Synthesis and characterization of a novel eco-friendly corrosion inhibition for mild steel in 1 M hydrochloric acid

• Published in: Scientific reports 2016-01, Vol.6 (1), p.19890-19890, Article 19890
• Main Authors: Al-Amiery, Ahmed A., Binti Kassim, Fatin A., Kadhum, Abdul Amir H., Mohamad, Abu Bakar
• Format: Article
• Language: English
• Subjects: 140/131; 639/301; 639/638; Adsorption; Corrosion; Electrochemistry; Electron microscopy; Frequency dependence; Humanities and Social Sciences; Hydrochloric acid; Immersion; Mass spectroscopy; multidisciplinary; NMR; Nuclear magnetic resonance; Polarization; Scanning electron microscopy; Science; Spectrum analysis; Steel; Temperature effects
• ISSN: 2045-2322; 2045-2322
• DOI: 10.1038/srep19890

The acid corrosion inhibition process of mild steel in 1 M HCl by azelaic acid dihydrazide has been investigated using electrochemical impedance spectroscopy (EIS), potentiodynamic polarization, open circuit potential (OCP) and electrochemical frequency modulation (EFM). Azelaic acid dihydrazide was synthesized and its chemical structure was elucidated and confirmed using spectroscopic techniques (infrared, nuclear magnetic resonance and mass spectroscopy). Potentiodynamic polarization studies indicate that azelaic acid dihydrazide is a mixed-type inhibitor. The inhibition efficiency increases with increased inhibitor concentration and reaches its maximum of 93% at 5 × 10 −3 M. The adsorption of the inhibitor on a mild steel surface obeys Langmuir’s adsorption isotherm. The effect of temperature on corrosion behavior in the presence of 5 × 10 −3 M inhibitor was studied in the temperature range of 30–60 °C. The results indicated that inhibition efficiencies were enhanced with an increase in concentration of inhibitor and decreased with a rise in temperature. To inspect the surface morphology of inhibitor film on the mild steel surface, scanning electron microscopy (SEM) was used before and after immersion in 1.0 M HCl.