuclear resonance vibrational spectroscopy)
PORPHYRINS
RESONANCE
SPECTROSCOPY
Vibration
VIBRATIONAL STATES
title Probing Vibrational Anisotropy with Nuclear Resonance Vibrational Spectroscopy
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