XPS Study on Calcining Mixtures of Brucite with Titania

In this work, we studied the phases in a Mg-Ti-O system using a 1:1 formulation of MgO:TiO , mixing synthetic brucite of Mexican origin with TiO microparticles of high purity, with a heat treatment at 1100 °C for 1 h. Due to its valence electrons, TiO can contribute to the sintering process to impro...

Full description

Saved in:
Bibliographic Details
Published in:Materials 2022-04, Vol.15 (9), p.3117
Main Authors: Sánchez-Zambrano, Karla Sofía, Hernández-Reséndiz, Marina, Gómez-Rodríguez, Cristian, García-Quiñonez, Linda Viviana, Aguilar-Martínez, Josué Amilcar, Rodríguez-Castellanos, Edén Amaral, Verdeja, Luis Felipe, Fernández-González, Daniel, Castillo-Rodríguez, Guadalupe Alan
Format: Article
Language:English
Subjects:
Aqueous solutions
Brucite
Chemical reactions
Crystal lattices
Cubic lattice
Heat treatment
High temperature
Lattice vacancies
Magnesium hydroxide
Magnesium oxide
Microparticles
Nanoparticles
Oxidation
Phase diagrams
Raw materials
Roasting
Thermodynamic properties
Titanium
Titanium dioxide
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by cdi_FETCH-LOGICAL-c336t-cebea08d7f50d933e7f1de178205d9b7a322296f154964e63b1fa6334ccd9b893
cites cdi_FETCH-LOGICAL-c336t-cebea08d7f50d933e7f1de178205d9b7a322296f154964e63b1fa6334ccd9b893
container_end_page
container_issue 9
container_start_page 3117
container_title Materials
container_volume 15
creator Sánchez-Zambrano, Karla Sofía
Hernández-Reséndiz, Marina
Gómez-Rodríguez, Cristian
García-Quiñonez, Linda Viviana
Aguilar-Martínez, Josué Amilcar
Rodríguez-Castellanos, Edén Amaral
Verdeja, Luis Felipe
Fernández-González, Daniel
Castillo-Rodríguez, Guadalupe Alan
description In this work, we studied the phases in a Mg-Ti-O system using a 1:1 formulation of MgO:TiO , mixing synthetic brucite of Mexican origin with TiO microparticles of high purity, with a heat treatment at 1100 °C for 1 h. Due to its valence electrons, TiO can contribute to the sintering process to improve density in MgO products. The raw materials and formulation by XPS and X-RD techniques were characterized. The results demonstrate the presence of different oxidation states in titania and the formation of different oxides in the Mg-Ti-O system when mixed and calcined at 1100 °C; additionally, we estimated the formation of vacancies in the crystal lattice during the transformation from hexagonal brucite to magnesia with a cubic structure centered on the faces. Its thermal behavior is indicated by the MgO-TiO phase diagram.
doi_str_mv 10.3390/ma15093117
format article
fullrecord <record><control><sourceid>proquest_pubme</sourceid><recordid>TN_cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9100921</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>2667795106</sourcerecordid><originalsourceid>FETCH-LOGICAL-c336t-cebea08d7f50d933e7f1de178205d9b7a322296f154964e63b1fa6334ccd9b893</originalsourceid><addsrcrecordid>eNpdkV9LwzAUxYMobsy9-AGk4IsI1dzeNlleBB3-g4nCJvgWsjTdMrp2Jq26b2_H5pzel3vh_DicyyHkGOgFoqCXcwUJFQjA90gbhGAhiDje37lbpOv9jDaDCL1IHJIWJomAOIE24W8vw2BY1ekyKIugr3JtC1tMgif7VdXO-KDMghtXa1uZ4NNW02BkK1VYdUQOMpV7093sDnm9ux31H8LB8_1j_3oQakRWhdqMjaK9lGcJTQWi4RmkBngvokkqxlxhFEWCZZDEgsWG4RgyxRBjrRu5J7BDrta-i3o8N6k2ReVULhfOzpVbylJZ-Vcp7FROyg8pgFIRQWNwtjFw5XttfCXn1muT56owZe1lxBjnIgHKGvT0Hzora1c0760opBwjjg11vqa0K713JtuGASpXlcjfShr4ZDf-Fv0pAL8BSNKE7A</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>2663073273</pqid></control><display><type>article</type><title>XPS Study on Calcining Mixtures of Brucite with Titania</title><source>Publicly Available Content Database</source><source>PubMed Central</source><source>Free Full-Text Journals in Chemistry</source><creator>Sánchez-Zambrano, Karla Sofía ; Hernández-Reséndiz, Marina ; Gómez-Rodríguez, Cristian ; García-Quiñonez, Linda Viviana ; Aguilar-Martínez, Josué Amilcar ; Rodríguez-Castellanos, Edén Amaral ; Verdeja, Luis Felipe ; Fernández-González, Daniel ; Castillo-Rodríguez, Guadalupe Alan</creator><creatorcontrib>Sánchez-Zambrano, Karla Sofía ; Hernández-Reséndiz, Marina ; Gómez-Rodríguez, Cristian ; García-Quiñonez, Linda Viviana ; Aguilar-Martínez, Josué Amilcar ; Rodríguez-Castellanos, Edén Amaral ; Verdeja, Luis Felipe ; Fernández-González, Daniel ; Castillo-Rodríguez, Guadalupe Alan</creatorcontrib><description>In this work, we studied the phases in a Mg-Ti-O system using a 1:1 formulation of MgO:TiO , mixing synthetic brucite of Mexican