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Porous coordination polymers with ubiquitous and biocompatible metals and a neutral bridging ligand
The design of inexpensive and less toxic porous coordination polymers (PCPs) that show selective adsorption or high adsorption capacity is a critical issue in research on applicable porous materials. Although use of Group II magnesium(II) and calcium(II) ions as building blocks could provide cheaper...
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Published in: | Nature communications 2015-01, Vol.6 (1), p.5851, Article 5851 |
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creator | Noro, Shin-ichiro Mizutani, Junya Hijikata, Yuh Matsuda, Ryotaro Sato, Hiroshi Kitagawa, Susumu Sugimoto, Kunihisa Inubushi, Yasutaka Kubo, Kazuya Nakamura, Takayoshi |
description | The design of inexpensive and less toxic porous coordination polymers (PCPs) that show selective adsorption or high adsorption capacity is a critical issue in research on applicable porous materials. Although use of Group II magnesium(II) and calcium(II) ions as building blocks could provide cheaper materials and lead to enhanced biocompatibility, examples of magnesium(II) and calcium(II) PCPs are extremely limited compared with commonly used transition metal ones, because neutral bridging ligands have not been available for magnesium(II) and calcium(II) ions. Here we report a rationally designed neutral and charge-polarized bridging ligand as a new partner for magnesium(II) and calcium(II) ions. The three-dimensional magnesium(II) and calcium(II) PCPs synthesized using such a neutral ligand are stable and show selective adsorption and separation of carbon dioxide over methane at ambient temperature. This synthetic approach allows the structural diversification of Group II magnesium(II) and calcium(II) PCPs.
Inexpensive porous materials synthesized from Group II metals may be useful for industrial applications. Here, the authors demonstrate that neutral bridging ligands can be used for the synthesis of magnesium(II) and calcium(II) porous coordination polymers. |
doi_str_mv | 10.1038/ncomms6851 |
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Inexpensive porous materials synthesized from Group II metals may be useful for industrial applications. Here, the authors demonstrate that neutral bridging ligands can be used for the synthesis of magnesium(II) and calcium(II) porous coordination polymers.</description><identifier>ISSN: 2041-1723</identifier><identifier>EISSN: 2041-1723</identifier><identifier>DOI: 10.1038/ncomms6851</identifier><identifier>PMID: 25592677</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>639/301/299/1013 ; 639/638/263/49 ; 639/638/298/921 ; 639/638/455/955 ; Adsorption ; Biocompatible Materials - chemistry ; Calcium - chemistry ; Humanities and Social Sciences ; Magnesium - chemistry ; Metals - chemistry ; Molecular Structure ; multidisciplinary ; Polymers - chemistry ; Porosity ; Science ; Science (multidisciplinary)</subject><ispartof>Nature communications, 2015-01, Vol.6 (1), p.5851, Article 5851</ispartof><rights>The Author(s) 2015</rights><rights>Copyright Nature Publishing Group Jan 2015</rights><rights>Copyright © 2015, Nature Publishing Group, a division of Macmillan Publishers Limited. All Rights Reserved. 2015 Nature Publishing Group, a division of Macmillan Publishers Limited. All Rights Reserved.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c552t-5291f30ae73cc15ca586f0e912fec5c696fdf7a414b1bb04133e568de5de22e43</citedby><cites>FETCH-LOGICAL-c552t-5291f30ae73cc15ca586f0e912fec5c696fdf7a414b1bb04133e568de5de22e43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/1645882927/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/1645882927?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,25731,27901,27902,36989,44566,53766,53768,74869</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25592677$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Noro, Shin-ichiro</creatorcontrib><creatorcontrib>Mizutani, Junya</creatorcontrib><creatorcontrib>Hijikata, Yuh</creatorcontrib><creatorcontrib>Matsuda, Ryotaro</creatorcontrib><creatorcontrib>Sato, Hiroshi</creatorcontrib><creatorcontrib>Kitagawa, Susumu</creatorcontrib><creatorcontrib>Sugimoto, Kunihisa</creatorcontrib><creatorcontrib>Inubushi, Yasutaka</creatorcontrib><creatorcontrib>Kubo, Kazuya</creatorcontrib><creatorcontrib>Nakamura, Takayoshi</creatorcontrib><title>Porous coordination polymers with ubiquitous and biocompatible metals and a neutral bridging ligand</title><title>Nature communications</title><addtitle>Nat Commun</addtitle><addtitle>Nat Commun</addtitle><description>The design of inexpensive and less toxic porous coordination polymers (PCPs) that show selective adsorption or high adsorption capacity is a critical issue in research on applicable porous materials. Although use of Group II magnesium(II) and calcium(II) ions as building blocks could provide cheaper materials and lead to enhanced biocompatibility, examples of magnesium(II) and calcium(II) PCPs are extremely limited compared with commonly used transition metal ones, because neutral bridging ligands have not been available for magnesium(II) and calcium(II) ions. Here we report a rationally designed neutral and charge-polarized bridging ligand as a new partner for magnesium(II) and calcium(II) ions. The three-dimensional magnesium(II) and calcium(II) PCPs synthesized using such a neutral ligand are stable and show selective adsorption and separation of carbon dioxide over methane at ambient temperature. This synthetic approach allows the structural diversification of Group II magnesium(II) and calcium(II) PCPs.
Inexpensive porous materials synthesized from Group II metals may be useful for industrial applications. 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Commun</addtitle><date>2015-01-16</date><risdate>2015</risdate><volume>6</volume><issue>1</issue><spage>5851</spage><pages>5851-</pages><artnum>5851</artnum><issn>2041-1723</issn><eissn>2041-1723</eissn><abstract>The design of inexpensive and less toxic porous coordination polymers (PCPs) that show selective adsorption or high adsorption capacity is a critical issue in research on applicable porous materials. Although use of Group II magnesium(II) and calcium(II) ions as building blocks could provide cheaper materials and lead to enhanced biocompatibility, examples of magnesium(II) and calcium(II) PCPs are extremely limited compared with commonly used transition metal ones, because neutral bridging ligands have not been available for magnesium(II) and calcium(II) ions. Here we report a rationally designed neutral and charge-polarized bridging ligand as a new partner for magnesium(II) and calcium(II) ions. The three-dimensional magnesium(II) and calcium(II) PCPs synthesized using such a neutral ligand are stable and show selective adsorption and separation of carbon dioxide over methane at ambient temperature. This synthetic approach allows the structural diversification of Group II magnesium(II) and calcium(II) PCPs.
Inexpensive porous materials synthesized from Group II metals may be useful for industrial applications. Here, the authors demonstrate that neutral bridging ligands can be used for the synthesis of magnesium(II) and calcium(II) porous coordination polymers.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>25592677</pmid><doi>10.1038/ncomms6851</doi><oa>free_for_read</oa></addata></record> |
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subjects | 639/301/299/1013 639/638/263/49 639/638/298/921 639/638/455/955 Adsorption Biocompatible Materials - chemistry Calcium - chemistry Humanities and Social Sciences Magnesium - chemistry Metals - chemistry Molecular Structure multidisciplinary Polymers - chemistry Porosity Science Science (multidisciplinary) |
title | Porous coordination polymers with ubiquitous and biocompatible metals and a neutral bridging ligand |
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