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Improvement in device performance from a mixture of a liquid crystal and photosensitive acrylic prepolymer with the photoinduced vertical alignment method
In a multicomponent nematic liquid crystal (NLC) mixture of a liquid crystal (negative-type NLC) and a photosensitive acrylic prepolymer, photopolymerization upon UV irradiation induces the separation of the LC and photosensitive acrylic prepolymer layers, thereby leading to a vertical arrangement o...
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Published in: | Science and technology of advanced materials 2011-12, Vol.12 (6), p.065002-065002 |
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container_title | Science and technology of advanced materials |
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creator | Ho, Czung-Yu Lin, Fa-Hsin Tao, Yu-Tai Lee, Jiunn-Yih |
description | In a multicomponent nematic liquid crystal (NLC) mixture of a liquid crystal (negative-type NLC) and a photosensitive acrylic prepolymer, photopolymerization upon UV irradiation induces the separation of the LC and photosensitive acrylic prepolymer layers, thereby leading to a vertical arrangement of LC molecules. In this study, we propose a simple vertical alignment method for LC molecules, by adding a chiral smectic A (SmA∗) liquid crystal having homeotropic texture characteristics to an NLC mixture solution. Measurements of electro-optical properties revealed that the addition of the SmA∗ LC not only strengthened the anchoring force of the copolymer alignment film surface, but also significantly enhanced the contrast ratio (∼73%), response time and grayscale switching performance of the device. |
doi_str_mv | 10.1088/1468-6996/12/6/065002 |
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Measurements of electro-optical properties revealed that the addition of the SmA∗ LC not only strengthened the anchoring force of the copolymer alignment film surface, but also significantly enhanced the contrast ratio (∼73%), response time and grayscale switching performance of the device.</description><subject>Alignment</subject><subject>Anchoring</subject><subject>Copolymers</subject><subject>electro-optical properties</subject><subject>grayscale switching</subject><subject>homeotropic texture</subject><subject>liquid crystal</subject><subject>Liquid crystals</subject><subject>Nematic crystals</subject><subject>Optical properties</subject><subject>Photopolymerization</subject><subject>photosensitive</subject><subject>Photosensitivity</subject><subject>prepolymer</subject><subject>Prepolymers</subject><subject>Response time</subject><subject>Ultraviolet radiation</subject><subject>vertical arrangement effect</subject><issn>1468-6996</issn><issn>1878-5514</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2011</creationdate><recordtype>article</recordtype><sourceid>DOA</sourceid><recordid>eNqFkstu1DAUhiMEoqXwCCBLbFgwjO3YjrNBRRWXkSqxgbXl2MczHiVxaidT5lV4WjzNtFBUwcq373w-tv6ieEnwO4KlXBIm5ELUtVgSuhRLLDjG9FFxSmQlF5wT9jjPb5mT4llKW4yxIJQ9LU5oJauKCXpa_Fx1Qww76KAfke-RhZ03gAaILsRO93nuYuiQRp3_MU4RUHB50fqryVtk4j6NukW6t2jYhDEk6JMf_Q6QzmetN2iIMIR230FE137coHEDM-p7OxmwaAdx9OYgaf26v-mjg3ET7PPiidNtghfH8az4_unjt4svi8uvn1cXHy4XRjA8LuoGTFNhrW0jDK2FxYI23DmujSayFqJiVgDTxGHOOKPSYcNr2TjZ8IYRUp4Vq9lrg96qIfpOx70K2qubjRDXSh9abEGV3BGoGg4NLVklrOQVo4LmOypLJEB2vZ9dw9R0YE1-TdTtPen9k95v1DrsFMc1zpYseHMUxHA1QRpV55OBttU9hCkpIllZk4rJMqOv_0K3YYp9_ipFy5JiUZYCZ4rPlIkhpQjurhmC1SFJ6pASdUiJIlQJNScp17368yV3VbfRycDbGfBh-O18yKUG6zKOH8D_08L5saS_CeN1iK1Vo963IbqYs-mTKv-t-AU1Sfij</recordid><startdate>20111201</startdate><enddate>20111201</enddate><creator>Ho, Czung-Yu</creator><creator>Lin, Fa-Hsin</creator><creator>Tao, Yu-Tai</creator><creator>Lee, Jiunn-Yih</creator><general>Taylor & Francis</general><general>IOP Publishing</general><general>Taylor & Francis Ltd</general><general>Taylor & Francis Group</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7U5</scope><scope>7XB</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FK</scope><scope>8G5</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>GUQSH</scope><scope>JG9</scope><scope>L7M</scope><scope>M2O</scope><scope>MBDVC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope><scope>DOA</scope></search><sort><creationdate>20111201</creationdate><title>Improvement