origin with TiO microparticles of high purity, with a heat treatment at 1100 °C for 1 h. Due to its valence electrons, TiO can contribute to the sintering process to improve density in MgO products. The raw materials and formulation by XPS and X-RD techniques were characterized. The results demonstrate the presence of different oxidation states in titania and the formation of different oxides in the Mg-Ti-O system when mixed and calcined at 1100 °C; additionally, we estimated the formation of vacancies in the crystal lattice during the transformation from hexagonal brucite to magnesia with a cubic structure centered on the faces. Its thermal behavior is indicated by the MgO-TiO phase diagram.</description><identifier>ISSN: 1996-1944</identifier><identifier>EISSN: 1996-1944</identifier><identifier>DOI: 10.3390/ma15093117</identifier><identifier>PMID: 35591451</identifier><language>eng</language><publisher>Switzerland: MDPI AG</publisher><subject>Aqueous solutions ; Brucite ; Chemical reactions ; Crystal lattices ; Cubic lattice ; Heat treatment ; High temperature ; Lattice vacancies ; Magnesium hydroxide ; Magnesium oxide ; Microparticles ; Nanoparticles ; Oxidation ; Phase diagrams ; Raw materials ; Roasting ; Thermodynamic properties ; Titanium ; Titanium dioxide</subject><ispartof>Materials, 2022-04, Vol.15 (9), p.3117</ispartof><rights>2022 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (https://creativecommons.org/licenses/by/4.0/). Notwithstanding the ProQuest Terms and Conditions, you may use this content in accordance with the terms of the License.</rights><rights>2022 by the authors. 2022</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c336t-cebea08d7f50d933e7f1de178205d9b7a322296f154964e63b1fa6334ccd9b893</citedby><cites>FETCH-LOGICAL-c336t-cebea08d7f50d933e7f1de178205d9b7a322296f154964e63b1fa6334ccd9b893</cites><orcidid>0000-0001-6957-4764 ; 0000-0002-8470-3584</orcidid></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.proquest.com/docview/2663073273/fulltextPDF?pq-origsite=primo$$EPDF$$P50$$Gproquest$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.proquest.com/docview/2663073273?pq-origsite=primo$$EHTML$$P50$$Gproquest$$Hfree_for_read</linktohtml><link.rule.ids>230,314,727,780,784,885,25753,27924,27925,37012,37013,44590,53791,53793,75126</link.rule.ids><backlink>$$Uhttps://www.ncbi.nlm.nih.gov/pubmed/35591451$$D View this record in MEDLINE/PubMed$$Hfree_for_read</backlink></links><search><creatorcontrib>Sánchez-Zambrano, Karla Sofía</creatorcontrib><creatorcontrib>Hernández-Reséndiz, Marina</creatorcontrib><creatorcontrib>Gómez-Rodríguez, Cristian</creatorcontrib><creatorcontrib>García-Quiñonez, Linda Viviana</creatorcontrib><creatorcontrib>Aguilar-Martínez, Josué Amilcar</creatorcontrib><creatorcontrib>Rodríguez-Castellanos, Edén Amaral</creatorcontrib><creatorcontrib>Verdeja, Luis Felipe</creatorcontrib><creatorcontrib>Fernández-González, Daniel</creatorcontrib><creatorcontrib>Castillo-Rodríguez, Guadalupe Alan</creatorcontrib><title>XPS Study on Calcining Mixtures of Brucite with Titania</title><title>Materials</title><addtitle>Materials (Basel)</addtitle><description>In this work, we studied the phases in a Mg-Ti-O system using a 1:1 formulation of MgO:TiO , mixing synthetic brucite of Mexican origin with TiO microparticles of high purity, with a heat treatment at 1100 °C for 1 h. Due to its valence electrons, TiO can contribute to the sintering process to improve density in MgO products. The raw materials and formulation by XPS and X-RD techniques were characterized. The results demonstrate the presence of different oxidation states in titania and the formation of different oxides in the Mg-Ti-O system when mixed and calcined at 1100 °C; additionally, we estimated the formation of vacancies in the crystal lattice during the transformation from hexagonal brucite to magnesia with a cubic structure centered on the faces. Its thermal behavior is indicated by the MgO-TiO phase diagram.