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Waste NR Latex Based-Precursors as Carbon Source for CNTs Eco-Fabrications
In this work, the potential of utilizing a waste latex-based precursor (i.e., natural rubber glove (NRG)) as a carbon source for carbon nanotube (CNT) fabrication via chemical vapor deposition has been demonstrated. Gas chromatography-mass spectroscopy (GC-MS) analysis reveals that the separation of...
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Published in: | Polymers 2021-10, Vol.13 (19), p.3409 |
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creator | Hazan, Mohd Adib Chan, Kar Fei Jofri, Khairun Afiqa Mamat, Md Shuhazlly Endot, Nor Azam Liza, Shahira Ismail, Ismayadi Hussein, Mohd Zobir Tanemura, Masaki Yaakob, Yazid |
description | In this work, the potential of utilizing a waste latex-based precursor (i.e., natural rubber glove (NRG)) as a carbon source for carbon nanotube (CNT) fabrication via chemical vapor deposition has been demonstrated. Gas chromatography-mass spectroscopy (GC-MS) analysis reveals that the separation of the lightweight hydrocarbon chain from the heavier long chain differs in hydrocarbon contents in the NRG fraction (NRG-L). Both solid NRG (NRG-S) and NRG-L samples contain >63% carbon, |
doi_str_mv | 10.3390/polym13193409 |
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Gas chromatography-mass spectroscopy (GC-MS) analysis reveals that the separation of the lightweight hydrocarbon chain from the heavier long chain differs in hydrocarbon contents in the NRG fraction (NRG-L). Both solid NRG (NRG-S) and NRG-L samples contain >63% carbon, <0.6% sulfur and <0.08% nitrogen content, respectively, as per carbon-nitrogen-sulfur (CNS) analysis. Growth of CNTs on the samples was confirmed by Raman spectra, SEM and TEM images, whereby it was shown that NRG-S is better than NRG-L in terms of synthesized CNTs yield percentage with similar quality. The optimum vaporization and reaction temperatures were 350 and 800 °C, respectively, considering the balance of good yield percentage (26.7%) and quality of CNTs (ID/IG = 0.84 ± 0.08, diameter ≈ 122 nm) produced. Thus, utilization of waste NRG as a candidate for carbon feedstock to produce value-added CNTs products could be a significant approach for eco-technology.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym13193409</identifier><identifier>PMID: 34641224</identifier><language>eng</language><publisher>Basel: MDPI AG</publisher><subject>Carbon ; Carbon nanotubes ; Chemical vapor deposition ; Chromatography ; Consumption ; COVID-19 ; Decomposition ; Gas chromatography ; Gas flow ; Graphene ; Hydrocarbons ; Laboratories ; Latex ; Microscopy ; Molecular chains ; Natural rubber ; Nitrogen ; Organic chemicals ; Precursors ; Raman spectra ; Raw materials ; Rubber ; Spectrum analysis ; Sulfur ; Vaporization ; Waste utilization</subject><ispartof>Polymers, 2021-10, Vol.13 (19), p.3409</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2021 by the authors. 2021</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c392t-b24bef8e5ae0dc71baeb6960e1df95bd30a1e34067d7b8e041aa70b76231629b3</citedby><cites>FETCH-LOGICAL-c392t-b24bef8e5ae0dc71baeb6960e1df95bd30a1e34067d7b8e041aa70b76231629b3</cites><orcidid>0000-0003-3333-814X ; 0000-0002-0741-261X ; 0000-0001-6691-433X ; 0000-0002-8424-4971</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2580984396?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2580984396?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,25730,27900,27901,36988,36989,38492,43870,44565,53765,53767,74381,75095</link.rule.ids></links><search><creatorcontrib>Hazan, Mohd Adib</creatorcontrib><creatorcontrib>Chan, Kar Fei</creatorcontrib><creatorcontrib>Jofri, Khairun Afiqa</creatorcontrib><creatorcontrib>Mamat, Md Shuhazlly</creatorcontrib><creatorcontrib>Endot, Nor Azam</creatorcontrib><creatorcontrib>Liza, Shahira</creatorcontrib><creatorcontrib>Ismail, Ismayadi</creatorcontrib><creatorcontrib>Hussein, Mohd Zobir</creatorcontrib><creatorcontrib>Tanemura, Masaki</creatorcontrib><creatorcontrib>Yaakob, Yazid</creatorcontrib><title>Waste NR Latex Based-Precursors as Carbon Source for CNTs Eco-Fabrications</title><title>Polymers</title><description>In this work, the potential of utilizing a waste latex-based precursor (i.e., natural rubber glove (NRG)) as a carbon source for carbon nanotube (CNT) fabrication via chemical vapor deposition has been demonstrated. Gas chromatography-mass spectroscopy (GC-MS) analysis reveals that the separation of the lightweight hydrocarbon chain from the heavier long chain differs