Monomer-on-Monomer (MoM) Mitsunobu Reaction: Facile Purification Utilizing Surface-Initiated Sequestration

A monomer-on-monomer (MoM) Mitsunobu reaction utilizing norbornenyl-tagged (Nb-tagged) reagents is reported, whereby purification was rapidly achieved by employing ring-opening metathesis polymerization, which was initiated by any of three methods utilizing Grubbs catalyst: (i) free catalyst in solu...

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Published in:Organic letters 2011-01, Vol.13 (1), p.8-10
Main Authors: Maity, Pradip K, Rolfe, Alan, Samarakoon, Thiwanka B, Faisal, Saqib, Kurtz, Ryan D, Long, Toby R, Schätz, Alexander, Flynn, Daniel L, Grass, Robert N, Stark, Wendelin J, Reiser, Oliver, Hanson, Paul R
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Language:English
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Magnetics
Metal Nanoparticles - chemistry
Polymers - chemical synthesis
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cited_by cdi_FETCH-LOGICAL-a470t-5fa702d9626b3a96b9b579d6c6eef48738614508132194a910b8183ee0aef18d3
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container_title Organic letters
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creator Maity, Pradip K
Rolfe, Alan
Samarakoon, Thiwanka B
Faisal, Saqib
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Long, Toby R
Schätz, Alexander
Flynn, Daniel L
Grass, Robert N
Stark, Wendelin J
Reiser, Oliver
Hanson, Paul R
description A monomer-on-monomer (MoM) Mitsunobu reaction utilizing norbornenyl-tagged (Nb-tagged) reagents is reported, whereby purification was rapidly achieved by employing ring-opening metathesis polymerization, which was initiated by any of three methods utilizing Grubbs catalyst: (i) free catalyst in solution, (ii) surface-initiated catalyst-armed silica, or (iii) surface-initiated catalyst-armed Co/C magnetic nanoparticles.
doi_str_mv 10.1021/ol1022382
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source American Chemical Society:Jisc Collections:American Chemical Society Read & Publish Agreement 2022-2024 (Reading list)
subjects Magnetics
Metal Nanoparticles - chemistry
Polymers - chemical synthesis
title Monomer-on-Monomer (MoM) Mitsunobu Reaction: Facile Purification Utilizing Surface-Initiated Sequestration
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