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Monitoring of odors emitted from stabilized dewatered sludge subjected to aging using proton transfer reaction–mass spectrometry
One of the potential emission sources of odorous compounds from wastewater treatment plants is sludge processing. The odorous compounds released from dewatered sludge can result in odor nuisance. This study concerns the use of flux hood chamber combined with proton transfer reaction—time of flight—m...
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Published in: | Environmental science and pollution research international 2019-02, Vol.26 (6), p.5500-5513 |
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description | One of the potential emission sources of odorous compounds from wastewater treatment plants is sludge processing. The odorous compounds released from dewatered sludge can result in odor nuisance. This study concerns the use of flux hood chamber combined with proton transfer reaction—time of flight—mass spectrometry (PTR-MS) technique for periodical monitoring of odorous compounds emitted from aged, stabilized dewatered sludge samples from 2 different wastewater treatment plants located in Pomeranian Voivodeship, Poland. Based on determined concentration of the chemical compounds and olfactory threshold values, theoretical odor concentrations (known also as “odor activity value” or “odor index”) were calculated for 17 selected odorous compounds. As a result, sulfur compounds such as diethyl sulphide, dimethyl sulphide, methanethiol, and ethanethiol were estimated as the most significant chemical compounds responsible for malodorous effect (average results, e.g., methanethiol, 178 ou/m
3
; diethyl sulphide, 184 ou/m
3
). Based on Pearson correlation coefficient, we revealed a correlation between odorous substances emitted from aged, stabilized dewatered sludge cakes. It was revealed that stabilized dewatered sludge still possessed significant amount of odorous compounds and applied measurement technique could be used for monitoring of odor concentration level of selected malodorous compounds. |
doi_str_mv | 10.1007/s11356-018-4041-4 |
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3
; diethyl sulphide, 184 ou/m
3
). Based on Pearson correlation coefficient, we revealed a correlation between odorous substances emitted from aged, stabilized dewatered sludge cakes. It was revealed that stabilized dewatered sludge still possessed significant amount of odorous compounds and applied measurement technique could be used for monitoring of odor concentration level of selected malodorous compounds.</description><identifier>ISSN: 0944-1344</identifier><identifier>EISSN: 1614-7499</identifier><identifier>DOI: 10.1007/s11356-018-4041-4</identifier><identifier>PMID: 30610582</identifier><language>eng</language><publisher>Berlin/Heidelberg: Springer Berlin Heidelberg</publisher><subject>Aging ; Air Pollutants - analysis ; Aquatic Pollution ; Atmospheric Protection/Air Quality Control/Air Pollution ; Cakes ; Chemical compounds ; Correlation coefficient ; Correlation coefficients ; Dimethyl sulfide ; Earth and Environmental Science ; Ecotoxicology ; Environment ; Environmental Chemistry ; Environmental Health ; Environmental Monitoring - methods ; Environmental science ; Malodorous compounds ; Mass Spectrometry ; Mass spectroscopy ; Measurement techniques ; Methanethiol ; Monitoring ; odor compounds ; Odor thresholds ; Odorants - analysis ; Odors ; Off odor ; Olfactory thresholds ; Organic chemistry ; Poland ; Protons ; Research Article ; Scientific imaging ; Sewage - chemistry ; Sludge ; Smell ; Spectroscopy ; Sulfhydryl Compounds ; Sulfides ; Sulfur ; Sulfur Compounds ; Waste Disposal, Fluid ; Waste Water ; Waste Water Technology ; Wastewater treatment ; Wastewater treatment plants ; Water Management ; Water Pollution Control ; Water treatment</subject><ispartof>Environmental science and pollution research international, 2019-02, Vol.26 (6), p.5500-5513</ispartof><rights>The Author(s) 2019</rights><rights>Environmental Science and Pollution Research is a copyright of Springer, (2019). All Rights Reserved. © 2019. This work is published under http://creativecommons.org/licenses/by/4.0/ (the “License”). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c503t-4ec862ef820129069b1d54c6f1dad5af80e272fe2afc1d3313ffc17eaca05ef83</citedby><cites>FETCH-LOGICAL-c503t-4ec862ef820129069b1d54c6f1dad5af80e272fe2afc1d3313ffc17eaca05ef83</cites><orcidid>0000-0002-1350-4094</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2163284757/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$H</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2163284757?pq-origsite=primo$$EHTML$$P50$$Gproquest$$H</linktohtml><link.rule.ids>230,314,776,780,881,11667,27901,27902,36037,36038,44339,74638</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/30610582$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Byliński, Hubert</creatorcontrib><creatorcontrib>Barczak, Radosław J.