Tetra-aqua-bis-[5-(3-pyrid-yl)tetra-zolido-κN]zinc(II) tetra-hydrate

The title compound, [Zn(C(6)H(4)N(5))(2)(H(2)O)(4)]·4H(2)O, was synthesized by the hydro-thermal reaction of Zn(CH(3)COO)(2)·2H(2)O with 3-(2H-tetra-zol-5-yl)pyridine. The Zn(II) ion is located on an inversion center and is coordinated by two pyridine N atoms from two 5-(3-pyrid-yl)tetra-zolide liga...

Full description

Saved in:
Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2010-11, Vol.66 (Pt 12), p.m1667-m1667
Main Authors: Mu, Yi-Qiang, Zhao, Jun, Li, Cai
Format: Article
Language:English
Subjects:
Metal-Organic Papers
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The title compound, [Zn(C(6)H(4)N(5))(2)(H(2)O)(4)]·4H(2)O, was synthesized by the hydro-thermal reaction of Zn(CH(3)COO)(2)·2H(2)O with 3-(2H-tetra-zol-5-yl)pyridine. The Zn(II) ion is located on an inversion center and is coordinated by two pyridine N atoms from two 5-(3-pyrid-yl)tetra-zolide ligands and four coordinated water mol-ecules in a slightly distorted octa-hedral geometry. The dihedral angle between the pyridine and tetra-zole rings is 9.920 (7)°. In the crystal, mol-ecules are linked into a three-dimensional network by inter-molecular O-H⋯O and O-H⋯N hydrogen bonds involving the tetra-zole group N atoms, the aqua ligands and solvent water mol-ecules.
ISSN:1600-5368
DOI:10.1107/S1600536810048464