(+)- trans -Chlorido-{2-[( R p )-2-(methyl-sulfan-yl)ferro-cen-yl]-2,5,6,7-tetra-hydro-pyrrolo-[1,2- c ]imidazol-3-yl-idene}bis(tri-phenyl-phosphane-κ P )palladium(II) hexa-fluorido-phosphate di-chloro-form disolvate

The title solvated complex, [FePd(C H )(C H N S)Cl(C H P) ]PF ·2CHCl , bearing a chiral ferrocenyl pyrrolo-imidazolyl-idene -heterocyclic carbene (NHC) ligand, was synthesized by oxidative addition of a chloro-imidazolium salt to Pd(PPh ) . The Pd ion is coordinated in a slightly distorted square-pl...

Full description

Saved in:
Bibliographic Details
Published in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2016-09, Vol.72 (Pt 9), p.1330-1334
Main Authors: Wilson-Konderka, Cody, Lough, Alan J, Metallinos, Costa
Format: Article
Language:English
Subjects:
Research Communications
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The title solvated complex, [FePd(C H )(C H N S)Cl(C H P) ]PF ·2CHCl , bearing a chiral ferrocenyl pyrrolo-imidazolyl-idene -heterocyclic carbene (NHC) ligand, was synthesized by oxidative addition of a chloro-imidazolium salt to Pd(PPh ) . The Pd ion is coordinated in a slightly distorted square-planar coordination geometry, with the Cl atom to the coordinating C atom of the pyrrolo-imidazolyl-idene ligand. The complex features a pendant thio-ether group that is not involved in coordination to Pd. In the crystal, weak C-H⋯F and C-H⋯π inter-actions connect the components of the structure, forming chains propagating along [1-10]. The fused pyrrolidine ring is in an envelope conformation, and the flap atom was refined as disordered over two sets of sites, with occupancies of 0.77 (4) and 0.23 (4).
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989016013190