The Influence of the Ceramic Nanoparticles on the Thermoplastic Polymers Matrix: Their Structural, Optical, and Conductive Properties

• Published in: Polymers 2021-08, Vol.13 (16), p.2773
• Main Authors: Smaranda, Ion, Nila, Andreea, Ganea, Paul, Daescu, Monica, Zgura, Irina, Ciobanu, Romeo C., Trandabat, Alexandru, Baibarac, Mihaela
• Format: Article
• Language: English
• Subjects: 3-D printers; Absorbance; Accuracy; Composite materials; Dielectric properties; Dielectric relaxation; Electrical conduction; Flexibility; Geometry; Mechanical properties; Nanoparticles; Olefinic thermoplastic elastomers; Optical properties; Photoluminescence; Polymers; Polyolefins; Polyurethane resins; Spectrum analysis; Strontium titanates; Urethane thermoplastic elastomers
• ISSN: 2073-4360; 2073-4360
• DOI: 10.3390/polym13162773

This paper prepared composites under the free membranes form that are based on thermoplastic polymers of the type of polyurethane (TPU) and polyolefin (TPO), which are blended in the weight ratio of 2:1, and ceramic nanoparticles (CNs) such as BaSrTiO3 and SrTiO3. The structural, optical, and conductive properties of these new composite materials are reported. The X-ray diffraction studies highlight a cubic crystalline structure of these CNs. The main variations in the vibrational properties of the TPU:TPO blend induced by CNs consist of the following: (i) the increase in the intensity of the Raman line of 1616 cm−1; (ii) the down-shift of the IR band from 800 to 791 cm−1; (iii) the change of the ratio between the absorbance of IR bands localized in the spectral range 950–1200 cm−1; and (iv) the decrease in the absorbance of the IR band from 1221 cm−1. All these variations were correlated with a preferential adsorption of thermoplastic polymers on the CNs surface. A photoluminescence (PL) quenching process of thermoplastic polymers is demonstrated to occur in the presence of CNs. The anisotropic PL measurements have highlighted a change in the angle of the binding of the TPU:TPO blend, which varies from 23.7° to ≈49.3° and ≈53.4°, when the concentration of BaSrTiO3 and SrTiO3 CNs, respectively, is changed from 0 to 25 wt. %. Using dielectric spectroscopy, two mechanisms are invoked to take place in the case of the composites based on TPU:TPO blends and CNs, i.e., one regarding the type of the electrical conduction and another specifying the dielectric–dipolar relaxation processes.