in device performance from a mixture of a liquid crystal and photosensitive acrylic prepolymer with the photoinduced vertical alignment method</title><author>Ho, Czung-Yu ; Lin, Fa-Hsin ; Tao, Yu-Tai ; Lee, Jiunn-Yih</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c640t-9becb70aadb6c296d062b5ff5aca1896674d6e4a1f0545428f0c598bf8b5b4113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2011</creationdate><topic>Alignment</topic><topic>Anchoring</topic><topic>Copolymers</topic><topic>electro-optical properties</topic><topic>grayscale switching</topic><topic>homeotropic texture</topic><topic>liquid crystal</topic><topic>Liquid crystals</topic><topic>Nematic crystals</topic><topic>Optical properties</topic><topic>Photopolymerization</topic><topic>photosensitive</topic><topic>Photosensitivity</topic><topic>prepolymer</topic><topic>Prepolymers</topic><topic>Response time</topic><topic>Ultraviolet radiation</topic><topic>vertical arrangement effect</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Ho, Czung-Yu</creatorcontrib><creatorcontrib>Lin, Fa-Hsin</creatorcontrib><creatorcontrib>Tao, Yu-Tai</creatorcontrib><creatorcontrib>Lee, Jiunn-Yih</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Research Library (Alumni Edition)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central</collection><collection>ProQuest Central Student</collection><collection>Research Library Prep</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><collection>ProQuest research library</collection><collection>Research Library (Corporate)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><collection>Directory of Open Access Journals</collection><jtitle>Science and technology of advanced materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Ho, Czung-Yu</au><au>Lin, Fa-Hsin</au><au>Tao, Yu-Tai</au><au>Lee, Jiunn-Yih</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Improvement in device performance from a mixture of a liquid crystal and photosensitive acrylic prepolymer with the photoinduced vertical alignment method</atitle><jtitle>Science and technology of advanced materials</jtitle><addtitle>Sci Technol Adv Mater</addtitle><date>2011-12-01</date><risdate>2011</risdate><volume>12</volume><issue>6</issue><spage>065002</spage><epage>065002</epage><pages>065002-065002</pages><issn>1468-6996</issn><eissn>1878-5514</eissn><abstract>In a multicomponent nematic liquid crystal (NLC) mixture of a liquid crystal (negative-type NLC) and a photosensitive acrylic prepolymer, photopolymerization upon UV irradiation induces the separation of the LC and photosensitive acrylic prepolymer layers, thereby leading to a vertical arrangement of LC molecules. In this study, we propose a simple vertical alignment method for LC molecules, by adding a chiral smectic A (SmA∗) liquid crystal having homeotropic texture characteristics to an NLC mixture solution. Measurements of electro-optical properties revealed that the addition of the SmA∗ LC not only strengthened the anchoring force of the copolymer alignment film surface, but also significantly enhanced the contrast ratio (∼73%), response time and grayscale switching performance of the device.</abstract><cop>United States</cop><pub>Taylor & Francis</pub><pmid>27877462</pmid><doi>10.1088/1468-6996/12/6/065002</doi><tpages>1</tpages><oa>free_for_read</oa></addata></record> |
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subjects | Alignment Anchoring Copolymers electro-optical properties grayscale switching homeotropic texture liquid crystal Liquid crystals Nematic crystals Optical properties Photopolymerization photosensitive Photosensitivity prepolymer Prepolymers Response time Ultraviolet radiation vertical arrangement effect |
title | Improvement in device performance from a mixture of a liquid crystal and photosensitive acrylic prepolymer with the photoinduced vertical alignment method |
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