Synergetic catalysis of a cobalt-based coordination polymer for selective visible-light driven CO2-to-CO conversion

Herein, based on the strategy of synergetic catalysis, we report a cobalt-based coordination polymer PEI6-Co. As a heterogeneous catalyst, PEI6-Co shows a selectivity of 95% and a yield of 1170 mmol g−1 for visible-light-driven CO2-to-CO conversion in a water containing system, which is almost 2.8 t...

Full description

Saved in:
Bibliographic Details
Published in:RSC advances 2020-05, Vol.10 (31), p.17951-17954
Main Authors: Sheng-Jie, Li, Yong-Bin, Chang, Li, Ming, You-Xiang, Feng, Zhang, Wen
Format: Article
Language:English
Subjects:
Absorption spectra
Carbon dioxide
Carbon monoxide
Catalysis
Catalysts
Chemistry
Cobalt
Conversion
Coordination polymers
Selectivity
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Herein, based on the strategy of synergetic catalysis, we report a cobalt-based coordination polymer PEI6-Co. As a heterogeneous catalyst, PEI6-Co shows a selectivity of 95% and a yield of 1170 mmol g−1 for visible-light-driven CO2-to-CO conversion in a water containing system, which is almost 2.8 times that of the mononuclear cobalt catalyst CoL1 and is comparable to that of the dinuclear cobalt catalyst Co2L.
ISSN:2046-2069
DOI:10.1039/c9ra10962e