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In situ autologous growth of self-supporting NiFe-based nanosheets on nickel foam as an efficient electrocatalyst for the oxygen evolution reaction
A highly efficient and low-cost oxygen evolution reaction electrocatalyst is essential for water splitting. Herein, a simple and cost-effective autologous growth method is developed to prepare NiFe-based integrated electrodes for water oxidation. In this method, a Ni(OH) nanosheet film is first deve...
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Published in: | RSC advances 2019-07, Vol.9 (38), p.21679-21684 |
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creator | Wang, Jianying Teng, Xue Niu, Yanli Guo, Lixia Kong, Jianfei He, Xiaoming Chen, Zuofeng |
description | A highly efficient and low-cost oxygen evolution reaction electrocatalyst is essential for water splitting. Herein, a simple and cost-effective autologous growth method is developed to prepare NiFe-based integrated electrodes for water oxidation. In this method, a Ni(OH)
nanosheet film is first developed on nickel foam by oxidative deposition in a chemical bath solution. The as-prepared nanosheet electrode is then immersed into a solution containing Fe(iii) cations to form an Fe-doped Ni(OH)
electrode by utilization of the different solubility of metal cations. Benefiting from its unique and integrated nanostructure, this hierarchically structured electrode displays extremely high catalytic activity toward water oxidation. In 1 M KOH, the electrode can deliver a current density of 1000 mA cm
at an overpotential of only 330 mV. This work provides a facile way to produce an efficient, durable, and Earth-abundant OER electrocatalyst with no energy input, which is attractive for large-scale water splitting. |
doi_str_mv | 10.1039/c9ra04368c |
format | article |
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nanosheet film is first developed on nickel foam by oxidative deposition in a chemical bath solution. The as-prepared nanosheet electrode is then immersed into a solution containing Fe(iii) cations to form an Fe-doped Ni(OH)
electrode by utilization of the different solubility of metal cations. Benefiting from its unique and integrated nanostructure, this hierarchically structured electrode displays extremely high catalytic activity toward water oxidation. In 1 M KOH, the electrode can deliver a current density of 1000 mA cm
at an overpotential of only 330 mV. This work provides a facile way to produce an efficient, durable, and Earth-abundant OER electrocatalyst with no energy input, which is attractive for large-scale water splitting.</description><identifier>ISSN: 2046-2069</identifier><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/c9ra04368c</identifier><identifier>PMID: 35518845</identifier><language>eng</language><publisher>England: Royal Society of Chemistry</publisher><subject>Catalysis ; Catalytic activity ; Cations ; Chemistry ; Electrodes ; Intermetallic compounds ; Iron compounds ; Metal foams ; Nanosheets ; Nanostructure ; Nickel compounds ; Organic chemistry ; Oxidation ; Oxygen evolution reactions ; Water splitting</subject><ispartof>RSC advances, 2019-07, Vol.9 (38), p.21679-21684</ispartof><rights>This journal is © The Royal Society of Chemistry.</rights><rights>Copyright Royal Society of Chemistry 2019</rights><rights>This journal is © The Royal Society of Chemistry 2019 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c406t-93af99e375d1d5e09d66cdc2f2ca8e62fcce4fa2453b59306ec8c08f32edfbfc3</citedby><cites>FETCH-LOGICAL-c406t-93af99e375d1d5e09d66cdc2f2ca8e62fcce4fa2453b59306ec8c08f32edfbfc3</cites><orcidid>0000-0003-2596-7042 ; 0000-0002-2376-2150</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066415/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9066415/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,723,776,780,881,27903,27904,53769,53771</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35518845$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Wang, Jianying</creatorcontrib><creatorcontrib>Teng, Xue</creatorcontrib><creatorcontrib>Niu, Yanli</creatorcontrib><creatorcontrib>Guo, Lixia</creatorcontrib><creatorcontrib>Kong, Jianfei</creatorcontrib><creatorcontrib>He, Xiaoming</creatorcontrib><creatorcontrib>Chen, Zuofeng</creatorcontrib><title>In situ autologous growth of self-supporting NiFe-based nanosheets on nickel foam as an efficient electrocatalyst for the oxygen evolution reaction</title><title>RSC advances</title><addtitle>RSC Adv</addtitle><description>A highly efficient and low-cost oxygen evolution reaction electrocatalyst is essential for water splitting. Herein, a simple and cost-effective autologous growth method is developed to prepare NiFe-based integrated electrodes for water oxidation. In this method, a Ni(OH)
nanosheet film is first developed on nickel foam by oxidative deposition in a chemical bath solution. The as-prepared nanosheet electrode is then immersed into a solution containing Fe(iii) cations to form an Fe-doped Ni(OH)
electrode by utilization of the different solubility of metal cations. Benefiting from its unique and integrated nanostructure, this hierarchically structured electrode displays extremely high catalytic activity toward water oxidation. In 1 M KOH, the electrode can deliver a current density of 1000 mA cm
