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Optical Sensing and Imaging of pH Values: Spectroscopies, Materials, and Applications
This is the first comprehensive review on methods and materials for use in optical sensing of pH values and on applications of such sensors. The Review starts with an introduction that contains subsections on the definition of the pH value, a brief look back on optical methods for sensing of pH, on...
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Published in: | Chemical reviews 2020-11, Vol.120 (22), p.12357-12489 |
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description | This is the first comprehensive review on methods and materials for use in optical sensing of pH values and on applications of such sensors. The Review starts with an introduction that contains subsections on the definition of the pH value, a brief look back on optical methods for sensing of pH, on the effects of ionic strength on pH values and pK a values, on the selectivity, sensitivity, precision, dynamic ranges, and temperature dependence of such sensors. Commonly used optical sensing schemes are covered in a next main chapter, with subsections on methods based on absorptiometry, reflectometry, luminescence, refractive index, surface plasmon resonance, photonic crystals, turbidity, mechanical displacement, interferometry, and solvatochromism. This is followed by sections on absorptiometric and luminescent molecular probes for use pH in sensors. Further large sections cover polymeric hosts and supports, and methods for immobilization of indicator dyes. Further and more specific sections summarize the state of the art in materials with dual functionality (indicator and host), nanomaterials, sensors based on upconversion and 2-photon absorption, multiparameter sensors, imaging, and sensors for extreme pH values. A chapter on the many sensing formats has subsections on planar, fiber optic, evanescent wave, refractive index, surface plasmon resonance and holography based sensor designs, and on distributed sensing. Another section summarizes selected applications in areas, such as medicine, biology, oceanography, bioprocess monitoring, corrosion studies, on the use of pH sensors as transducers in biosensors and chemical sensors, and their integration into flow-injection analyzers, microfluidic devices, and lab-on-a-chip systems. An extra section is devoted to current challenges, with subsections on challenges of general nature and those of specific nature. A concluding section gives an outlook on potential future trends and perspectives. |
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Rev</addtitle><description>This is the first comprehensive review on methods and materials for use in optical sensing of pH values and on applications of such sensors. The Review starts with an introduction that contains subsections on the definition of the pH value, a brief look back on optical methods for sensing of pH, on the effects of ionic strength on pH values and pK a values, on the selectivity, sensitivity, precision, dynamic ranges, and temperature dependence of such sensors. Commonly used optical sensing schemes are covered in a next main chapter, with subsections on methods based on absorptiometry, reflectometry, luminescence, refractive index, surface plasmon resonance, photonic crystals, turbidity, mechanical displacement, interferometry, and solvatochromism. This is followed by sections on absorptiometric and luminescent molecular probes for use pH in sensors. Further large sections cover polymeric hosts and supports, and methods for immobilization of indicator dyes. Further and more specific sections summarize the state of the art in materials with dual functionality (indicator and host), nanomaterials, sensors based on upconversion and 2-photon absorption, multiparameter sensors, imaging, and sensors for extreme pH values. A chapter on the many sensing formats has subsections on planar, fiber optic, evanescent wave, refractive index, surface plasmon resonance and holography based sensor designs, and on distributed sensing. Another section summarizes selected applications in areas, such as medicine, biology, oceanography, bioprocess monitoring, corrosion studies, on the use of pH sensors as transducers in biosensors and chemical sensors, and their integration into flow-injection analyzers, microfluidic devices, and lab-on-a-chip systems. An extra section is devoted to current challenges, with subsections on challenges of general nature and those of specific nature. A concluding section gives an outlook on potential future trends and perspectives.