Interstitial Oxide Ion Order and Conductivity in La₁.₆₄Ca₀.₃₆Ga₃O₇.₃₂ Melilite

The spatial ordering of interstitial oxide charge carriers in La1.64Ca0.36Ga3O7.32 melilite reduces the ion conductivity. The complex ordering pattern is produced by the accommodation of local structural relaxation around the interstitial oxides, which extends beyond the simple formation of GaO5 tri...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie (International ed.) 2010-03, Vol.49 (13), p.2362-2366
Main Authors: Li, Man-Rong, Kuang, Xiaojun, Chong, Samantha Y, Xu, Zhongling, Thomas, Christopher I, Niu, Hongjun, Claridge, John B, Rosseinsky, Matthew J
Format: Article
Language:English
Subjects:
Communications
defect structures
ion conductivity
oxido ligands
solid-state structures
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page 2366
container_issue 13
container_start_page 2362
container_title Angewandte Chemie (International ed.)
container_volume 49
creator Li, Man-Rong
Kuang, Xiaojun
Chong, Samantha Y
Xu, Zhongling
Thomas, Christopher I
Niu, Hongjun
Claridge, John B
Rosseinsky, Matthew J
description The spatial ordering of interstitial oxide charge carriers in La1.64Ca0.36Ga3O7.32 melilite reduces the ion conductivity. The complex ordering pattern is produced by the accommodation of local structural relaxation around the interstitial oxides, which extends beyond the simple formation of GaO5 trigonal bipyramids from GaO4 tetrahedra (see picture; brown, orange, and teal are Ga, all others O) in disordered structures at low interstitial concentrations.
doi_str_mv 10.1002/anie.200906220
format article
fullrecord <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3430004</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>733438840</sourcerecordid><originalsourceid>FETCH-LOGICAL-f3690-dc64f958f6a62d751155bdaf6c999d5bcabd2c124bd7629af4d46acc7ddd04753</originalsourceid><addsrcrecordid>eNpVkUtv1DAUhS0Eog_YsoTsWGW4fsSPDVI7aoeRho6q0sLOcmKnGDJJiTOls4MUwf-cX4KrlKisfI7ud8-98kXoBYYJBiBvTO3dhAAo4ITAI7SLM4JTKgR9HDWjNBUywztoL4QvkZcS-FO0QwArzBnsonxed64Nne-8qZLljbcumTd1smytaxNT22Ta1HZddP7ad5vE18nCbPufk23_e9v_mkb9I-rbaGdR3y63_Z_B98l7V_nKd-4ZelKaKrjn9-8-Oj8--jB9ly6Ws_n0YJGWlCtIbcFZqTJZcsOJFRnGWZZbU_JCKWWzvDC5JQUmLLeCE2VKZhk3RSGstcBERvfR2yH3ap2vnC1c3bWm0letX5l2oxvj9f-V2n_Wl821powCAIsBr-8D2ubb2oVOr3woXFWZ2jXroAWNpJQMIvny4ahxxr9_jYAagO--cpuxjkHfXU3fXU2PV9MHJ_Oj0cXedOj1oXM3Y69pv2ouqMj0x5OZvoDTi0P86VQfRv7VwJem0eay9UGfn8VNKGBJqJCS_gW6jq0J</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>733438840</pqid></control><display><type>article</type><title>Interstitial Oxide Ion Order and Conductivity in La₁.₆₄Ca₀.₃₆Ga₃O₇.₃₂ Melilite</title><source>Wiley-Blackwell Read &amp; Publish Collection</source><creator>Li, Man-Rong ; Kuang, Xiaojun ; Chong, Samantha Y ; Xu, Zhongling ; Thomas, Christopher I ; Niu, Hongjun ; Claridge, John B ; Rosseinsky, Matthew J</creator><creatorcontrib>Li, Man-Rong ; Kuang, Xiaojun ; Chong, Samantha Y ; Xu, Zhongling ; Thomas, Christopher I ; Niu, Hongjun ; Claridge, John B ; Rosseinsky, Matthew J</creatorcontrib><description>The spatial ordering of interstitial oxide charge carriers in La1.64Ca0.36Ga3O7.32 melilite reduces the ion conductivity. The complex ordering pattern is produced by the accommodation of local structural relaxation around the interstitial oxides, which extends beyond the simple formation of GaO5 trigonal bipyramids from GaO4 tetrahedra (see picture; brown, orange, and teal are Ga, all others O) in disordered structures at low interstitial concentrations.