Immobilization of Air-Stable Copper Nanoparticles on Graphene Oxide Flexible Hybrid Films for Smart Clothes

Through the use of organic/inorganic hybrid dispersants-which are composed of polymeric dispersant and two-dimension nanomaterial graphene oxide (GO)-copper nanoparticles (CuNPs) were found to exhibit nano stability, air-stable characteristics, as well as long-term conductive stability. The polymeri...

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Published in:Polymers 2022-01, Vol.14 (2), p.237
Main Authors: Huang, Peng-Yang, Huang, Chen-Yang, Li, Jia-Wun, Shen, Sheng-Yen, Cheng, Chih-Chia, Chiu, Chih-Wei, Jeng, Ru-Jong, Lin, Jiang-Jen
Format: Article
Language:English
Subjects:
Anhydrides
Antioxidants
Carbon
Chemical reduction
Composite materials
Copper
Dispersants
Dispersion
Electrocardiography
Electrodes
Esters
Graphene
Nanomaterials
Nanoparticles
Oxidation
Particle size
Physiology
Polyethylene glycol
Polyoxyethylene
Redox reactions
Silver
Skin
Spectrum analysis
Stability
Stabilizers (agents)
Surfactants
Wearable computers
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cited_by cdi_FETCH-LOGICAL-c415t-aadaf7e61e372a6f7b912098bec7cf3cf75d120b9513beb6bb6099f69d2821b63
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container_title Polymers
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creator Huang, Peng-Yang
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Li, Jia-Wun
Shen, Sheng-Yen
Cheng, Chih-Chia
Chiu, Chih-Wei
Jeng, Ru-Jong
Lin, Jiang-Jen
description Through the use of organic/inorganic hybrid dispersants-which are composed of polymeric dispersant and two-dimension nanomaterial graphene oxide (GO)-copper nanoparticles (CuNPs) were found to exhibit nano stability, air-stable characteristics, as well as long-term conductive stability. The polymeric dispersant consists of branched poly(oxyethylene)-segmented esters of trimellitic anhydride adduct (polyethylene glycol-trimethylolpropane-trimellitic anhydride, designated as PTT). PTT acts as a stabilizer for CuNPs, which are synthesized via in situ polymerization and redox reaction of the precursor Cu(CH COO) within an aqueous system, and use graphene oxide to avoid the reduction reaction of CuNPs. The results show that after 30 days of storage the CuNPs/PTT/GO composite film maintains a highly conductive network (9.06 × 10 Ω/sq). These results indicate that organic/inorganic PTT/GO hybrid dispersants can effectively maintain the conductivity stability of CuNPs and address the problem of CuNP oxidation. Finally, the new CuNPs/PTT/GO composite film was applied to the electrocardiogram (ECG) smart clothes. This way, a stable and antioxidant-sensing electrode can be produced, which is expected to serve as a long-term ECG monitoring device.
doi_str_mv 10.3390/polym14020237
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This way, a stable and antioxidant-sensing electrode can be produced, which is expected to serve as a long-term ECG monitoring device.</description><identifier>ISSN: 2073-4360</identifier><identifier>EISSN: 2073-4360</identifier><identifier>DOI: 10.3390/polym14020237</identifier><identifier>PMID: 35054646</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Anhydrides ; Antioxidants ; Carbon ; Chemical reduction ; Composite materials ; Copper ; Dispersants ; Dispersion ; Electrocardiography ; Electrodes ; Esters ; Graphene ; Nanomaterials ; Nanoparticles ; Oxidation ; Particle size ; Physiology ; Polyethylene glycol ; Polyoxyethylene ; Redox reactions ; Silver ; Skin ; Spectrum analysis ; Stability ; Stabilizers (agents) ; Surfactants ; Wearable computers</subject><ispartof>Polymers, 2022-01, Vol.14 (2), p.237</ispartof><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. 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subjects Anhydrides
Antioxidants
Carbon
Chemical reduction
Composite materials
Copper
Dispersants
Dispersion
Electrocardiography
Electrodes
Esters
Graphene
Nanomaterials
Nanoparticles
Oxidation
Particle size
Physiology
Polyethylene glycol
Polyoxyethylene
Redox reactions
Silver
Skin
Spectrum analysis
Stability
Stabilizers (agents)
Surfactants
Wearable computers
title Immobilization of Air-Stable Copper Nanoparticles on Graphene Oxide Flexible Hybrid Films for Smart Clothes
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