The construction of a two-dimensional organic–inorganic hybrid double perovskite ferroelastic with a high Tc and narrow band gap

• Published in: Chemical science (Cambridge) 2022-05, Vol.13 (17), p.4794-4800
• Main Authors: Chang-Yuan, Su, Ye-Feng, Yao, Zhi-Xu, Zhang, Wang, Ying, Chen, Ming, Pei-Zhi Huang, Zhang, Yi, Wen-Cheng, Qiao, Da-Wei, Fu
• Format: Article
• Language: English
• Subjects: Chain dynamics; Chemistry; Curie temperature; Energy gap; Ferroelectricity; Lead free; Microprocessors; Molecular motion; NMR; Nuclear magnetic resonance; Perovskites; Phase transitions; Physical properties; Shape memory; Single crystals; Switches; Temperature dependence
• ISSN: 2041-6520; 2041-6539
• DOI: 10.1039/d1sc07045b

Two-dimensional (2D) hybrid double perovskites have attracted extensive research interest for their fascinating physical properties, such as ferroelectricity, X-ray detection, light response and so on. In addition, ferroelastics, as an important branch of ferroic materials, exhibits wide prospects in mechanical switches, shape memory and templating electronic nanostructures. Here, we designed a 2D phase-transition double perovskite ferroelastic through a structurally progressive strategy. This evolution is core to our construction process from 0D to 1D and AgBi-based 2D. In this way, we successfully synthesized 2D lead-free ferroelastic (DPA)4AgBiBr8 (DPA = 2,2-dimethylpropan-1-aminium) with a high Curie temperature (Tc), which shows a narrower band gap than 0D (DPA)4Bi2Br10 and 1D (DPA)5Pb2Br9. Moreover, the mechanism of structural phase transition and molecular motion are fully characterized by temperature dependent solid-state NMR and single crystal XRD. (DPA)4AgBiBr8 injects power into the discovery of new ferroelastics or the construction and dimensional adjustment in new hybrid double perovskites.