Spectroscopic and Crystal Field Consequences of Fluoride Binding by [Yb⋅DTMA]3+ in Aqueous Solution

Yb⋅DTMA forms a ternary complex with fluoride in aqueous solution by displacement of a bound solvent molecule from the lanthanide ion. [Yb⋅DTMA⋅F]2+ and [Yb⋅DTMA⋅OH2]3+ are in slow exchange on the relevant NMR timescale (

Saved in:
Bibliographic Details
Published in:Angewandte Chemie International Edition 2015-09, Vol.54 (37), p.10783-10786
Main Authors: Blackburn, Octavia A., Chilton, Nicholas F., Keller, Katharina, Tait, Claudia E., Myers, William K., McInnes, Eric J. L., Kenwright, Alan M., Beer, Paul D., Timmel, Christiane R., Faulkner, Stephen
Format: Article
Language:English
Subjects:
anion coordination
Aqueous solutions
Communications
Fluorides
lanthanide
Ligands
magnetic anisotropy
NMR
NMR spectroscopy
Nuclear magnetic resonance
spectroscopic methods
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Yb⋅DTMA forms a ternary complex with fluoride in aqueous solution by displacement of a bound solvent molecule from the lanthanide ion. [Yb⋅DTMA⋅F]2+ and [Yb⋅DTMA⋅OH2]3+ are in slow exchange on the relevant NMR timescale (
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201503421