Dichlorido(4-meth-oxy-2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenol-ate)cadmium

In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol-ecules are linked through C-H⋯π inter-a...

Full description

Saved in:
Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-07, Vol.67 (Pt 7), p.m927-m927
Main Authors: Saleh Salga, Muhammad, Khaledi, Hamid, Mohd Ali, Hapipah
Format: Article
Language:English
Subjects:
Metal-Organic Papers
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page m927
container_issue Pt 7
container_start_page m927
container_title Acta crystallographica. Section E, Structure reports online
container_volume 67
creator Saleh Salga, Muhammad
Khaledi, Hamid
Mohd Ali, Hapipah
description In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol-ecules are linked through C-H⋯π inter-actions into infinite chains along the a axis. The mol-ecules are further connected into a three-dimensional network via N-H⋯O, N-H⋯Cl and C-H⋯Cl inter-actions. The ethyl-ene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio.
doi_str_mv 10.1107/S1600536811022100
format article
fullrecord <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3151769</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>883311345</sourcerecordid><originalsourceid>FETCH-LOGICAL-p180t-4134162ffd294a59719486c71de0ef7dd396fffa5689632ca05e035c9905368f3</originalsourceid><addsrcrecordid>eNpVUE1LxDAQDYK46-oP8OLV3UM0kzRpcxFk_YQFD-pBREJsExtJm9oPsYr_3a6uoqdh3rx5780gtANkH4DEB1cgCOFMJENHKRCyhsZLCC-xEdpsmidCQMQUNtCIQsKEBBij22OX5j7ULgvTCBemzXF47THF73cUTytXmVq_uRJH2HUFBtz72ZLT-3tXuDJ8b_T-o8pNGTzWrZmlOisG8hZat9o3ZntVJ-jm9OR6fo4Xl2cX86MFriAhLY6ARSCotRmVkeYyBhklIo0hM8TYOMuYFNZazUUiBaOpJtwQxlMpv661bIIOv3Wr7qEwWWrKttZeVbUrdN2roJ36Pyldrh7Di2LAIRZyENhbCdThuTNNqwrXpMZ7XZrQNSpJGIMhJR-Yu3-tfj1-3sk-AaH3daE</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>883311345</pqid></control><display><type>article</type><title>Dichlorido(4-meth-oxy-2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenol-ate)cadmium</title><source>PubMed Central</source><creator>Saleh Salga, Muhammad ; Khaledi, Hamid ; Mohd Ali, Hapipah</creator><creatorcontrib>Saleh Salga, Muhammad ; Khaledi, Hamid ; Mohd Ali, Hapipah</creatorcontrib><description>In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol-ecules are linked through C-H⋯π inter-actions into infinite chains along the a axis. The mol-ecules are further connected into a three-dimensional network via N-H⋯O, N-H⋯Cl and C-H⋯Cl inter-actions. The ethyl-ene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio.</description><identifier>EISSN: 1600-5368</identifier><identifier>DOI: 10.1107/S1600536811022100</identifier><identifier>PMID: 21836911</identifier><language>eng</language><publisher>United States: International Union of Crystallography</publisher><subject>Metal-Organic Papers</subject><ispartof>Acta crystallographica. Section E, Structure reports online, 2011-07, Vol.67 (Pt 7), p.m927-m927</ispartof><rights>Saleh Salga et al. 2011 2011</rights><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151769/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC3151769/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,27923,27924,53790,53792</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/21836911$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Saleh Salga, Muhammad</creatorcontrib><creatorcontrib>Khaledi, Hamid</creatorcontrib><creatorcontrib>Mohd Ali, Hapipah</creatorcontrib><title>Dichlorido(4-meth-oxy-2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenol-ate)cadmium</title><title>Acta crystallographica. Section E, Structure reports online</title><addtitle>Acta Crystallogr Sect E Struct Rep Online</addtitle><description>In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol-ecules are linked through C-H⋯π inter-actions into infinite chains along the a axis. The mol-ecules are further connected into a three-dimensional network via N-H⋯O, N-H⋯Cl and C-H⋯Cl inter-actions. The ethyl-ene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio.