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Chiral Nematic Cellulose Nanocrystal Films Cooperated with Amino Acids for Tunable Optical Properties
The exploration of functional materials relies greatly on the understanding of material structures and nanotechnologies. In the present work, chiral nematic cellulose nanocrystal (CNC) films were prepared by incorporation with four types of amino acids (AAs, glycine, histidine, phenylalanine, and se...
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| Published in: | Polymers 2021-12, Vol.13 (24), p.4389 |
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| Main Authors: | , , , , , , |
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| cites | cdi_FETCH-LOGICAL-c415t-7309648aa1403fd5fa2528409eedd62ea4107d19854a526b04d5dd77a28c3a3d3 |
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| container_issue | 24 |
| container_start_page | 4389 |
| container_title | Polymers |
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| creator | Xiao, Xiao Chen, Jie Ling, Zhe Guo, Jiaqi Huang, Jianbin Ma, Jianfeng Jin, Zhi |
| description | The exploration of functional materials relies greatly on the understanding of material structures and nanotechnologies. In the present work, chiral nematic cellulose nanocrystal (CNC) films were prepared by incorporation with four types of amino acids (AAs, glycine, histidine, phenylalanine, and serine) via evaporation-induced self-assembly. The films present ideal iridescence and birefringence that can be tuned by the amount of AAs added. The intercalation of AAs enlarged the pitch values, contributing to the red-shift trend of the reflective wavelength. Among the AAs, serine presented the most compatible intercalation into cellulose crystals. Interestingly, histidine and phenylalanine composite films showed high shielding capabilities of UV light in diverse wavelength regions, exhibiting multi-optical functions. The sustainable preparation of chiral nematic CNC films may provide new strategies for materials production from biocompatible lignocellulose. |
| doi_str_mv | 10.3390/polym13244389 |
| format | article |
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In the present work, chiral nematic cellulose nanocrystal (CNC) films were prepared by incorporation with four types of amino acids (AAs, glycine, histidine, phenylalanine, and serine) via evaporation-induced self-assembly. The films present ideal iridescence and birefringence that can be tuned by the amount of AAs added. The intercalation of AAs enlarged the pitch values, contributing to the red-shift trend of the reflective wavelength. Among the AAs, serine presented the most compatible intercalation into cellulose crystals. Interestingly, histidine and phenylalanine composite films showed high shielding capabilities of UV light in diverse wavelength regions, exhibiting multi-optical functions. The sustainable preparation of chiral nematic CNC films may provide new strategies for materials production from biocompatible lignocellulose.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym13244389</identifier><identifier>PMID: 34960940</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Amino acids ; Biocompatibility ; Birefringence ; Cellulose ; Color ; Doppler effect ; Functional materials ; Glucose ; Glycine ; Histidine ; Intercalation ; Iridescence ; Light ; Lignocellulose ; Mechanical properties ; Microscopy ; Nanocrystals ; Nanoparticles ; Optical properties ; Phenylalanine ; Red shift ; Self-assembly ; Shielding ; Trends ; Ultraviolet radiation</subject><ispartof>Polymers, 2021-12, Vol.13 (24), p.4389</ispartof><rights>2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). 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The sustainable preparation of chiral nematic CNC films may provide new strategies for materials production from biocompatible lignocellulose.</description><subject>Amino acids</subject><subject>Biocompatibility</subject><subject>Birefringence</subject><subject>Cellulose</subject><subject>Color</subject><subject>Doppler effect</subject><subject>Functional materials</subject><subject>Glucose</subject><subject>Glycine</subject><subject>Histidine</subject><subject>Intercalation</subject><subject>Iridescence</subject><subject>Light</subject><subject>Lignocellulose</subject><subject>Mechanical properties</subject><subject>Microscopy</subject><subject>Nanocrystals</subject><subject>Nanoparticles</subject><subject>Optical properties</subject><subject>Phenylalanine</subject><subject>Red shift</subject><subject>Self-assembly</subject><subject>Shielding</subject><subject>Trends</subject><subject>Ultraviolet radiation</subject><issn>2073-4360</issn><issn>2073-4360</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2021</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><recordid>eNpdkc1LxDAQxYMorqhHrxLw4qWar6btRViKXyC7HvQcss3UzdI2NWmV_e_N4rqouUxgfvOYNw-hM0quOC_Ide-adUs5E4LnxR46YiTjieCS7P_6T9BpCCsSn0ilpNkhmnBRSFIIcoSgXFqvGzyDVg-2wiU0zdi4AHimO1f5dRhi9842bcClcz14PYDBn3ZY4mlrO4enlTUB187jl7HTiwbwvI9KcerZb_jBQjhBB7VuApxu6zF6vbt9KR-Sp_n9Yzl9SipB0yHJOCmkyLWmgvDapLVmKcsFKQCMkQy0oCQztMhToVMmF0SY1Jgs0yyvuOaGH6Obb91-XLRgKuiGaE713rbar5XTVv3tdHap3tyHyjOS55mIApdbAe_eRwiDam2o4k10B24MikmaUkqoJBG9-Ieu3Oi7aG9DxbWZLFikkm-q8i4ED_VuGUrUJkP1J8PIn_92sKN_EuNfXc-Yvw</recordid><startdate>20211215</startdate><enddate>20211215</enddate><creator>Xiao, Xiao</creator><creator>Chen, Jie</creator><creator>Ling, Zhe</creator><creator>Guo, Jiaqi</creator><creator>Huang, Jianbin</creator><creator>Ma, Jianfeng</creator><creator>Jin, Zhi</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20211215</creationdate><title>Chiral Nematic Cellulose Nanocrystal Films Cooperated with Amino Acids for Tunable Optical Properties</title><author>Xiao, Xiao ; 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| subjects | Amino acids Biocompatibility Birefringence Cellulose Color Doppler effect Functional materials Glucose Glycine Histidine Intercalation Iridescence Light Lignocellulose Mechanical properties Microscopy Nanocrystals Nanoparticles Optical properties Phenylalanine Red shift Self-assembly Shielding Trends Ultraviolet radiation |
| title | Chiral Nematic Cellulose Nanocrystal Films Cooperated with Amino Acids for Tunable Optical Properties |
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