Potassium N-bromo-4-chloro-2-methyl-benzene-sulfonamidate monohydrate

In the title compound, K(+)·C7H6BrClNO2S(-)·H2O, the K(+) cation is hepta-coordinated by two water O atoms, four sulfonyl O atoms of four different N-bromo-4-chloro-2-methyl-benzene-sulfonamidate anions, and one Br atom of one of the anions. The S-N distance of 1.584 (3) Å is consistent with an S=N...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Structure reports online Structure reports online, 2013, Vol.69 (Pt 7), p.m370-m370
Main Authors: Spandana, H S, Foro, Sabine, Gowda, B Thimme
Format: Article
Language:English
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Metal-Organic Papers
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Summary:In the title compound, K(+)·C7H6BrClNO2S(-)·H2O, the K(+) cation is hepta-coordinated by two water O atoms, four sulfonyl O atoms of four different N-bromo-4-chloro-2-methyl-benzene-sulfonamidate anions, and one Br atom of one of the anions. The S-N distance of 1.584 (3) Å is consistent with an S=N double bond. In the crystal, the anions are linked into layers by O-H⋯Br and O-H⋯N hydrogen bonds.
ISSN:1600-5368
1600-5368
DOI:10.1107/S1600536813014979