Sodium borohydride-nickel chloride hexahydrate in EtOH/PEG-400 as an efficient and recyclable catalytic system for the reduction of alkenes

An efficient, safe and one-pot convenient catalytic system has been developed for the reduction of alkenes using NaBH 4 -NiCl 2 ·6H 2 O in EtOH/PEG-400 under mild conditions. In this catalytic system, a variety of alkenes (including trisubstituted alkene α-pinene) were well reduced and the Ni cataly...

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Bibliographic Details
Published in:RSC advances 2018-01, Vol.8 (14), p.7761-7764
Main Authors: Li, Kaoxue, Liu, Chuanchao, Wang, Kang, Ren, Yang, Li, Fahui
Format: Article
Language:English
Subjects:
Alkenes
Catalysis
Chemistry
Metal chlorides
Nickel chloride
Nickel compounds
Reduction
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Summary:An efficient, safe and one-pot convenient catalytic system has been developed for the reduction of alkenes using NaBH 4 -NiCl 2 ·6H 2 O in EtOH/PEG-400 under mild conditions. In this catalytic system, a variety of alkenes (including trisubstituted alkene α-pinene) were well reduced and the Ni catalyst could be recycled. An efficient, safe and one-pot convenient catalytic system has been developed for the reduction of alkenes using NaBH 4 -NiCl 2 ·6H 2 O in EtOH/PEG-400 under mild conditions.
ISSN:2046-2069
2046-2069
DOI:10.1039/c8ra00905h