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Electrochemical properties of novel FeV2O4 as an anode for Na-ion batteries
Spinel based transition metal oxide – FeV 2 O 4 is applied as a novel anode for sodium-ion battery. The electrochemical tests indicate that FeV 2 O 4 is generally controlled by pseudo-capacitive process. Using cost-effective and eco-friendly aqueous based binders, Sodium-Carboxymethylcellulose/Styre...
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| Published in: | Scientific reports 2018-06, Vol.8 (1), p.1-11, Article 8839 |
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| creator | Maggay, Irish Valerie B. De Juan, Lyn Marie Z. Lu, Jeng-Shin Nguyen, Mai Thanh Yonezawa, Tetsu Chan, Ting-Shan Liu, Wei-Ren |
| description | Spinel based transition metal oxide – FeV
2
O
4
is applied as a novel anode for sodium-ion battery. The electrochemical tests indicate that FeV
2
O
4
is generally controlled by pseudo-capacitive process. Using cost-effective and eco-friendly aqueous based binders, Sodium-Carboxymethylcellulose/Styrene butadiene rubber, a highly stable capacity of ~97 mAh∙g
−1
is obtained after 200 cycles. This is attributed to the strong hydrogen bonding of carboxyl and hydroxyl groups indicating superior binding with the active material and current collector which is confirmed by the
ex-situ
cross-section images of the electrode. Meanwhile, only ~27 mAh∙g
−1
is provided by the electrode using poly(vinylidene difluoride) due to severe detachment of the electrode material from the Cu foil after 200 cycles. The obtained results provide an insight into the possible applications of FeV
2
O
4
as an anode material and the use of water-based binders to obtain highly stable electrochemical tests for sodium-ion battery. |
| doi_str_mv | 10.1038/s41598-018-27083-z |
| format | article |
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2
O
4
is applied as a novel anode for sodium-ion battery. The electrochemical tests indicate that FeV
2
O
4
is generally controlled by pseudo-capacitive process. Using cost-effective and eco-friendly aqueous based binders, Sodium-Carboxymethylcellulose/Styrene butadiene rubber, a highly stable capacity of ~97 mAh∙g
−1
is obtained after 200 cycles. This is attributed to the strong hydrogen bonding of carboxyl and hydroxyl groups indicating superior binding with the active material and current collector which is confirmed by the
ex-situ
cross-section images of the electrode. Meanwhile, only ~27 mAh∙g
−1
is provided by the electrode using poly(vinylidene difluoride) due to severe detachment of the electrode material from the Cu foil after 200 cycles. The obtained results provide an insight into the possible applications of FeV
2
O
4
as an anode material and the use of water-based binders to obtain highly stable electrochemical tests for sodium-ion battery.</description><identifier>ISSN: 2045-2322</identifier><identifier>EISSN: 2045-2322</identifier><identifier>DOI: 10.1038/s41598-018-27083-z</identifier><identifier>PMID: 29891924</identifier><language>eng</language><publisher>London: Nature Publishing Group UK</publisher><subject>140/146 ; 639/4077/4079/891 ; 639/638/898 ; Carboxymethylcellulose ; Copper ; Electrodes ; Humanities and Social Sciences ; Hydrogen bonding ; multidisciplinary ; Rubber ; Science ; Science (multidisciplinary) ; Sodium ; Styrene</subject><ispartof>Scientific reports, 2018-06, Vol.8 (1), p.1-11, Article 8839</ispartof><rights>The Author(s) 2018</rights><rights>2018. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c556t-3d3f5da75bab1ccebebd4e5893a05a56fdce406e1078a598b919a9cbd993a8d43</citedby><cites>FETCH-LOGICAL-c556t-3d3f5da75bab1ccebebd4e5893a05a56fdce406e1078a598b919a9cbd993a8d43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2053314273/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2053314273?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25752,27923,27924,37011,37012,44589,53790,53792,74897</link.rule.ids></links><search><creatorcontrib>Maggay, Irish Valerie B.</creatorcontrib><creatorcontrib>De Juan, Lyn Marie Z.</creatorcontrib><creatorcontrib>Lu, Jeng-Shin</creatorcontrib><creatorcontrib>Nguyen, Mai Thanh</creatorcontrib><creatorcontrib>Yonezawa, Tetsu</creatorcontrib><creatorcontrib>Chan, Ting-Shan</creatorcontrib><creatorcontrib>Liu, Wei-Ren</creatorcontrib><title>Electrochemical properties of novel FeV2O4 as an anode for Na-ion batteries</title><title>Scientific reports</title><addtitle>Sci Rep</addtitle><description>Spinel based transition metal oxide – FeV
