Bis[(E)-3-(4-meth-oxy-phen-yl)prop-2-enoato]triphenyl-anti-mony(V) benzene monosolvate

The asymmetric unit of the title compound, [Sb(C6H5)3(C10H9O3)2]·C6H6, contains one organometallic mol-ecule and one benzene mol-ecule that is disordered over two sets of sites with an occupancy ratio of 0.556 (15):0.444 (15). The Sb(V) atom is in a distorted trigonal-bipyramidal environment with th...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013-03, Vol.69 (Pt 3), p.m167-m167
Main Authors: Andreev, Pavel V, Somov, Nikolay V, Kalistratova, Olga S, Gushchin, Alexey V, Chuprunov, Evgeny V
Format: Article
Language:English
Subjects:
Metal-Organic Papers
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Summary:The asymmetric unit of the title compound, [Sb(C6H5)3(C10H9O3)2]·C6H6, contains one organometallic mol-ecule and one benzene mol-ecule that is disordered over two sets of sites with an occupancy ratio of 0.556 (15):0.444 (15). The Sb(V) atom is in a distorted trigonal-bipyramidal environment with the carboxyl-ate O atoms in axial positions and phenyl C atoms in the equatorial plane. As a result of additional Sb⋯O inter-actions, one of the C-Sb-C angles is widened to 140.19 (6)°.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813004674