2,4,5-Tris(biphenyl-2-yl)-1-bromo-benzene

In the title compound, C(42)H(29)Br, the dihedral angles between the central benzene ring and the three attached benzene rings are very similar, lying in the range 52.65 (6)-57.20 (7)°. Of the dihedral angles between the rings of the o-biphenyl substituents, two are similar [46.34 (7) and 47.35 (7)°...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2011-08, Vol.67 (Pt 8), p.o2090-o2091
Main Authors: Rodrigues, Ana S M C, Gomes, Ligia R, Santos, Luís M N B F, Low, John Nicolson
Format: Article
Language:English
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Organic Papers
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Summary:In the title compound, C(42)H(29)Br, the dihedral angles between the central benzene ring and the three attached benzene rings are very similar, lying in the range 52.65 (6)-57.20 (7)°. Of the dihedral angles between the rings of the o-biphenyl substituents, two are similar [46.34 (7) and 47.35 (7)°], while the other differs significantly [64.17 (7)°]. In the crystal, mol-ecules are linked into centrosymmetric dimers by two weak C-H⋯π inter-actions.
ISSN:1600-5368
DOI:10.1107/S1600536811028455