</creatorcontrib><creatorcontrib>Gębicki, Jacek</creatorcontrib><creatorcontrib>Namieśnik, Jacek</creatorcontrib><title>Monitoring of odors emitted from stabilized dewatered sludge subjected to aging using proton transfer reaction–mass spectrometry</title><title>Environmental science and pollution research international</title><addtitle>Environ Sci Pollut Res</addtitle><addtitle>Environ Sci Pollut Res Int</addtitle><description>One of the potential emission sources of odorous compounds from wastewater treatment plants is sludge processing. The odorous compounds released from dewatered sludge can result in odor nuisance. This study concerns the use of flux hood chamber combined with proton transfer reaction—time of flight—mass spectrometry (PTR-MS) technique for periodical monitoring of odorous compounds emitted from aged, stabilized dewatered sludge samples from 2 different wastewater treatment plants located in Pomeranian Voivodeship, Poland. Based on determined concentration of the chemical compounds and olfactory threshold values, theoretical odor concentrations (known also as “odor activity value” or “odor index”) were calculated for 17 selected odorous compounds. As a result, sulfur compounds such as diethyl sulphide, dimethyl sulphide, methanethiol, and ethanethiol were estimated as the most significant chemical compounds responsible for malodorous effect (average results, e.g., methanethiol, 178 ou/m
3
; diethyl sulphide, 184 ou/m
3
). Based on Pearson correlation coefficient, we revealed a correlation between odorous substances emitted from aged, stabilized dewatered sludge cakes. It was revealed that stabilized dewatered sludge still possessed significant amount of odorous compounds and applied measurement technique could be used for monitoring of odor concentration level of selected malodorous compounds.</description><subject>Aging</subject><subject>Air Pollutants - analysis</subject><subject>Aquatic Pollution</subject><subject>Atmospheric Protection/Air Quality Control/Air Pollution</subject><subject>Cakes</subject><subject>Chemical compounds</subject><subject>Correlation coefficient</subject><subject>Correlation coefficients</subject><subject>Dimethyl sulfide</subject><subject>Earth and Environmental Science</subject><subject>Ecotoxicology</subject><subject>Environment</subject><subject>Environmental Chemistry</subject><subject>Environmental Health</subject><subject>Environmental Monitoring - methods</subject><subject>Environmental science</subject><subject>Malodorous compounds</subject><subject>Mass Spectrometry</subject><subject>Mass spectroscopy</subject><subject>Measurement techniques</subject><subject>Methanethiol</subject><subject>Monitoring</subject><subject>odor compounds</subject><subject>Odor thresholds</subject><subject>Odorants - analysis</subject><subject>Odors</subject><subject>Off odor</subject><subject>Olfactory thresholds</subject><subject>Organic chemistry</subject><subject>Poland</subject><subject>Protons</subject><subject>Research Article</subject><subject>Scientific imaging</subject><subject>Sewage - chemistry</subject><subject>Sludge</subject><subject>Smell</subject><subject>Spectroscopy</subject><subject>Sulfhydryl Compounds</subject><subject>Sulfides</subject><subject>Sulfur</subject><subject>Sulfur Compounds</subject><subject>Waste Disposal, Fluid</subject><subject>Waste Water</subject><subject>Waste Water Technology</subject><subject>Wastewater treatment</subject><subject>Wastewater treatment plants</subject><subject>Water Management</subject><subject>Water Pollution Control</subject><subject>Water treatment</subject><issn>0944-1344</issn><issn>1614-7499</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><sourceid>M0C</sourceid><recordid>eNqFkstu1TAQhi1ERQ-FB2CDLLFhEzpjO7cNEqq4Sa3YwNryScYHHyVxsJ2iskK8Am_Ik-DolBaQEBt7LH_zz9jzM_YI4RkC1KcRUZZVAdgUChQW6g7bYIWqqFXb3mUbaJUqUCp1zO7HuAcQ0Ir6HjuWUCGUjdiwbxd-cskHN-24t9z3PkROo0uJem6DH3lMZusG9yWfe_psEoUcxWHpd8Tjst1Tt6LJc7NbRZa4rnPwyU88BTNFS4EHMl1yfvrx9ftoYuRxzmlZnVK4esCOrBkiPbzeT9iHVy_fn70pzt-9fnv24rzoSpCpUNQ1lSDbCEDRQtVusS9VV1nsTV8a2wCJWlgSxnbYS4nS5qDOhQ2UOU2esOcH3XnZjtR3NOX2Bj0HN5pwpb1x-s-byX3UO3-pKwVSQJ0Fnl4LBP9poZj06GJHw2Am8kvUQog8llag-j-KlUJQZSsz-uQvdO-XMOWfWCkpGlWXa208UF3wMQayN30j6NUM-mAGnc2gVzPotYnHvz_4JuPX9DMgDkCcVwNQuC39b9WfBRTEfg</recordid><startdate>20190201</startdate><enddate>20190201</enddate><creator>Byliński, Hubert</creator><creator>Barczak, Radosław J.