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Disorder in the anionic part of catena-poly[[(pyrazine-2-carboxyl-ato)copper(II)]-μ-pyrazine-2-carboxyl-ato]

The title compound, [Cu(C(5)H(3)N(2)O(2))(0.88)(C(6)H(4)NO(2))(1.12)](n), is characterized by disorder of the anion, resulting from a statistical occupation in a 0.44 (3):0.56 (3) ratio of pyrazine-2-carboxylate and pyridine-2-carboxylate. The compound was isolated during attempts to synthesize a mi...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-04, Vol.68 (Pt 4), p.m498-m499
Main Authors: Albanez, Joselyn, Brito, Iván, Cárdenas, Alejandro, López-Rodríguez, Matías
Format: Article
Language:English
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Summary:The title compound, [Cu(C(5)H(3)N(2)O(2))(0.88)(C(6)H(4)NO(2))(1.12)](n), is characterized by disorder of the anion, resulting from a statistical occupation in a 0.44 (3):0.56 (3) ratio of pyrazine-2-carboxylate and pyridine-2-carboxylate. The compound was isolated during attempts to synthesize a mixed-ligand coordination polymer by solvothermal reaction between copper(II) nitrate and equimolar mixtures of pyrazine-2-carboxylic acid and pyridine-2-carb-oxy-lic acid in a mixture of water and EtOH. The difference in the two components of the compound is due to substitutional disorder of a CH group for one of the N atoms of the pyrazine ring which share the same site in the structure. In the crystal structure, the Cu(II) atom lies on an inversion centre and is six-coordinated in a distorted N(2)O(4) geometry. The carboxyl-ate group carbonyl O atoms are weakly coordinated to an equivalent Cu(II) atom that is translated one unit cell in the a-axis direction, thus forming a polymeric chain through carboxyl-ate bridges.
ISSN:1600-5368
DOI:10.1107/S1600536812012378