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Monitoring of odors emitted from stabilized dewatered sludge subjected to aging using proton transfer reaction–mass spectrometry

One of the potential emission sources of odorous compounds from wastewater treatment plants is sludge processing. The odorous compounds released from dewatered sludge can result in odor nuisance. This study concerns the use of flux hood chamber combined with proton transfer reaction—time of flight—m...

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Published in:Environmental science and pollution research international 2019-02, Vol.26 (6), p.5500-5513
Main Authors: Byliński, Hubert, Barczak, Radosław J., Gębicki, Jacek, Namieśnik, Jacek
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description One of the potential emission sources of odorous compounds from wastewater treatment plants is sludge processing. The odorous compounds released from dewatered sludge can result in odor nuisance. This study concerns the use of flux hood chamber combined with proton transfer reaction—time of flight—mass spectrometry (PTR-MS) technique for periodical monitoring of odorous compounds emitted from aged, stabilized dewatered sludge samples from 2 different wastewater treatment plants located in Pomeranian Voivodeship, Poland. Based on determined concentration of the chemical compounds and olfactory threshold values, theoretical odor concentrations (known also as “odor activity value” or “odor index”) were calculated for 17 selected odorous compounds. As a result, sulfur compounds such as diethyl sulphide, dimethyl sulphide, methanethiol, and ethanethiol were estimated as the most significant chemical compounds responsible for malodorous effect (average results, e.g., methanethiol, 178 ou/m 3 ; diethyl sulphide, 184 ou/m 3 ). Based on Pearson correlation coefficient, we revealed a correlation between odorous substances emitted from aged, stabilized dewatered sludge cakes. It was revealed that stabilized dewatered sludge still possessed significant amount of odorous compounds and applied measurement technique could be used for monitoring of odor concentration level of selected malodorous compounds.
doi_str_mv 10.1007/s11356-018-4041-4
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Based on Pearson correlation coefficient, we revealed a correlation between odorous substances emitted from aged, stabilized dewatered sludge cakes. It was revealed that stabilized dewatered sludge still possessed significant amount of odorous compounds and applied measurement technique could be used for monitoring of odor concentration level of selected malodorous compounds.</abstract><cop>Berlin/Heidelberg</cop><pub>Springer Berlin Heidelberg</pub><pmid>30610582</pmid><doi>10.1007/s11356-018-4041-4</doi><tpages>14</tpages><orcidid>https://orcid.org/0000-0002-1350-4094</orcidid><oa>free_for_read</oa></addata></record>
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ispartof Environmental science and pollution research international, 2019-02, Vol.26 (6), p.5500-5513
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source ABI/INFORM Global; Springer Link
subjects Aging
Air Pollutants - analysis
Aquatic Pollution
Atmospheric Protection/Air Quality Control/Air Pollution
Cakes
Chemical compounds
Correlation coefficient
Correlation coefficients
Dimethyl sulfide
Earth and Environmental Science
Ecotoxicology
Environment
Environmental Chemistry
Environmental Health
Environmental Monitoring - methods
Environmental science
Malodorous compounds
Mass Spectrometry
Mass spectroscopy
Measurement techniques
Methanethiol
Monitoring
odor compounds
Odor thresholds
Odorants - analysis
Odors
Off odor
Olfactory thresholds
Organic chemistry
Poland
Protons
Research Article
Scientific imaging
Sewage - chemistry
Sludge
Smell
Spectroscopy
Sulfhydryl Compounds
Sulfides
Sulfur
Sulfur Compounds
Waste Disposal, Fluid
Waste Water
Waste Water Technology
Wastewater treatment
Wastewater treatment plants
Water Management
Water Pollution Control
Water treatment
title Monitoring of odors emitted from stabilized dewatered sludge subjected to aging using proton transfer reaction–mass spectrometry
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