9-Benzyl-10-methyl-acridinium trifluoro-methane-sulfonate

In the crystal structure of the title compound, C(21)H(18)N(+)·CF(3)OS(3) (-), the cations form inversion dimers through π-π inter-actions between the acridine ring systems. These dimers are further linked by C-H⋯π inter-actions. The cations and anions are connected by C-H⋯O, C-F⋯π and S-O⋯π inter-a...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-06, Vol.66 (Pt 7), p.o1548-o1549
Main Authors: Trzybiński, Damian, Zadykowicz, Beata, Krzymiński, Karol, Sikorski, Artur, Błażejowski, Jerzy
Format: Article
Language:English
Subjects:
Organic Papers
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Summary:In the crystal structure of the title compound, C(21)H(18)N(+)·CF(3)OS(3) (-), the cations form inversion dimers through π-π inter-actions between the acridine ring systems. These dimers are further linked by C-H⋯π inter-actions. The cations and anions are connected by C-H⋯O, C-F⋯π and S-O⋯π inter-actions. The acridine and benzene ring systems are oriented at a dihedral angle of 76.8 (1)°with respect to each other. The acridine moieties are either parallel or inclined at an angle of 62.4 (1)° in the crystal structure.
ISSN:1600-5368
1600-5368
DOI:10.1107/S160053681001963X