in hydrocarbon contents in the NRG fraction (NRG-L). Both solid NRG (NRG-S) and NRG-L samples contain >63% carbon, <0.6% sulfur and <0.08% nitrogen content, respectively, as per carbon-nitrogen-sulfur (CNS) analysis. Growth of CNTs on the samples was confirmed by Raman spectra, SEM and TEM images, whereby it was shown that NRG-S is better than NRG-L in terms of synthesized CNTs yield percentage with similar quality. The optimum vaporization and reaction temperatures were 350 and 800 °C, respectively, considering the balance of good yield percentage (26.7%) and quality of CNTs (ID/IG = 0.84 ± 0.08, diameter ≈ 122 nm) produced. Thus, utilization of waste NRG as a candidate for carbon feedstock to produce value-added CNTs products could be a significant approach for eco-technology.</description><subject>Carbon</subject><subject>Carbon nanotubes</subject><subject>Chemical vapor deposition</subject><subject>Chromatography</subject><subject>Consumption</subject><subject>COVID-19</subject><subject>Decomposition</subject><subject>Gas chromatography</subject><subject>Gas flow</subject><subject>Graphene</subject><subject>Hydrocarbons</subject><subject>Laboratories</subject><subject>Latex</subject><subject>Microscopy</subject><subject>Molecular chains</subject><subject>Natural rubber</subject><subject>Nitrogen</subject><subject>Organic chemicals</subject><subject>Precursors</subject><subject>Raman spectra</subject><subject>Raw materials</subject><subject>Rubber</subject><subject>Spectrum analysis</subject><subject>Sulfur</subject><subject>Vaporization</subject><subject>Waste utilization</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>COVID</sourceid><sourceid>PIMPY</sourceid><recordid>eNpdkctLxDAQxoMoKurRe8CLl2peTZuLoMv6YlHxgccwSada6TZr0or-93ZRRJ3LDMyPj_nmI2SXswMpDTtchPZjziU3UjGzQjYFK2SmpGarv-YNspPSCxtL5VrzYp1sSKUVF0JtkstHSD3Sq1s6gx7f6QkkrLKbiH6IKcREIdEJRBc6eheG6JHWIdLJ1X2iUx-yU3Cx8dA3oUvbZK2GNuHOd98iD6fT-8l5Nrs-u5gczzIvjegzJ5TDusQckFW-4A7QaaMZ8qo2uaskA46jH11UhSuRKQ5QMFdoIbkWxsktcvSluxjcHCuPXR-htYvYzCF-2ACN_bvpmmf7FN5smXOheD4K7H8LxPA6YOrtvEke2xY6DEOyIi95yZTQS3TvH_oyfqEb7S0pZkoljR6p7IvyMaQUsf45hjO7DMr-CUp-AgArhKE</recordid><startdate>20211004</startdate><enddate>20211004</enddate><creator>Hazan, Mohd Adib</creator><creator>Chan, Kar Fei</creator><creator>Jofri, Khairun Afiqa</creator><creator>Mamat, Md Shuhazlly</creator><creator>Endot, Nor Azam</creator><creator>Liza, Shahira</creator><creator>Ismail, Ismayadi</creator><creator>Hussein, Mohd Zobir</creator><creator>Tanemura, Masaki</creator><creator>Yaakob, Yazid</creator><general>MDPI AG</general><general>MDPI</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>COVID</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PHGZM</scope><scope>PHGZT</scope><scope>PIMPY</scope><scope>PKEHL</scope><scope>PQEST</scope><scope>PQGLB</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-3333-814X</orcidid><orcidid>https://orcid.org/0000-0002-0741-261X</orcidid><orcidid>https://orcid.org/0000-0001-6691-433X</orcidid><orcidid>https://orcid.org/0000-0002-8424-4971</orcidid></search><sort><creationdate>20211004</creationdate><title>Waste NR Latex Based-Precursors as Carbon Source for CNTs Eco-Fabrications</title><author>Hazan, Mohd Adib ; 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Gas chromatography-mass spectroscopy (GC-MS) analysis reveals that the separation of the lightweight hydrocarbon chain from the heavier long chain differs in hydrocarbon contents in the NRG fraction (NRG-L). Both solid NRG (NRG-S) and NRG-L samples contain >63% carbon, <0.6% sulfur and <0.08% nitrogen content, respectively, as per carbon-nitrogen-sulfur (CNS) analysis. Growth of CNTs on the samples was confirmed by Raman spectra, SEM and TEM images, whereby it was shown that NRG-S is better than NRG-L in terms of synthesized CNTs yield percentage with similar quality. The optimum vaporization and reaction temperatures were 350 and 800 °C, respectively, considering the balance of good yield percentage (26.7%) and quality of CNTs (ID/IG = 0.84 ± 0.08, diameter ≈ 122 nm) produced. 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subjects | Carbon Carbon nanotubes Chemical vapor deposition Chromatography Consumption COVID-19 Decomposition Gas chromatography Gas flow Graphene Hydrocarbons Laboratories Latex Microscopy Molecular chains Natural rubber Nitrogen Organic chemicals Precursors Raman spectra Raw materials Rubber Spectrum analysis Sulfur Vaporization Waste utilization |
title | Waste NR Latex Based-Precursors as Carbon Source for CNTs Eco-Fabrications |
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