A new desorption method for removing organic solvents from activated carbon using surfactant

• Published in: Journal of Occupational Health 2017-03, Vol.59 (2), p.194-200
• Main Authors: Hinoue, Mitsuo, Ishimatsu, Sumiyo, Fueta, Yukiko, Hori, Hajime
• Format: Article
• Language: English
• Subjects: 2-Propanol - analysis; 2-Propanol - chemistry; Acetic acid; Acetone; Activated carbon; Adsorbents; Adsorption; Alcohols; Benzene; Benzenesulfonic acids; Butanones - analysis; Butanones - chemistry; Carbon; Charcoal; Chemistry Techniques, Analytical; Chromatography, Gas; Desorption; Dichloromethane; Efficiency; Emulsification; Environmental Monitoring - methods; Ethyl acetate; Gas chromatography; Hydrocarbons; Ionization; Ionization counters; Isopropanol; Isopropyl alcohol; Methyl ethyl ketone; Occupational health; Organic Chemicals - analysis; Organic Chemicals - chemistry; Organic solvent; Organic solvents; Original; Pollutants; Salts; Sensors; Sodium; Sodium dodecyl sulfate; Sodium Dodecyl Sulfate - administration & dosage; Sodium lauryl sulfate; Sodium salts; Solvents; Solvents - analysis; Sulfonic acid; Sulfonic Acids - administration & dosage; Surface-Active Agents - administration & dosage; Surfactant; Surfactants; Temperature; Temperature effects; Toluene; Toluene - analysis; Toluene - chemistry; Work environment; Xylene
• ISSN: 1341-9145; 1348-9585; 1348-9585
• DOI: 10.1539/joh.16-0214-OA

[Abstract]: [Objectives]: A new desorption method was investigated, which does not require toxic organic solvents. Efficient desorption of organic solvents from activated carbon was achieved with an ananionic surfactant solution, focusing on its washing and emulsion action. [Methods]: Isopropyl alcohol (IPA) and methyl ethyl ketone (MEK) were used as test solvents. Lauryl benzene sulfonic acid sodium salt (LAS) and sodium dodecyl sulfate (SDS) were used as the surfactant. Activated carbon (100 mg) was placed in a vial and a predetermined amount of organic solvent was added. After leaving for about 24 h, a predetermined amount of the surfactant solution was added. After leaving for another 72 h, the vial was heated in an incubator at 60℃ for a predetermined time. The organic vapor concentration was then determined with a frame ionization detector (FID)-gas chromatograph and the desorption efficiency was calculated. [Results]: A high desorption efficiency was obtained with a 10% surfactant solution (LAS 8%, SDS 2%), 5 ml desorption solution, 60℃ desorption temperature, and desorption time of over 24 h, and the desorption efficiency was 72% for IPA and 9% for MEK. Under identical conditions, the desorption efficiencies for another five organic solvents were investigated, which were 36%, 3%, 32%, 2%, and 3% for acetone, ethyl acetate, dichloromethane, toluene, and m-xylene, respectively. [Conclusions]: A combination of two anionic surfactants exhibited a relatively high desorption efficiency for IPA. For toluene, the desorption efficiency was low due to poor detergency and emulsification power.