at an overpotential of only 330 mV. This work provides a facile way to produce an efficient, durable, and Earth-abundant OER electrocatalyst with no energy input, which is attractive for large-scale water splitting.</description><subject>Catalysis</subject><subject>Catalytic activity</subject><subject>Cations</subject><subject>Chemistry</subject><subject>Electrodes</subject><subject>Intermetallic compounds</subject><subject>Iron compounds</subject><subject>Metal foams</subject><subject>Nanosheets</subject><subject>Nanostructure</subject><subject>Nickel compounds</subject><subject>Organic chemistry</subject><subject>Oxidation</subject><subject>Oxygen evolution reactions</subject><subject>Water splitting</subject><issn>2046-2069</issn><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2019</creationdate><recordtype>article</recordtype><recordid>eNpdkV1rFTEQhhex2NL2xh8gAW9E2DYfuzmbG6EcrBZKBdHrkDM72ZOakxyTbOv5Hf5hU_tBdW5mYB5e3pm3aV4zesKoUKegkqGdkAO8aA447WTLqVQvn837zXHO17SW7BmX7FWzL_qeDUPXHzS_LwLJrszEzCX6OMU5kynF27Im0ZKM3rZ53m5jKi5M5MqdY7syGUcSTIh5jVgyiYEEBz_QExvNhphMTCBorQOHoRD0CCVFMMX4XS4VSqSskcRfuwkreBP9XFwVSWjgbjhq9qzxGY8f-mHz_fzjt-Xn9vLLp4vl2WULHZWlVcJYpVAs-pGNPVI1SgkjcMvBDCi5BcDOGt71YtUrQSXCAHSwguNoVxbEYfPhXnc7rzY4QjWbjNfb5DYm7XQ0Tv-7CW6tp3ijFZWyY30VePcgkOLPGXPRG5cBvTcB6yM1l5LRxUIOrKJv_0Ov45xCPU9zXt0xKQZeqff3FKSYc0L7ZIZRfRe3XqqvZ3_jXlb4zXP7T-hjuOIP3xyqaA</recordid><startdate>20190712</startdate><enddate>20190712</enddate><creator>Wang, Jianying</creator><creator>Teng, Xue</creator><creator>Niu, Yanli</creator><creator>Guo, Lixia</creator><creator>Kong, Jianfei</creator><creator>He, Xiaoming</creator><creator>Chen, Zuofeng</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0003-2596-7042</orcidid><orcidid>https://orcid.org/0000-0002-2376-2150</orcidid></search><sort><creationdate>20190712</creationdate><title>In situ autologous growth of self-supporting NiFe-based nanosheets on nickel foam as an efficient electrocatalyst for the oxygen evolution reaction</title><author>Wang, Jianying ; Teng, Xue ; Niu, Yanli ; Guo, Lixia ; Kong, Jianfei ; He, Xiaoming ; Chen, Zuofeng</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c406t-93af99e375d1d5e09d66cdc2f2ca8e62fcce4fa2453b59306ec8c08f32edfbfc3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2019</creationdate><topic>Catalysis</topic><topic>Catalytic activity</topic><topic>Cations</topic><topic>Chemistry</topic><topic>Electrodes</topic><topic>Intermetallic compounds</topic><topic>Iron compounds</topic><topic>Metal foams</topic><topic>Nanosheets</topic><topic>Nanostructure</topic><topic>Nickel compounds</topic><topic>Organic chemistry</topic><topic>Oxidation</topic><topic>Oxygen evolution reactions</topic><topic>Water splitting</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Wang, Jianying</creatorcontrib><creatorcontrib>Teng, Xue</creatorcontrib><creatorcontrib>Niu, Yanli</creatorcontrib><creatorcontrib>Guo, Lixia</creatorcontrib><creatorcontrib>Kong, Jianfei</creatorcontrib><creatorcontrib>He, Xiaoming</creatorcontrib><creatorcontrib>Chen, Zuofeng</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Wang, Jianying</au><au>Teng, Xue</au><au>Niu, Yanli</au><au>Guo, Lixia</au><au>Kong, Jianfei</au><au>He, Xiaoming</au><au>Chen, Zuofeng</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>In situ autologous growth of self-supporting NiFe-based nanosheets on nickel foam as an efficient electrocatalyst for the oxygen evolution reaction</atitle><jtitle>RSC advances</jtitle><addtitle>RSC Adv</addtitle><date>2019-07-12</date><risdate>2019</risdate><volume>9</volume><issue>38</issue><spage>21679</spage><epage>21684</epage><pages>21679-21684</pages><issn>2046-2069</issn><eissn>2046-2069</eissn><abstract>A highly efficient and low-cost oxygen evolution reaction electrocatalyst is essential for water splitting. Herein, a simple and cost-effective autologous growth method is developed to prepare NiFe-based integrated electrodes for water oxidation. In this method, a Ni(OH)
nanosheet film is first developed on nickel foam by oxidative deposition in a chemical bath solution. The as-prepared nanosheet electrode is then immersed into a solution containing Fe(iii) cations to form an Fe-doped Ni(OH)
electrode by utilization of the different solubility of metal cations. Benefiting from its unique and integrated nanostructure, this hierarchically structured electrode displays extremely high catalytic activity toward water oxidation. In 1 M KOH, the electrode can deliver a current density of 1000 mA cm
at an overpotential of only 330 mV. This work provides a facile way to produce an efficient, durable, and Earth-abundant OER electrocatalyst with no energy input, which is attractive for large-scale water splitting.</abstract><cop>England</cop><pub>Royal Society of Chemistry</pub><pmid>35518845</pmid><doi>10.1039/c9ra04368c</doi><tpages>6</tpages><orcidid>https://orcid.org/0000-0003-2596-7042</orcidid><orcidid>https://orcid.org/0000-0002-2376-2150</orcidid><oa>free_for_read</oa></addata></record> |
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subjects | Catalysis Catalytic activity Cations Chemistry Electrodes Intermetallic compounds Iron compounds Metal foams Nanosheets Nanostructure Nickel compounds Organic chemistry Oxidation Oxygen evolution reactions Water splitting |
title | In situ autologous growth of self-supporting NiFe-based nanosheets on nickel foam as an efficient electrocatalyst for the oxygen evolution reaction |
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