A short review of recent advances in CO2 hydrogenation to hydrocarbons over heterogeneous catalysts

CO2 hydrogenation to hydrocarbons is a promising way of making waste to wealth and energy storage, which also solves the environmental and energy issues caused by CO2 emissions. Much efforts and research are aimed at the conversion of CO2via hydrogenation to various value-added hydrocarbons, such as...

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Bibliographic Details
Published in:RSC advances 2018-01, Vol.8 (14), p.7651-7669
Main Authors: Li, Wenhui, Wang, Haozhi, Jiang, Xiao, Zhu, Jie, Liu, Zhongmin, Guo, Xinwen, Song, Chunshan
Format: Article
Language:English
Subjects:
Alkenes
Carbon dioxide
Catalysis
Catalysts
Chemistry
Conversion
Density functional theory
Energy storage
Gasoline
Hydrocarbons
Hydrogenation
Reaction mechanisms
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Summary:CO2 hydrogenation to hydrocarbons is a promising way of making waste to wealth and energy storage, which also solves the environmental and energy issues caused by CO2 emissions. Much efforts and research are aimed at the conversion of CO2via hydrogenation to various value-added hydrocarbons, such as CH4, lower olefins, gasoline, or long-chain hydrocarbons catalyzed by different catalysts with various mechanisms. This review provides an overview of advances in CO2 hydrogenation to hydrocarbons that have been achieved recently in terms of catalyst design, catalytic performance and reaction mechanism from both experiments and density functional theory calculations. In addition, the factors influencing the performance of catalysts and the first C–C coupling mechanism through different routes are also revealed. The fundamental factor for product selectivity is the surface H/C ratio adjusted by active metals, supports and promoters. Furthermore, the technical and application challenges of CO2 conversion into useful fuels/chemicals are also summarized. To meet these challenges, future research directions are proposed in this review.
ISSN:2046-2069
2046-2069
DOI:10.1039/c7ra13546g