The crystal structure of a new ferrocenyl P,N ligand: 1-[(2,2-di-methyl-hydrazin-1-yl-idene)meth-yl]-1'-(di-phenyl-phospho-rothio-yl)ferrocene

The asymmetric unit of the title compound, [Fe(C H N )(C H PS)], contains two independent mol-ecules ( and ) with very similar conformations. Each mol-ecule is built up from a ferrocene unit substituted in the 1 and 1' positions by a protected sulfur di-phenyl-phosphine and by a di-methyl-hydra...

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Bibliographic Details
Published in:Acta crystallographica. Section E, Crystallographic communications Crystallographic communications, 2018-02, Vol.74 (Pt 2), p.133-136
Main Authors: Mouas, Toma Nardjes, Daran, Jean-Claude, Merazig, Hocine, Manoury, Eric
Format: Article
Language:English
Subjects:
Chemical Sciences
Coordination chemistry
Research Communications
Online Access:Get full text
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Summary:The asymmetric unit of the title compound, [Fe(C H N )(C H PS)], contains two independent mol-ecules ( and ) with very similar conformations. Each mol-ecule is built up from a ferrocene unit substituted in the 1 and 1' positions by a protected sulfur di-phenyl-phosphine and by a di-methyl-hydrazine, -C(H)=N-N(CH ) , fragment. The two independent mol-ecules are linked by a C-H⋯N hydrogen bond. In the crystal, the - dimer is linked by a pair of C-H⋯S hydrogen bonds, forming a centrosymmetric four-mol-ecule arrangement. These units are linked by C-H⋯π inter-actions, forming a supra-molecular three-dimensional structure.
ISSN:2056-9890
2056-9890
DOI:10.1107/S2056989018000440