Strong Electronic and Counterion Effects on Geminal Digold Formation and Reactivity as Revealed by Gold(I)-Aryl Model Complexes

Geminal diauration of [Ph3PAu(aryl)] complexes has been investigated to model the intermediacy of geminally diaurated gold(I)–vinyl complexes in catalysis (see scheme). The results advance our understanding of the factors influencing the stability, reactivity, and dynamics of these organometallic in...

Full description

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2012-03, Vol.51 (10), p.2452-2456
Main Authors: Weber, Dieter, Jones, T. David, Adduci, Laura L., Gagné, Michel R.
Format: Article
Language:English
Subjects:
aurophilicity
Catalysis
Dynamics
Electronics
Electrons
Formations
geminal diauration
Gold - chemistry
gold complexes
Ions
Mathematical models
Metalorganic compounds
Molecular Structure
Organometallic Compounds - chemistry
protodemetalation
Stability
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Geminal diauration of [Ph3PAu(aryl)] complexes has been investigated to model the intermediacy of geminally diaurated gold(I)–vinyl complexes in catalysis (see scheme). The results advance our understanding of the factors influencing the stability, reactivity, and dynamics of these organometallic intermediates.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201107659