</description><subject>Analyzers</subject><subject>Bacterial corrosion</subject><subject>Biomonitoring</subject><subject>Biosensors</subject><subject>Chemical sensors</subject><subject>Crystals</subject><subject>Evanescent waves</subject><subject>Extreme values</subject><subject>Fiber optics</subject><subject>Holography</subject><subject>Interferometry</subject><subject>Microfluidic devices</subject><subject>Nanomaterials</subject><subject>Nanotechnology</subject><subject>Oceanography</subject><subject>Optical fibers</subject><subject>Optics</subject><subject>pH sensors</subject><subject>Photon absorption</subject><subject>Photonic crystals</subject><subject>Physical oceanography</subject><subject>Refractivity</subject><subject>Resonance</subject><subject>Review</subject><subject>Selectivity</subject><subject>Sensors</subject><subject>Surface chemistry</subject><subject>Surface plasmon resonance</subject><subject>Temperature dependence</subject><subject>Transducers</subject><subject>Turbidity</subject><subject>Upconversion</subject><issn>0009-2665</issn><issn>1520-6890</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2020</creationdate><recordtype>article</recordtype><recordid>eNp9kU1rVDEUhoModqz-AkEuuHHhnZ583sSFUIraQksXtW5DbuZkmnK_TO4U_PdmmHFoXXSVE87zvicnLyHvKSwpMHrifF76O-wTPizBAwhJX5AFlQxqpQ28JAsAMDVTSh6RNznfl6uUrHlNjjinohEgF-T2epqjd111g0OOw7pyw6q66N16W4-hms6rX67bYP5S3Uzo5zRmP04R8-fqys2YoutKuRWdTlNXnOY4DvkteRVKA9_tz2Ny-_3bz7Pz-vL6x8XZ6WXtJDdzjeip4RCE4qvAUQkOCE1wq1YhBsNa1NgaxpVpdRu0EkxzGYRkAl0Awfkx-brznTZtjyuPw5xcZ6cUe5f-2NFF-7QzxDu7Hh9s04DURhaDT3uDNP4uW862j9lj17kBx022TMjGNEC1LujH_9D7cZOGsl6hlCp-QtNC8R3ly0_lhOHwGAp2G5stsdl9bHYfW1F9eLzHQfMvpwKc7ICt-jD3Ocu_kRSnDw</recordid><startdate>20201125</startdate><enddate>20201125</enddate><creator>Steinegger, Andreas</creator><creator>Wolfbeis, Otto S</creator><creator>Borisov, Sergey M</creator><general>American Chemical Society</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0002-6124-2842</orcidid><orcidid>https://orcid.org/0000-0001-9318-8273</orcidid></search><sort><creationdate>20201125</creationdate><title>Optical Sensing and Imaging of pH Values: Spectroscopies, Materials, and Applications</title><author>Steinegger, Andreas ; Wolfbeis, Otto S ; Borisov, Sergey M</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-a539t-eec1930f463df3e6430e07fadb6eef92be8eb92369b8bf8642835f4524eaf0433</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2020</creationdate><topic>Analyzers</topic><topic>Bacterial corrosion</topic><topic>Biomonitoring</topic><topic>Biosensors</topic><topic>Chemical sensors</topic><topic>Crystals</topic><topic>Evanescent waves</topic><topic>Extreme values</topic><topic>Fiber optics</topic><topic>Holography</topic><topic>Interferometry</topic><topic>Microfluidic devices</topic><topic>Nanomaterials</topic><topic>Nanotechnology</topic><topic>Oceanography</topic><topic>Optical fibers</topic><topic>Optics</topic><topic>pH sensors</topic><topic>Photon absorption</topic><topic>Photonic crystals</topic><topic>Physical oceanography</topic><topic>Refractivity</topic><topic>Resonance</topic><topic>Review</topic><topic>Selectivity</topic><topic>Sensors</topic><topic>Surface chemistry</topic><topic>Surface plasmon resonance</topic><topic>Temperature dependence</topic><topic>Transducers</topic><topic>Turbidity</topic><topic>Upconversion</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Steinegger, Andreas</creatorcontrib><creatorcontrib>Wolfbeis, Otto S</creatorcontrib><creatorcontrib>Borisov, Sergey M</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Chemical reviews</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Steinegger, Andreas</au><au>Wolfbeis, Otto S</au><au>Borisov, Sergey M</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Optical Sensing and Imaging of pH Values: Spectroscopies, Materials, and Applications</atitle><jtitle>Chemical reviews</jtitle><addtitle>Chem. 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subjects | Analyzers Bacterial corrosion Biomonitoring Biosensors Chemical sensors Crystals Evanescent waves Extreme values Fiber optics Holography Interferometry Microfluidic devices Nanomaterials Nanotechnology Oceanography Optical fibers Optics pH sensors Photon absorption Photonic crystals Physical oceanography Refractivity Resonance Review Selectivity Sensors Surface chemistry Surface plasmon resonance Temperature dependence Transducers Turbidity Upconversion |
title | Optical Sensing and Imaging of pH Values: Spectroscopies, Materials, and Applications |
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