Lanthanide(III)-Based Single-Ion Magnets

Mononuclear lanthanide-based single-ion magnets (SIMs) are known since 2003 with the discovery of SIM properties in a bis-(phthalocyaninato)­lanthanide complex. A recent report on [Dy­(Cpttt)2]­[BC6F5] indicating that it exhibits the highest known blocking temperature (60 K) has spurred fresh intere...

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Published in:ACS omega 2018-08, Vol.3 (8), p.9462-9475
Main Authors: Dey, Atanu, Kalita, Pankaj, Chandrasekhar, Vadapalli
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description Mononuclear lanthanide-based single-ion magnets (SIMs) are known since 2003 with the discovery of SIM properties in a bis-(phthalocyaninato)­lanthanide complex. A recent report on [Dy­(Cpttt)2]­[BC6F5] indicating that it exhibits the highest known blocking temperature (60 K) has spurred fresh interest in this area. In this article, we discuss about the various requirements of lanthanide-based SIMs along with representative examples. Specifically, we describe the complexes whose coordination numbers vary from 2 to 8. We also discuss the representative examples of organometallic lanthanide complexes that can function as molecular magnets.
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title Lanthanide(III)-Based Single-Ion Magnets
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