Roles of sliding-induced defects and dissociated water molecules on low friction of graphene

Sliding contact experiments and first-principles calculations were performed to elucidate the roles of structural defects and water dissociative adsorption process on the tribo-chemical mechanisms responsible for low friction of graphene. Sliding friction tests conducted in ambient air and under a d...

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Bibliographic Details
Published in:Scientific reports 2018-01, Vol.8 (1), p.121-121, Article 121
Main Authors: Yang, Zaixiu, Bhowmick, Sukanta, Sen, Fatih G., Banerji, Anindya, Alpas, Ahmet T.
Format: Article
Language:English
Subjects:
119/118
140/133
639/301
639/301/357
639/301/357/918
Adsorption
Atmosphere
Defects
Friction
Humanities and Social Sciences
Interfaces
multidisciplinary
Science
Science & Technology - Other Topics
Science (multidisciplinary)
Transmission electron microscopy
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Summary:Sliding contact experiments and first-principles calculations were performed to elucidate the roles of structural defects and water dissociative adsorption process on the tribo-chemical mechanisms responsible for low friction of graphene. Sliding friction tests conducted in ambient air and under a dry N 2 atmosphere showed that in both cases a high running-in coefficient of friction (COF) occurred initially but a low steady-state COF was reached only when the sliding was continued in air with moisture. Density functional theory (DFT) calculations indicated that the energy barrier ( E b ) for dissociative adsorption of H 2 O was significantly lower in case of reconstructed graphene with a monovacancy compared to pristine graphene. Cross-sectional transmission electron microscopy of graphene transferred to the counterface revealed a partly amorphous structure incorporating damaged graphene layers with d-spacings larger than that of the original layers. DFT calculations on the reconstructed bilayer AB graphene systems revealed an increase of d-spacing due to the chemisorption of H, O, and OH at the vacancy sites and a reduction in the interlayer binding energy ( E B ) between the bilayer graphene interfaces compared to pristine graphene. Thus, sliding induced defects facilitated dissociative adsorption of water molecules and reduced COF of graphene for sliding tests under ambient and humid environments but not under an inert atmosphere.
ISSN:2045-2322
2045-2322
DOI:10.1038/s41598-017-17971-1