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Dichlorido(2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenolate)cadmium(II)
In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is penta-coordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conforma...
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Published in: | Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-08, Vol.66 (Pt 9), p.m1131-m1131 |
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container_title | Acta crystallographica. Section E, Structure reports online |
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creator | Saleh Salga, Muhammad Khaledi, Hamid Mohd Ali, Hapipah |
description | In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is penta-coordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the crystal structure, adjacent mol-ecules are linked together via N-H⋯O and N-H⋯Cl hydrogen bonds, forming infinite layers parallel to the ab plane. The layers are further connected through C-H⋯Cl inter-actions into a three-dimensional network. |
doi_str_mv | 10.1107/S1600536810032563 |
format | article |
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Section E, Structure reports online</title><addtitle>Acta Crystallogr Sect E Struct Rep Online</addtitle><description>In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is penta-coordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the crystal structure, adjacent mol-ecules are linked together via N-H⋯O and N-H⋯Cl hydrogen bonds, forming infinite layers parallel to the ab plane. 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Section E, Structure reports online</jtitle><addtitle>Acta Crystallogr Sect E Struct Rep Online</addtitle><date>2010-08-18</date><risdate>2010</risdate><volume>66</volume><issue>Pt 9</issue><spage>m1131</spage><epage>m1131</epage><pages>m1131-m1131</pages><eissn>1600-5368</eissn><abstract>In the title compound, [CdCl(2)(C(13)H(19)N(3)O)], the Cd(II) ion is penta-coordinated with the N,N,O-tridentate Schiff base 2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenolate ligand and two Cl atoms in a highly distorted square-pyramidal geometry; the piperazine ring adopts a chair conformation. In the crystal structure, adjacent mol-ecules are linked together via N-H⋯O and N-H⋯Cl hydrogen bonds, forming infinite layers parallel to the ab plane. 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subjects | Metal-Organic Papers |
title | Dichlorido(2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenolate)cadmium(II) |
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