</description><identifier>ISSN: 1433-7851</identifier><identifier>EISSN: 1521-3773</identifier><identifier>DOI: 10.1002/anie.200906220</identifier><identifier>PMID: 20191640</identifier><language>eng</language><publisher>Weinheim: Wiley-VCH Verlag</publisher><subject>Communications ; defect structures ; ion conductivity ; oxido ligands ; solid-state structures</subject><ispartof>Angewandte Chemie (International ed.), 2010-03, Vol.49 (13), p.2362-2366</ispartof><rights>Copyright © 2010 WILEY‐VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><rights>Copyright © 2010 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim 2010</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>230,314,780,784,885,27924,27925</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/20191640$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Li, Man-Rong</creatorcontrib><creatorcontrib>Kuang, Xiaojun</creatorcontrib><creatorcontrib>Chong, Samantha Y</creatorcontrib><creatorcontrib>Xu, Zhongling</creatorcontrib><creatorcontrib>Thomas, Christopher I</creatorcontrib><creatorcontrib>Niu, Hongjun</creatorcontrib><creatorcontrib>Claridge, John B</creatorcontrib><creatorcontrib>Rosseinsky, Matthew J</creatorcontrib><title>Interstitial Oxide Ion Order and Conductivity in La₁.₆₄Ca₀.₃₆Ga₃O₇.₃₂ Melilite</title><title>Angewandte Chemie (International ed.)</title><addtitle>Angew. Chem. Int. Ed</addtitle><description>The spatial ordering of interstitial oxide charge carriers in La1.64Ca0.36Ga3O7.32 melilite reduces the ion conductivity. The complex ordering pattern is produced by the accommodation of local structural relaxation around the interstitial oxides, which extends beyond the simple formation of GaO5 trigonal bipyramids from GaO4 tetrahedra (see picture; brown, orange, and teal are Ga, all others O) in disordered structures at low interstitial concentrations.</description><subject>Communications</subject><subject>defect structures</subject><subject>ion conductivity</subject><subject>oxido ligands</subject><subject>solid-state structures</subject><issn>1433-7851</issn><issn>1521-3773</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2010</creationdate><recordtype>article</recordtype><sourceid>24P</sourceid><recordid>eNpVkUtv1DAUhS0Eog_YsoTsWGW4fsSPDVI7aoeRho6q0sLOcmKnGDJJiTOls4MUwf-cX4KrlKisfI7ud8-98kXoBYYJBiBvTO3dhAAo4ITAI7SLM4JTKgR9HDWjNBUywztoL4QvkZcS-FO0QwArzBnsonxed64Nne-8qZLljbcumTd1smytaxNT22Ta1HZddP7ad5vE18nCbPufk23_e9v_mkb9I-rbaGdR3y63_Z_B98l7V_nKd-4ZelKaKrjn9-8-Oj8--jB9ly6Ws_n0YJGWlCtIbcFZqTJZcsOJFRnGWZZbU_JCKWWzvDC5JQUmLLeCE2VKZhk3RSGstcBERvfR2yH3ap2vnC1c3bWm0letX5l2oxvj9f-V2n_Wl821powCAIsBr-8D2ubb2oVOr3woXFWZ2jXroAWNpJQMIvny4ahxxr9_jYAagO--cpuxjkHfXU3fXU2PV9MHJ_Oj0cXedOj1oXM3Y69pv2ouqMj0x5OZvoDTi0P86VQfRv7VwJem0eay9UGfn8VNKGBJqJCS_gW6jq0J</recordid><startdate>20100322</startdate><enddate>20100322</enddate><creator>Li, Man-Rong</creator><creator>Kuang, Xiaojun</creator><creator>Chong, Samantha Y</creator><creator>Xu, Zhongling</creator><creator>Thomas, Christopher I</creator><creator>Niu, Hongjun</creator><creator>Claridge, John B</creator><creator>Rosseinsky, Matthew J</creator><general>Wiley-VCH Verlag</general><general>WILEY-VCH Verlag</general><general>WILEY‐VCH Verlag</general><scope>FBQ</scope><scope>BSCLL</scope><scope>24P</scope><scope>WIN</scope><scope>NPM</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20100322</creationdate><title>Interstitial Oxide Ion Order and Conductivity in La₁.₆₄Ca₀.₃₆Ga₃O₇.