</creator><creator>Gębicki, Jacek</creator><creator>Namieśnik, Jacek</creator><general>Springer Berlin Heidelberg</general><general>Springer Nature B.V</general><scope>C6C</scope><scope>CGR</scope><scope>CUY</scope><scope>CVF</scope><scope>ECM</scope><scope>EIF</scope><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7QL</scope><scope>7SN</scope><scope>7T7</scope><scope>7TV</scope><scope>7U7</scope><scope>7WY</scope><scope>7WZ</scope><scope>7X7</scope><scope>7XB</scope><scope>87Z</scope><scope>88E</scope><scope>88I</scope><scope>8AO</scope><scope>8C1</scope><scope>8FD</scope><scope>8FI</scope><scope>8FJ</scope><scope>8FK</scope><scope>8FL</scope><scope>ABUWG</scope><scope>AEUYN</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BEZIV</scope><scope>BHPHI</scope><scope>C1K</scope><scope>CCPQU</scope><scope>DWQXO</scope><scope>FR3</scope><scope>FRNLG</scope><scope>FYUFA</scope><scope>F~G</scope><scope>GHDGH</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>K60</scope><scope>K6~</scope><scope>K9.</scope><scope>L.-</scope><scope>M0C</scope><scope>M0S</scope><scope>M1P</scope><scope>M2P</scope><scope>M7N</scope><scope>P64</scope><scope>PATMY</scope><scope>PQBIZ</scope><scope>PQBZA</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7X8</scope><scope>7S9</scope><scope>L.6</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-1350-4094</orcidid></search><sort><creationdate>20190201</creationdate><title>Monitoring of odors emitted from stabilized dewatered sludge subjected to aging using proton transfer reaction–mass spectrometry</title><author>Byliński, Hubert ; Barczak, Radosław J. ; Gębicki, Jacek ; Namieśnik, Jacek</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c503t-4ec862ef820129069b1d54c6f1dad5af80e272fe2afc1d3313ffc17eaca05ef83</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Aging</topic><topic>Air Pollutants - analysis</topic><topic>Aquatic Pollution</topic><topic>Atmospheric Protection/Air Quality Control/Air Pollution</topic><topic>Cakes</topic><topic>Chemical compounds</topic><topic>Correlation coefficient</topic><topic>Correlation coefficients</topic><topic>Dimethyl sulfide</topic><topic>Earth and Environmental Science</topic><topic>Ecotoxicology</topic><topic>Environment</topic><topic>Environmental Chemistry</topic><topic>Environmental Health</topic><topic>Environmental Monitoring - methods</topic><topic>Environmental science</topic><topic>Malodorous compounds</topic><topic>Mass Spectrometry</topic><topic>Mass spectroscopy</topic><topic>Measurement techniques</topic><topic>Methanethiol</topic><topic>Monitoring</topic><topic>odor compounds</topic><topic>Odor thresholds</topic><topic>Odorants - analysis</topic><topic>Odors</topic><topic>Off odor</topic><topic>Olfactory thresholds</topic><topic>Organic chemistry</topic><topic>Poland</topic><topic>Protons</topic><topic>Research Article</topic><topic>Scientific imaging</topic><topic>Sewage - chemistry</topic><topic>Sludge</topic><topic>Smell</topic><topic>Spectroscopy</topic><topic>Sulfhydryl Compounds</topic><topic>Sulfides</topic><topic>Sulfur</topic><topic>Sulfur Compounds</topic><topic>Waste Disposal, Fluid</topic><topic>Waste Water</topic><topic>Waste Water Technology</topic><topic>Wastewater treatment</topic><topic>Wastewater treatment plants</topic><topic>Water Management</topic><topic>Water Pollution Control</topic><topic>Water treatment</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Byliński, Hubert</creatorcontrib><creatorcontrib>Barczak, Radosław J.</creatorcontrib><creatorcontrib>Gębicki, Jacek</creatorcontrib><creatorcontrib>Namieśnik, Jacek</creatorcontrib><collection>Springer Open Access</collection><collection>Medline</collection><collection>MEDLINE</collection><collection>MEDLINE (Ovid)</collection><collection>MEDLINE</collection><collection>MEDLINE</collection><collection>PubMed</collection><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Bacteriology Abstracts (Microbiology B)</collection><collection>Ecology Abstracts</collection><collection>Industrial and Applied Microbiology Abstracts (Microbiology A)</collection><collection>Pollution Abstracts</collection><collection>Toxicology Abstracts</collection><collection>ABI/INFORM Collection (ProQuest)</collection><collection>ABI/INFORM Global (PDF only)</collection><collection>Health & Medical Collection</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection</collection><collection>Medical Database (Alumni Edition)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Public Health Database</collection><collection>Technology Research Database</collection><collection>Hospital Premium Collection</collection><collection>Hospital Premium Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>ABI/INFORM Collection (Alumni Edition)</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest One Sustainability</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>ProQuest Business Premium Collection</collection><collection>ProQuest Natural Science Collection</collection><collection>Environmental Sciences and Pollution