2
O
4
is applied as a novel anode for sodium-ion battery. The electrochemical tests indicate that FeV
2
O
4
is generally controlled by pseudo-capacitive process. Using cost-effective and eco-friendly aqueous based binders, Sodium-Carboxymethylcellulose/Styrene butadiene rubber, a highly stable capacity of ~97 mAh∙g
−1
is obtained after 200 cycles. This is attributed to the strong hydrogen bonding of carboxyl and hydroxyl groups indicating superior binding with the active material and current collector which is confirmed by the
ex-situ
cross-section images of the electrode. Meanwhile, only ~27 mAh∙g
−1
is provided by the electrode using poly(vinylidene difluoride) due to severe detachment of the electrode material from the Cu foil after 200 cycles. The obtained results provide an insight into the possible applications of FeV
2
O
4
as an anode material and the use of water-based binders to obtain highly stable electrochemical tests for sodium-ion battery.</description><subject>140/146</subject><subject>639/4077/4079/891</subject><subject>639/638/898</subject><subject>Carboxymethylcellulose</subject><subject>Copper</subject><subject>Electrodes</subject><subject>Humanities and Social Sciences</subject><subject>Hydrogen bonding</subject><subject>multidisciplinary</subject><subject>Rubber</subject><subject>Science</subject><subject>Science (multidisciplinary)</subject><subject>Sodium</subject><subject>Styrene</subject><issn>2045-2322</issn><issn>2045-2322</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2018</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><recordid>eNp9kUtLxDAUhYMojuj8AVcBN26qebbJRhAZHzjoRt2GNL3VDp1mTDoD-uvN2MHXwkvgXsh3DvdyEDqk5IQSrk6joFKrjFCVsYIonr1voT1GhMwYZ2z7xzxC4xhnJJVkWlC9i0ZMK001E3vodtKC64N3LzBvnG3xIvgFhL6BiH2NO7-CFl_CE7sX2EZsu_R8Bbj2Ad_ZrPEdLm3fQ0iCA7RT2zbCeNP30ePl5OHiOpveX91cnE8zJ2XeZ7zitaxsIUtbUueghLISIJXmlkgr87pyIEgOlBTKphvLtKrVrqx0IlQl-D46G3wXy3IOie76YFuzCM3chjfjbWN-_3TNi3n2KyO1lorzZHC8MQj-dQmxN_MmOmhb24FfRsOIFFrkItcJPfqDzvwydOm8NcU5FaxYG7KBcsHHGKD-WoYSs47LDHGZFJf5jMu8JxEfRDHB3TOEb-t_VB9iE5eL</recordid><startdate>20180611</startdate><enddate>20180611</enddate><creator>Maggay, Irish Valerie B.</creator><creator>De Juan, Lyn Marie Z.</creator><creator>Lu, Jeng-Shin</creator><creator>Nguyen, Mai Thanh</creator><creator>Yonezawa, Tetsu</creator><creator>Chan, Ting-Shan</creator><creator>Liu, Wei-Ren</creator><general>Nature Publishing Group UK</general><general>Nature Publishing Group</general><scope>C6C</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7X7</scope><scope>7XB</scope><scope>88A</scope><scope>88E</scope><scope>88I</scope><scope>8FE</scope><scope>8FH</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BBNVY</scope><scope>BENPR</scope><scope>BHPHI</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FYUFA</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K9.</scope><scope>LK8</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7P</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>Q9U</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20180611</creationdate><title>Electrochemical properties of novel FeV2O4 as an anode for Na-ion batteries</title><author>Maggay, Irish Valerie B. ; De Juan, Lyn Marie Z. ; Lu, Jeng-Shin ; Nguyen, Mai Thanh ; Yonezawa, Tetsu ; Chan, Ting-Shan ; Liu, Wei-Ren</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c556t-3d3f5da75bab1ccebebd4e5893a05a56fdce406e1078a598b919a9cbd993a8d43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2018</creationdate><topic>140/146</topic><topic>639/4077/4079/891</topic><topic>639/638/898</topic><topic>Carboxymethylcellulose</topic><topic>Copper</topic><topic>Electrodes</topic><topic>Humanities and Social Sciences</topic><topic>Hydrogen bonding</topic><topic>multidisciplinary</topic><topic>Rubber</topic><topic>Science</topic><topic>Science (multidisciplinary)</topic><topic>Sodium</topic><topic>Styrene</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Maggay, Irish Valerie B.