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Pore-tuning to boost the electrocatalytic activity of polymeric micelle-templated mesoporous Pd nanoparticles† †Electronic supplementary information (ESI) available. See DOI: 10.1039/c8sc03911a

Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for the rational design and preparation of high-performance electrocatalysts. Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for...

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Bibliographic Details
Published in:Chemical science (Cambridge) 2019-03, Vol.10 (14), p.4054-4061
Main Authors: Li, Cuiling, Iqbal, Muhammad, Jiang, Bo, Wang, Zhongli, Kim, Jeonghun, Nanjundan, Ashok Kumar, Whitten, Andrew E., Wood, Kathleen, Yamauchi, Yusuke
Format: Article
Language:English
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Summary:Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for the rational design and preparation of high-performance electrocatalysts. Understanding how mesoporous noble metal architectures affect electrocatalytic performance is very important for the rational design and preparation of high-performance electrocatalysts. Herein, by using polymeric micelle-assembled structures as templates, mesoporous Pd nanoparticles with tunable porous constructions are synthesized by simply tuning the solvent compositions. The effect of porous Pd nanoparticles on the electrocatalytic performance is thoroughly studied. Their superior electrocatalytic activity can be attributed to the mass transport efficiency and open porous structures.
ISSN:2041-6520
2041-6539
DOI:10.1039/c8sc03911a