Photoinduced Heterogeneous C−H Arylation by a Reusable Hybrid Copper Catalyst

Heterogeneous copper catalysis enabled photoinduced C−H arylations under exceedingly mild conditions at room temperature. The versatile hybrid copper catalyst provided step‐economical access to arylated heteroarenes, terpenes and alkaloid natural products with various aryl halides. The hybrid copper...

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Published in:Chemistry : a European journal 2020-03, Vol.26 (16), p.3509-3514
Main Authors: Choi, Isaac, Müller, Valentin, Lole, Gaurav, Köhler, Robert, Karius, Volker, Viöl, Wolfgang, Jooss, Christian, Ackermann, Lutz
Format: Article
Language:English
Subjects:
Aromatic compounds
Catalysis
Catalysts
Chemistry
Communication
Communications
Copper
copper catalysis
C−H arylation
Halides
heterogeneous catalysis
hybrid catalysis
Natural products
photocatalysis
Room temperature
Terpenes
X ray photoelectron spectroscopy
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cited_by cdi_FETCH-LOGICAL-c5712-b30b331cd1ff9a04a5a78361497c84a5e470923ddce2390ce3372fa7e7da8f083
cites cdi_FETCH-LOGICAL-c5712-b30b331cd1ff9a04a5a78361497c84a5e470923ddce2390ce3372fa7e7da8f083
container_end_page 3514
container_issue 16
container_start_page 3509
container_title Chemistry : a European journal
container_volume 26
creator Choi, Isaac
Müller, Valentin
Lole, Gaurav
Köhler, Robert
Karius, Volker
Viöl, Wolfgang
Jooss, Christian
Ackermann, Lutz
description Heterogeneous copper catalysis enabled photoinduced C−H arylations under exceedingly mild conditions at room temperature. The versatile hybrid copper catalyst provided step‐economical access to arylated heteroarenes, terpenes and alkaloid natural products with various aryl halides. The hybrid copper catalyst could be reused without significant loss of catalytic efficacy. Detailed studies in terms of TEM, HRTEM and XPS analysis of the hybrid copper catalyst, among others, supported its outstanding stability and reusability. Let there be light: C−H arylations were realized at room temperature with a hybrid copper catalyst, enabling catalyst recycling and reuse.
doi_str_mv 10.1002/chem.202000192
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source Wiley-Blackwell Read & Publish Collection
subjects Aromatic compounds
Catalysis
Catalysts
Chemistry
Communication
Communications
Copper
copper catalysis
C−H arylation
Halides
heterogeneous catalysis
hybrid catalysis
Natural products
photocatalysis
Room temperature
Terpenes
X ray photoelectron spectroscopy
title Photoinduced Heterogeneous C−H Arylation by a Reusable Hybrid Copper Catalyst
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