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Organic-inorganic materials containing nanoparticles of zirconium hydrophosphate for baromembrane separation
Organic-inorganic membranes were obtained by stepwise modification of poly(ethyleneterephthalate) track membrane with nanoparticles of zirconium hydrophosphate. The modifier was inserted inside pores of the polymer, a size of which is 0.33 μm. Inner active layer was formed by this manner. Evolution...
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| Published in: | Nanoscale research letters 2015, Vol.10 (1), p.64-64, Article 64 |
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| cites | cdi_FETCH-LOGICAL-c470t-a725c6cd0e2e8f48efb1ddbefa153df2a4eda335f697942ab7a539bde84a9efb3 |
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| creator | Dzyazko, Yuliya S Rozhdestvenskaya, Ludmila M Zmievskii, Yu G Vilenskii, Alexander I Myronchuk, Valerii G Kornienko, Ludmila V Vasilyuk, Sergey V Tsyba, Nikolay N |
| description | Organic-inorganic membranes were obtained by stepwise modification of poly(ethyleneterephthalate) track membrane with nanoparticles of zirconium hydrophosphate. The modifier was inserted inside pores of the polymer, a size of which is 0.33 μm. Inner active layer was formed by this manner. Evolution of morphology and functional properties of the membranes were investigated using methods of porosimetry, potentiometry and electron microscopy. The nanoparticles (4 to 10 nm) were found to form aggregates, which block pores of the polymer. Pores between the aggregates (4 to 8 nm) as well as considerable surface charge density provide significant transport numbers of counter ions (up to 0.86 for Na
+
). The materials were applied to baromembrane separation of corn distillery. It was found that precipitate is formed mainly inside the pores of the pristine membrane. In the case of the organic-inorganic material, the deposition occurs onto the outer surface and can be removed by mechanical way. Location of the active layer inside membranes protects it against damage. |
| doi_str_mv | 10.1186/s11671-015-0758-x |
| format | article |
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+
). The materials were applied to baromembrane separation of corn distillery. It was found that precipitate is formed mainly inside the pores of the pristine membrane. In the case of the organic-inorganic material, the deposition occurs onto the outer surface and can be removed by mechanical way. Location of the active layer inside membranes protects it against damage.</description><identifier>ISSN: 1931-7573</identifier><identifier>EISSN: 1556-276X</identifier><identifier>DOI: 10.1186/s11671-015-0758-x</identifier><identifier>PMID: 25852361</identifier><language>eng</language><publisher>Boston: Springer US</publisher><subject>Chemistry and Materials Science ; Materials Science ; Molecular Medicine ; Nano ; Nano Commentary ; Nanochemistry ; Nanoscale Science and Technology ; Nanotechnology ; Nanotechnology and Microengineering ; Nanotechnology and nanomaterials (NANO-2014)</subject><ispartof>Nanoscale research letters, 2015, Vol.10 (1), p.64-64, Article 64</ispartof><rights>Dzyazko et al.; licensee Springer. 2015. This is an Open Access article distributed under the terms of the Creative Commons Attribution License ( ), which permits unrestricted use, distribution, and reproduction in any medium, provided the original work is properly credited.</rights><rights>The Author(s) 2015</rights><rights>Dzyazko et al.; licensee Springer. 2015</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c470t-a725c6cd0e2e8f48efb1ddbefa153df2a4eda335f697942ab7a539bde84a9efb3</citedby><cites>FETCH-LOGICAL-c470t-a725c6cd0e2e8f48efb1ddbefa153df2a4eda335f697942ab7a539bde84a9efb3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/1769018620/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/1769018620?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25753,27924,27925,37012,37013,44590,53791,53793,75126</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/25852361$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Dzyazko, Yuliya S</creatorcontrib><creatorcontrib>Rozhdestvenskaya, Ludmila M</creatorcontrib><creatorcontrib>Zmievskii, Yu G</creatorcontrib><creatorcontrib>Vilenskii, Alexander I</creatorcontrib><creatorcontrib>Myronchuk, Valerii G</creatorcontrib><creatorcontrib>Kornienko, Ludmila V</creatorcontrib><creatorcontrib>Vasilyuk, Sergey V</creatorcontrib><creatorcontrib>Tsyba, Nikolay N</creatorcontrib><title>Organic-inorganic materials containing nanoparticles of zirconium hydrophosphate for baromembrane separation</title><title>Nanoscale research letters</title><addtitle>Nanoscale Res Lett</addtitle><addtitle>Nanoscale Res Lett</addtitle><description>Organic-inorganic membranes were obtained by stepwise modification of poly(ethyleneterephthalate) track membrane with nanoparticles of zirconium hydrophosphate. The modifier was inserted inside pores of the polymer, a size of which is 0.33 μm. Inner active layer was formed by this manner. Evolution of morphology and functional properties of the membranes were investigated using methods of porosimetry, potentiometry and electron microscopy. The nanoparticles (4 to 10 nm) were found to form aggregates, which block pores of the polymer. Pores between the aggregates (4 to 8 nm) as well as considerable surface charge density provide significant transport numbers of counter ions (up to 0.86 for Na
+
). The materials were applied to baromembrane separation of corn distillery. It was found that precipitate is formed mainly inside the pores of the pristine membrane. In the case of the organic-inorganic material, the deposition occurs onto the outer surface and can be removed by mechanical way. Location of the active layer inside membranes protects it against damage.</description><subject>Chemistry and Materials Science</subject><subject>Materials Science</subject><subject>Molecular Medicine</subject><subject>Nano</subject><subject>Nano Commentary</subject><subject>Nanochemistry</subject><subject>Nanoscale Science and Technology</subject><subject>Nanotechnology</subject><subject>Nanotechnology and Microengineering</subject><subject>Nanotechnology and nanomaterials 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The modifier was inserted inside pores of the polymer, a size of which is 0.33 μm. Inner active layer was formed by this manner. Evolution of morphology and functional properties of the membranes were investigated using methods of porosimetry, potentiometry and electron microscopy. The nanoparticles (4 to 10 nm) were found to form aggregates, which block pores of the polymer. Pores between the aggregates (4 to 8 nm) as well as considerable surface charge density provide significant transport numbers of counter ions (up to 0.86 for Na
+
). The materials were applied to baromembrane separation of corn distillery. It was found that precipitate is formed mainly inside the pores of the pristine membrane. In the case of the organic-inorganic material, the deposition occurs onto the outer surface and can be removed by mechanical way. Location of the active layer inside membranes protects it against damage.</abstract><cop>Boston</cop><pub>Springer US</pub><pmid>25852361</pmid><doi>10.1186/s11671-015-0758-x</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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| issn | 1931-7573 1556-276X |
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| subjects | Chemistry and Materials Science Materials Science Molecular Medicine Nano Nano Commentary Nanochemistry Nanoscale Science and Technology Nanotechnology Nanotechnology and Microengineering Nanotechnology and nanomaterials (NANO-2014) |
| title | Organic-inorganic materials containing nanoparticles of zirconium hydrophosphate for baromembrane separation |
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