3-Methyl-1,2,3-triazolium-1N-dinitromethylylide and the strategy of zwitterionic dinitromethyl groups in energetic materials design

3-Methyl-1,2,3-triazolium-1N-dinitromethylylide, an exemplary zwitterionic energetic molecule, is the first fully-studied energetic material making use of the zwitterionic dinitromethyl functional group. This compound has impact and friction sensitivities of 8 J and 144–160 N respectively with a det...

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Bibliographic Details
Published in:RSC advances 2021-05, Vol.11 (29), p.17710-17714
Main Authors: Wozniak, Dominique R, Zeller, Matthias, Byrd, Edward F C, Piercey, Davin G
Format: Article
Language:English
Subjects:
Chemistry
Crystallography
Detonation
Energetic materials
Functional groups
NMR
Nuclear magnetic resonance
Zwitterions
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Summary:3-Methyl-1,2,3-triazolium-1N-dinitromethylylide, an exemplary zwitterionic energetic molecule, is the first fully-studied energetic material making use of the zwitterionic dinitromethyl functional group. This compound has impact and friction sensitivities of 8 J and 144–160 N respectively with a detonation velocity of 8162 m s−1.
ISSN:2046-2069
DOI:10.1039/d1ra00953b