</creatorcontrib><creatorcontrib>De Juan, Lyn Marie Z.</creatorcontrib><creatorcontrib>Lu, Jeng-Shin</creatorcontrib><creatorcontrib>Nguyen, Mai Thanh</creatorcontrib><creatorcontrib>Yonezawa, Tetsu</creatorcontrib><creatorcontrib>Chan, Ting-Shan</creatorcontrib><creatorcontrib>Liu, Wei-Ren</creatorcontrib><collection>SpringerOpen</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Biology Database (Alumni Edition)</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>Biological Science Collection</collection><collection>ProQuest Central</collection><collection>Natural Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central</collection><collection>Health Research Premium Collection</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ProQuest Biological Science Collection</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Biological Science Database</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Scientific reports</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Maggay, Irish Valerie B.</au><au>De Juan, Lyn Marie Z.</au><au>Lu, Jeng-Shin</au><au>Nguyen, Mai Thanh</au><au>Yonezawa, Tetsu</au><au>Chan, Ting-Shan</au><au>Liu, Wei-Ren</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrochemical properties of novel FeV2O4 as an anode for Na-ion batteries</atitle><jtitle>Scientific reports</jtitle><stitle>Sci Rep</stitle><date>2018-06-11</date><risdate>2018</risdate><volume>8</volume><issue>1</issue><spage>1</spage><epage>11</epage><pages>1-11</pages><artnum>8839</artnum><issn>2045-2322</issn><eissn>2045-2322</eissn><abstract>Spinel based transition metal oxide – FeV
2
O
4
is applied as a novel anode for sodium-ion battery. The electrochemical tests indicate that FeV
2
O
4
is generally controlled by pseudo-capacitive process. Using cost-effective and eco-friendly aqueous based binders, Sodium-Carboxymethylcellulose/Styrene butadiene rubber, a highly stable capacity of ~97 mAh∙g
−1
is obtained after 200 cycles. This is attributed to the strong hydrogen bonding of carboxyl and hydroxyl groups indicating superior binding with the active material and current collector which is confirmed by the
ex-situ
cross-section images of the electrode. Meanwhile, only ~27 mAh∙g
−1
is provided by the electrode using poly(vinylidene difluoride) due to severe detachment of the electrode material from the Cu foil after 200 cycles. The obtained results provide an insight into the possible applications of FeV
2
O
4
as an anode material and the use of water-based binders to obtain highly stable electrochemical tests for sodium-ion battery.</abstract><cop>London</cop><pub>Nature Publishing Group UK</pub><pmid>29891924</pmid><doi>10.1038/s41598-018-27083-z</doi><tpages>11</tpages><oa>free_for_read</oa></addata></record> |
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| ispartof | Scientific reports, 2018-06, Vol.8 (1), p.1-11, Article 8839 |
| issn | 2045-2322 2045-2322 |
| language | eng |
| recordid | cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_5995833 |
| source | Publicly Available Content Database; Full-Text Journals in Chemistry (Open access); PubMed Central; Springer Nature - nature.com Journals - Fully Open Access |
| subjects | 140/146 639/4077/4079/891 639/638/898 Carboxymethylcellulose Copper Electrodes Humanities and Social Sciences Hydrogen bonding multidisciplinary Rubber Science Science (multidisciplinary) Sodium Styrene |
| title | Electrochemical properties of novel FeV2O4 as an anode for Na-ion batteries |
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