Enhancing glass-forming ability via frustration of nano-clustering in alloys with a high solvent content

The glass-forming ability (GFA) of alloys with a high-solvent content such as soft magnetic Fe-based and Al-based alloys is usually limited due to strong formation of the solvent-based solid solution phase. Herein, we report that the GFA of soft magnetic Fe-based alloys (with >70 at.% Fe to ensur...

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Published in:Scientific reports 2013-06, Vol.3 (1), p.1983-1983, Article 1983
Main Authors: Li, H. X., Gao, J. E., Wu, Y., Jiao, Z. B., Ma, D., Stoica, A. D., Wang, X. L., Ren, Y., Miller, M. K., Lu, Z. P.
Format: Article
Language:English
Subjects:
639/301/1023/1026
639/301/119/997
639/301/923/218
639/766/25
Aluminum alloys
APPLIED PHYSICS
CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS
Crystallization
Enthalpy
GLASSES
Humanities and Social Sciences
Iron alloys
MAGNETIC PROPERTIES AND MATERIALS
MATERIALS SCIENCE
METALS AND ALLOYS
multidisciplinary
Nucleation
Science
Science & Technology - Other Topics
VOCs
Volatile organic compounds
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cited_by cdi_FETCH-LOGICAL-c465t-7c45a3a57a612b314dc4537547aa97b4febdd66f9ce385830e98198f2bf07c8e3
cites cdi_FETCH-LOGICAL-c465t-7c45a3a57a612b314dc4537547aa97b4febdd66f9ce385830e98198f2bf07c8e3
container_end_page 1983
container_issue 1
container_start_page 1983
container_title Scientific reports
container_volume 3
creator Li, H. X.
Gao, J. E.
Wu, Y.
Jiao, Z. B.
Ma, D.
Stoica, A. D.
Wang, X. L.
Ren, Y.
Miller, M. K.
Lu, Z. P.
description The glass-forming ability (GFA) of alloys with a high-solvent content such as soft magnetic Fe-based and Al-based alloys is usually limited due to strong formation of the solvent-based solid solution phase. Herein, we report that the GFA of soft magnetic Fe-based alloys (with >70 at.% Fe to ensure large saturation magnetization) could be dramatically improved by doping with only 0.3 at.% Cu which has a positive enthalpy of mixing with Fe. It was found that an appropriate Cu addition could enhance the liquid phase stability and crystallization resistance by destabilizing the α-Fe nano-clusters due to the necessity to redistribute the Cu atoms. However, excessive Cu doping would stimulate nucleation of the α-Fe nano-clusters due to the repulsive nature between the Fe and Cu atoms, thus deteriorating the GFA. Our findings provide new insights into understanding of glass formation in general.
doi_str_mv 10.1038/srep01983
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X. ; Gao, J. E. ; Wu, Y. ; Jiao, Z. B. ; Ma, D. ; Stoica, A. D. ; Wang, X. L. ; Ren, Y. ; Miller, M. K. ; Lu, Z. P.</creator><creatorcontrib>Li, H. X. ; Gao, J. E. ; Wu, Y. ; Jiao, Z. B. ; Ma, D. ; Stoica, A. D. ; Wang, X. L. ; Ren, Y. ; Miller, M. K. ; Lu, Z. P. ; Oak Ridge National Laboratory (ORNL), Oak Ridge, TN (United States)</creatorcontrib><description>The glass-forming ability (GFA) of alloys with a high-solvent content such as soft magnetic Fe-based and Al-based alloys is usually limited due to strong formation of the solvent-based solid solution phase. Herein, we report that the GFA of soft magnetic Fe-based alloys (with &gt;70 at.% Fe to ensure large saturation magnetization) could be dramatically improved by doping with only 0.3 at.% Cu which has a positive enthalpy of mixing with Fe. It was found that an appropriate Cu addition could enhance the liquid phase stability and crystallization resistance by destabilizing the α-Fe nano-clusters due to the necessity to redistribute the Cu atoms. However, excessive Cu doping would stimulate nucleation of the α-Fe nano-clusters due to the repulsive nature between the Fe and Cu atoms, thus deteriorating the GFA. 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subjects 639/301/1023/1026
639/301/119/997
639/301/923/218
639/766/25
Aluminum alloys
APPLIED PHYSICS
CLASSICAL AND QUANTUM MECHANICS, GENERAL PHYSICS
Crystallization
Enthalpy
GLASSES
Humanities and Social Sciences
Iron alloys
MAGNETIC PROPERTIES AND MATERIALS
MATERIALS SCIENCE
METALS AND ALLOYS
multidisciplinary
Nucleation
Science
Science & Technology - Other Topics
VOCs
Volatile organic compounds
title Enhancing glass-forming ability via frustration of nano-clustering in alloys with a high solvent content
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