cis-Diaqua-bis-[dimethyl (phenyl-sulfonyl-imino)-phospho-nato]cobalt(II)

In the title diaqua-cobalt complex, [Co(C(8)H(11)NO(5)PS)(2)(H(2)O)(2)], the Co(II) atom is surrounded by six O atoms belonging to the phosphoryl and sulfonyl groups of two deprotonated chelate ligands and two additional O atoms from water mol-ecules which are in cis positions with respect to one an...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-02, Vol.67 (Pt 3), p.m369-m370
Main Authors: Trush, Elizaveta A, Trush, Victor A, Sliva, Tetyana Yu, Konovalova, Irina S, Amirkhanov, Volodymyr M
Format: Article
Language:English
Subjects:
Metal-Organic Papers
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Summary:In the title diaqua-cobalt complex, [Co(C(8)H(11)NO(5)PS)(2)(H(2)O)(2)], the Co(II) atom is surrounded by six O atoms belonging to the phosphoryl and sulfonyl groups of two deprotonated chelate ligands and two additional O atoms from water mol-ecules which are in cis positions with respect to one another. The coordination environment of cobalt can be described as a distorted octa-hedron. O-H⋯O hydrogen bonds between the water and sulfonyl O atoms of neighboring mol-ecules form chains running parallel to [010]. Two methoxy groups attached to one phosphorus are disordered over two sets of sites in a 0.6:0.4 ratio.
ISSN:1600-5368
DOI:10.1107/S1600536811006027