₃₂ Melilite</title><author>Li, Man-Rong ; Kuang, Xiaojun ; Chong, Samantha Y ; Xu, Zhongling ; Thomas, Christopher I ; Niu, Hongjun ; Claridge, John B ; Rosseinsky, Matthew J</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-f3690-dc64f958f6a62d751155bdaf6c999d5bcabd2c124bd7629af4d46acc7ddd04753</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2010</creationdate><topic>Communications</topic><topic>defect structures</topic><topic>ion conductivity</topic><topic>oxido ligands</topic><topic>solid-state structures</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Man-Rong</creatorcontrib><creatorcontrib>Kuang, Xiaojun</creatorcontrib><creatorcontrib>Chong, Samantha Y</creatorcontrib><creatorcontrib>Xu, Zhongling</creatorcontrib><creatorcontrib>Thomas, Christopher I</creatorcontrib><creatorcontrib>Niu, Hongjun</creatorcontrib><creatorcontrib>Claridge, John B</creatorcontrib><creatorcontrib>Rosseinsky, Matthew J</creatorcontrib><collection>AGRIS</collection><collection>Istex</collection><collection>Wiley Online Library Open Access</collection><collection>Wiley-Blackwell Free Backfiles(OpenAccess)</collection><collection>PubMed</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Angewandte Chemie (International ed.)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Man-Rong</au><au>Kuang, Xiaojun</au><au>Chong, Samantha Y</au><au>Xu, Zhongling</au><au>Thomas, Christopher I</au><au>Niu, Hongjun</au><au>Claridge, John B</au><au>Rosseinsky, Matthew J</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Interstitial Oxide Ion Order and Conductivity in La₁.₆₄Ca₀.₃₆Ga₃O₇.₃₂ Melilite</atitle><jtitle>Angewandte Chemie (International ed.)</jtitle><addtitle>Angew. Chem. Int. Ed</addtitle><date>2010-03-22</date><risdate>2010</risdate><volume>49</volume><issue>13</issue><spage>2362</spage><epage>2366</epage><pages>2362-2366</pages><issn>1433-7851</issn><eissn>1521-3773</eissn><abstract>The spatial ordering of interstitial oxide charge carriers in La1.64Ca0.36Ga3O7.32 melilite reduces the ion conductivity. The complex ordering pattern is produced by the accommodation of local structural relaxation around the interstitial oxides, which extends beyond the simple formation of GaO5 trigonal bipyramids from GaO4 tetrahedra (see picture; brown, orange, and teal are Ga, all others O) in disordered structures at low interstitial concentrations.</abstract><cop>Weinheim</cop><pub>Wiley-VCH Verlag</pub><pmid>20191640</pmid><doi>10.1002/anie.200906220</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1433-7851
ispartof Angewandte Chemie (International ed.), 2010-03, Vol.49 (13), p.2362-2366
issn 1433-7851
1521-3773
language eng
recordid cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_3430004
source Wiley-Blackwell Read & Publish Collection
subjects Communications
defect structures
ion conductivity
oxido ligands
solid-state structures
title Interstitial Oxide Ion Order and Conductivity in La₁.₆₄Ca₀.₃₆Ga₃O₇.₃₂ Melilite
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-01T05%3A10%3A17IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Interstitial%20Oxide%20Ion%20Order%20and%20Conductivity%20in%20La%E2%82%81.%E2%82%86%E2%82%84Ca%E2%82%80.%E2%82%83%E2%82%86Ga%E2%82%83O%E2%82%87.%E2%82%83%E2%82%82%20Melilite&rft.jtitle=Angewandte%20Chemie%20(International%20ed.)&rft.au=Li,%20Man-Rong&rft.date=2010-03-22&rft.volume=49&rft.issue=13&rft.spage=2362&rft.epage=2366&rft.pages=2362-2366&rft.issn=1433-7851&rft.eissn=1521-3773&rft_id=info:doi/10.1002/anie.200906220&rft_dat=%3Cproquest_pubme%3E733438840%3C/proquest_pubme%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-f3690-dc64f958f6a62d751155bdaf6c999d5bcabd2c124bd7629af4d46acc7ddd04753%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=733438840&rft_id=info:pmid/20191640&rfr_iscdi=true