</description><subject>Metal-Organic Papers</subject><issn>1600-5368</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><recordid>eNpVUE1LxDAQDYK46-oP8OLV3UM0kzRpcxFk_YQFD-pBREJsExtJm9oPsYr_3a6uoqdh3rx5780gtANkH4DEB1cgCOFMJENHKRCyhsZLCC-xEdpsmidCQMQUNtCIQsKEBBij22OX5j7ULgvTCBemzXF47THF73cUTytXmVq_uRJH2HUFBtz72ZLT-3tXuDJ8b_T-o8pNGTzWrZmlOisG8hZat9o3ZntVJ-jm9OR6fo4Xl2cX86MFriAhLY6ARSCotRmVkeYyBhklIo0hM8TYOMuYFNZazUUiBaOpJtwQxlMpv661bIIOv3Wr7qEwWWrKttZeVbUrdN2roJ36Pyldrh7Di2LAIRZyENhbCdThuTNNqwrXpMZ7XZrQNSpJGIMhJR-Yu3-tfj1-3sk-AaH3daE</recordid><startdate>201107</startdate><enddate>201107</enddate><creator>Saleh Salga, Muhammad</creator><creator>Khaledi, Hamid</creator><creator>Mohd Ali, Hapipah</creator><general>International Union of Crystallography</general><scope>NPM</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>201107</creationdate><title>Dichlorido(4-meth-oxy-2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenol-ate)cadmium</title><author>Saleh Salga, Muhammad ; Khaledi, Hamid ; Mohd Ali, Hapipah</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p180t-4134162ffd294a59719486c71de0ef7dd396fffa5689632ca05e035c9905368f3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Metal-Organic Papers</topic><toplevel>online_resources</toplevel><creatorcontrib>Saleh Salga, Muhammad</creatorcontrib><creatorcontrib>Khaledi, Hamid</creatorcontrib><creatorcontrib>Mohd Ali, Hapipah</creatorcontrib><collection>PubMed</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Saleh Salga, Muhammad</au><au>Khaledi, Hamid</au><au>Mohd Ali, Hapipah</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Dichlorido(4-meth-oxy-2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenol-ate)cadmium</atitle><jtitle>Acta crystallographica. Section E, Structure reports online</jtitle><addtitle>Acta Crystallogr Sect E Struct Rep Online</addtitle><date>2011-07</date><risdate>2011</risdate><volume>67</volume><issue>Pt 7</issue><spage>m927</spage><epage>m927</epage><pages>m927-m927</pages><eissn>1600-5368</eissn><abstract>In the title compound, [CdCl(2)(C(14)H(21)N(3)O(2))], the Schiff base ligand chelates the Cd(II) ion in an N,N,O-tridentate fashion. Two Cl atoms complete a distorted square-pyramidal coordination environment around the metal atom. In the crystal, adjacent mol-ecules are linked through C-H⋯π inter-actions into infinite chains along the a axis. The mol-ecules are further connected into a three-dimensional network via N-H⋯O, N-H⋯Cl and C-H⋯Cl inter-actions. The ethyl-ene group is disordered over two sets of sites in a 0.520 (10):0.480 (10) ratio.</abstract><cop>United States</cop><pub>International Union of Crystallography</pub><pmid>21836911</pmid><doi>10.1107/S1600536811022100</doi><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier EISSN: 1600-5368
ispartof Acta crystallographica. Section E, Structure reports online, 2011-07, Vol.67 (Pt 7), p.m927-m927
issn 1600-5368
language eng
recordid cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3151769
source PubMed Central
subjects Metal-Organic Papers
title Dichlorido(4-meth-oxy-2-{[2-(piperazin-4-ium-1-yl)eth-yl]imino-meth-yl}phenol-ate)cadmium
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-11T15%3A43%3A42IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Dichlorido(4-meth-oxy-2-%7B%5B2-(piperazin-4-ium-1-yl)eth-yl%5Dimino-meth-yl%7Dphenol-ate)cadmium&rft.jtitle=Acta%20crystallographica.%20Section%20E,%20Structure%20reports%20online&rft.au=Saleh%20Salga,%20Muhammad&rft.date=2011-07&rft.volume=67&rft.issue=Pt%207&rft.spage=m927&rft.epage=m927&rft.pages=m927-m927&rft.eissn=1600-5368&rft_id=info:doi/10.1107/S1600536811022100&rft_dat=%3Cproquest_pubme%3E883311345%3C/proquest_pubme%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-p180t-4134162ffd294a59719486c71de0ef7dd396fffa5689632ca05e035c9905368f3%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=883311345&rft_id=info:pmid/21836911&rfr_iscdi=true