Management</collection><collection>ProQuest One Community College</collection><collection>ProQuest Central</collection><collection>Engineering Research Database</collection><collection>Business Premium Collection (Alumni)</collection><collection>Health Research Premium Collection</collection><collection>ABI/INFORM Global (Corporate)</collection><collection>Health Research Premium Collection (Alumni)</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>ProQuest Business Collection (Alumni Edition)</collection><collection>ProQuest Business Collection</collection><collection>ProQuest Health & Medical Complete (Alumni)</collection><collection>ABI/INFORM Professional Advanced</collection><collection>ABI/INFORM Global</collection><collection>Health & Medical Collection (Alumni Edition)</collection><collection>Medical Database</collection><collection>Science Database</collection><collection>Algology Mycology and Protozoology Abstracts (Microbiology C)</collection><collection>Biotechnology and BioEngineering Abstracts</collection><collection>Environmental Science Database</collection><collection>One Business (ProQuest)</collection><collection>ProQuest One Business (Alumni)</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>MEDLINE - Academic</collection><collection>AGRICOLA</collection><collection>AGRICOLA - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Environmental science and pollution research international</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Byliński, Hubert</au><au>Barczak, Radosław J.</au><au>Gębicki, Jacek</au><au>Namieśnik, Jacek</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Monitoring of odors emitted from stabilized dewatered sludge subjected to aging using proton transfer reaction–mass spectrometry</atitle><jtitle>Environmental science and pollution research international</jtitle><stitle>Environ Sci Pollut Res</stitle><addtitle>Environ Sci Pollut Res Int</addtitle><date>2019-02-01</date><risdate>2019</risdate><volume>26</volume><issue>6</issue><spage>5500</spage><epage>5513</epage><pages>5500-5513</pages><issn>0944-1344</issn><eissn>1614-7499</eissn><abstract>One of the potential emission sources of odorous compounds from wastewater treatment plants is sludge processing. The odorous compounds released from dewatered sludge can result in odor nuisance. This study concerns the use of flux hood chamber combined with proton transfer reaction—time of flight—mass spectrometry (PTR-MS) technique for periodical monitoring of odorous compounds emitted from aged, stabilized dewatered sludge samples from 2 different wastewater treatment plants located in Pomeranian Voivodeship, Poland. Based on determined concentration of the chemical compounds and olfactory threshold values, theoretical odor concentrations (known also as “odor activity value” or “odor index”) were calculated for 17 selected odorous compounds. As a result, sulfur compounds such as diethyl sulphide, dimethyl sulphide, methanethiol, and ethanethiol were estimated as the most significant chemical compounds responsible for malodorous effect (average results, e.g., methanethiol, 178 ou/m
3
; diethyl sulphide, 184 ou/m
3
). Based on Pearson correlation coefficient, we revealed a correlation between odorous substances emitted from aged, stabilized dewatered sludge cakes. It was revealed that stabilized dewatered sludge still possessed significant amount of odorous compounds and applied measurement technique could be used for monitoring of odor concentration level of selected malodorous compounds.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>30610582</pmid><doi>10.1007/s11356-018-4041-4</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-1350-4094</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Aging Air Pollutants - analysis Aquatic Pollution Atmospheric Protection/Air Quality Control/Air Pollution Cakes Chemical compounds Correlation coefficient Correlation coefficients Dimethyl sulfide Earth and Environmental Science Ecotoxicology Environment Environmental Chemistry Environmental Health Environmental Monitoring - methods Environmental science Malodorous compounds Mass Spectrometry Mass spectroscopy Measurement techniques Methanethiol Monitoring odor compounds Odor thresholds Odorants - analysis Odors Off odor Olfactory thresholds Organic chemistry Poland Protons Research Article Scientific imaging Sewage - chemistry Sludge Smell Spectroscopy Sulfhydryl Compounds Sulfides Sulfur Sulfur Compounds Waste Disposal, Fluid Waste Water Waste Water Technology Wastewater treatment Wastewater treatment plants Water Management Water Pollution Control Water treatment |
title | Monitoring of odors emitted from stabilized dewatered sludge subjected to aging using proton transfer reaction–mass spectrometry |
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