(1-{(E)-[Phen-yl(pyridin-2-yl-κN)methyl-idene]amino-κN}pyrrolidin-2-one-κO)bis-(thio-cyanato-κN)copper(II)

The Cu(II) atom in the title compound, [Cu(NCS)(2)(C(16)H(15)N(3)O)], is bonded to the N atoms of two thio-cyanate ions, and is N,N'-chelated by the Schiff base ligand. The four N atoms surround the metal atom to form a distorted square; the square environment is distorted towards a square pyra...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2012-10, Vol.68 (Pt 10), p.m1302-m1302
Main Authors: Kunnath, Roji J, Prathapachandra Kurup, M R, Ng, Seik Weng
Format: Article
Language:English
Subjects:
Metal-Organic Papers
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Summary:The Cu(II) atom in the title compound, [Cu(NCS)(2)(C(16)H(15)N(3)O)], is bonded to the N atoms of two thio-cyanate ions, and is N,N'-chelated by the Schiff base ligand. The four N atoms surround the metal atom to form a distorted square; the square environment is distorted towards a square pyramid by a long Cu⋯O inter-action. In the crystal, two C atoms of the pyrrolidin-2-one ring are disordered over two positions in a 1:1 ratio.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536812039918