Hydrogen peroxide generation from O2 electroreduction for environmental remediation: A state-of-the-art review

• Published in: Chemosphere (Oxford) 2019-06, Vol.225, p.588-607
• Main Authors: Zhou, Wei, Meng, Xiaoxiao, Gao, Jihui, Alshawabkeh, Akram N.
• Format: Article
• Language: English
• Subjects: anthraquinones; carbon; Carbon materials; cathodes; drugs; dyes; Electro-Fenton; electrochemistry; electrolytes; Environmental remediation; herbicides; Hydrogen peroxide; mercury; nitric oxide; oxygen; Oxygen reduction reaction; phenolic compounds; remediation; sulfur dioxide; temperature; volatile organic compounds
• ISSN: 0045-6535; 1879-1298; 1879-1298
• DOI: 10.1016/j.chemosphere.2019.03.042

The electrochemical production of hydrogen peroxide (H2O2) by 2-electron oxygen reduction reaction (ORR) is an attractive alternative to the present complex anthraquinone process. The objective of this paper is to provide a state-of-the-arts review of the most important aspects of this process. First, recent advances in H2O2 production are reviewed and the advantages of H2O2 electrogeneration via 2-electron ORR are highlighted. Second, the selectivity of the ORR pathway towards H2O2 formation as well as the development process of H2O2 production are presented. The cathode characteristics are the decisive factors of H2O2 production. Thus the focus is shifted to the introduction of commonly used carbon cathodes and their modification methods, including the introduction of other active carbon materials, hetero-atoms doping (i.e., O, N, F, B, and P) and decoration with metal oxides. Cathode stability is evaluated due to its significance for long-term application. Effects of various operational parameters, such as electrode potential/current density, supporting electrolyte, electrolyte pH, temperature, dissolved oxygen, and current mode on H2O2 production are then discussed. Additionally, the environmental application of electrogenerated H2O2 on aqueous and gaseous contaminants removal, including dyes, pesticides, herbicides, phenolic compounds, drugs, VOCs, SO2, NO, and Hg0, are described. Finally, a brief conclusion about the recent progress achieved in H2O2 electrogeneration via 2-electron ORR and an outlook on future research challenges are proposed. [Display omitted] •Recent advances in H2O2 production by various methods are reviewed.•H2O2 electrogeneration by various carbon-based materials are summarized.•Effects of operation parameters and reactors on H2O2 production are reviewed.•The applications of electrogenerated H2O2 on organic contaminants degradation are presented.•Future perspectives on O2 electroreduction for H2O2 production are suggested.