Formate‐Mediated Cross‐Electrophile Reductive Coupling of Aryl Iodides and Bromopyridines

Two catalytic systems for the formate‐mediated cross‐electrophile reductive coupling of aryl iodides with 6‐bromopyridines are described. Using homogenous rhodium or heterogeneous palladium catalysts, the products of reductive biaryl cross‐coupling could be formed in moderate yield with excellent le...

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Bibliographic Details
Published in:Israel journal of chemistry 2021-05, Vol.61 (5-6), p.298-301
Main Authors: Schwartz, Leyah A., Spielmann, Kim, Swyka, Robert A., Xiang, Ming, Krische, Michael J.
Format: Article
Language:English
Subjects:
Aromatic compounds
Cross coupling
cross-electrophile coupling
formate
Iodides
Palladium
reductive coupling
Rhodium
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Summary:Two catalytic systems for the formate‐mediated cross‐electrophile reductive coupling of aryl iodides with 6‐bromopyridines are described. Using homogenous rhodium or heterogeneous palladium catalysts, the products of reductive biaryl cross‐coupling could be formed in moderate yield with excellent levels of chemoselectivity.
ISSN:0021-2148
1869-5868
DOI:10.1002/ijch.202000069