Enhanced dielectricity coupled to spin-crossover in a one-dimensional polymer iron(ii) incorporating tetrathiafulvalene† †Electronic supplementary information (ESI) available. CCDC 1835730, 1835731 and 1942248. For ESI and crystallographic data in CIF or other electronic format see DOI: 10.1039/d0sc02388d

• Published in: Chemical science (Cambridge) 2020-05, Vol.11 (24), p.6229-6235
• Main Authors: Qiu, Ya-Ru, Cui, Long, Cai, Pei-Yu, Yu, Fei, Kurmoo, Mohamedally, Leong, Chanel F., D'Alessandro, Deanna M., Zuo, Jing-Lin
• Format: Article
• Language: English
• Subjects: Chemistry
• ISSN: 2041-6520; 2041-6539
• DOI: 10.1039/d0sc02388d

A concerted bending–flattening motion of the redox-active TTF within constructed one-dimensional Fe II –TTF–Schiff-base chain with bridging 4,4′-bpy enhances the dielectric constant coupled to its spin-crossover transition above room temperature. In designing multifunctional materials for potential switches that can be used as memory devices, the high-spin (HS) to low-spin (LS) crossover (SCO) one-dimensional polymer, [Fe II (L)(4,4′-bpy)] n , was constructed from a designed redox-active tetrathiafulvalene (TTF) functionalized Schiff-base and the ditopic linker 4,4′-bipyridine (bpy). It exhibits an 8 K hysteretic SCO centred at T 1/2 = 325 K which is coupled to changes in its dielectric constant. The crystal structures above and below the transition temperature reveal similar parallel linear ···Fe–bpy–Fe–bpy··· chains displaying expansion of the Fe II octahedron in the HS state. Density functional theory (DFT) calculations reveal a concerted electronic charge and spin change represented by the Mülliken charge of the Fe and the magnitude and direction of the dipole moment which substantiate the experimental observations.