</description><subject>Aqueous solutions</subject><subject>Brucite</subject><subject>Chemical reactions</subject><subject>Crystal lattices</subject><subject>Cubic lattice</subject><subject>Heat treatment</subject><subject>High temperature</subject><subject>Lattice vacancies</subject><subject>Magnesium hydroxide</subject><subject>Magnesium oxide</subject><subject>Microparticles</subject><subject>Nanoparticles</subject><subject>Oxidation</subject><subject>Phase diagrams</subject><subject>Raw materials</subject><subject>Roasting</subject><subject>Thermodynamic properties</subject><subject>Titanium</subject><subject>Titanium dioxide</subject><issn>1996-1944</issn><issn>1996-1944</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><sourceid>PIMPY</sourceid><recordid>eNpdkV9LwzAUxYMobsy9-AGk4IsI1dzeNlleBB3-g4nCJvgWsjTdMrp2Jq26b2_H5pzel3vh_DicyyHkGOgFoqCXcwUJFQjA90gbhGAhiDje37lbpOv9jDaDCL1IHJIWJomAOIE24W8vw2BY1ekyKIugr3JtC1tMgif7VdXO-KDMghtXa1uZ4NNW02BkK1VYdUQOMpV7093sDnm9ux31H8LB8_1j_3oQakRWhdqMjaK9lGcJTQWi4RmkBngvokkqxlxhFEWCZZDEgsWG4RgyxRBjrRu5J7BDrta-i3o8N6k2ReVULhfOzpVbylJZ-Vcp7FROyg8pgFIRQWNwtjFw5XttfCXn1muT56owZe1lxBjnIgHKGvT0Hzora1c0760opBwjjg11vqa0K713JtuGASpXlcjfShr4ZDf-Fv0pAL8BSNKE7A</recordid><startdate>20220426</startdate><enddate>20220426</enddate><creator>Sánchez-Zambrano, Karla Sofía</creator><creator>Hernández-Reséndiz, Marina</creator><creator>Gómez-Rodríguez, Cristian</creator><creator>García-Quiñonez, Linda Viviana</creator><creator>Aguilar-Martínez, Josué Amilcar</creator><creator>Rodríguez-Castellanos, Edén Amaral</creator><creator>Verdeja, Luis Felipe</creator><creator>Fernández-González, Daniel</creator><creator>Castillo-Rodríguez, Guadalupe Alan</creator><general>MDPI AG</general><general>MDPI</general><scope>NPM</scope><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PIMPY</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7X8</scope><scope>5PM</scope><orcidid>https://orcid.org/0000-0001-6957-4764</orcidid><orcidid>https://orcid.org/0000-0002-8470-3584</orcidid></search><sort><creationdate>20220426</creationdate><title>XPS Study on Calcining Mixtures of Brucite with Titania</title><author>Sánchez-Zambrano, Karla Sofía ; Hernández-Reséndiz, Marina ; Gómez-Rodríguez, Cristian ; García-Quiñonez, Linda Viviana ; Aguilar-Martínez, Josué Amilcar ; Rodríguez-Castellanos, Edén Amaral ; Verdeja, Luis Felipe ; Fernández-González, Daniel ; Castillo-Rodríguez, Guadalupe Alan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c336t-cebea08d7f50d933e7f1de178205d9b7a322296f154964e63b1fa6334ccd9b893</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Aqueous solutions</topic><topic>Brucite</topic><topic>Chemical reactions</topic><topic>Crystal lattices</topic><topic>Cubic lattice</topic><topic>Heat treatment</topic><topic>High temperature</topic><topic>Lattice vacancies</topic><topic>Magnesium hydroxide</topic><topic>Magnesium oxide</topic><topic>Microparticles</topic><topic>Nanoparticles</topic><topic>Oxidation</topic><topic>Phase diagrams</topic><topic>Raw materials</topic><topic>Roasting</topic><topic>Thermodynamic properties</topic><topic>Titanium</topic><topic>Titanium dioxide</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Sánchez-Zambrano, Karla Sofía</creatorcontrib><creatorcontrib>Hernández-Reséndiz, Marina</creatorcontrib><creatorcontrib>Gómez-Rodríguez, Cristian</creatorcontrib><creatorcontrib>García-Quiñonez, Linda Viviana</creatorcontrib><creatorcontrib>Aguilar-Martínez, Josué Amilcar</creatorcontrib><creatorcontrib>Rodríguez-Castellanos, Edén Amaral</creatorcontrib><creatorcontrib>Verdeja, Luis Felipe</creatorcontrib><creatorcontrib>Fernández-González, Daniel</creatorcontrib><creatorcontrib>Castillo-Rodríguez, Guadalupe Alan</creatorcontrib><collection>PubMed</collection><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>Materials Science &amp; Engineering Collection</collection><collection>ProQuest Central (Alumni)</collection><collection>ProQuest Central</collection><collection>ProQuest Central Essentials</collection><collection>AUTh Library subscriptions: ProQuest Central</collection><collection>Technology Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Materials Science Collection</collection><collection>Publicly Available Content Database</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>ProQuest Central China</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>Materials</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Sánchez-Zambrano, Karla Sofía</au><au>Hernández-Reséndiz, Marina</au><au>Gómez-Rodríguez, Cristian</au><au>García-Quiñonez, Linda Viviana</au><au>Aguilar-Martínez, Josué Amilcar</au><au>Rodríguez-Castellanos, Edén Amaral</au><au>Verdeja, Luis Felipe</au><au>Fernández-González, Daniel</au><au>Castillo-Rodríguez, Guadalupe Alan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>XPS Study on Calcining Mixtures of Brucite with Titania</atitle><jtitle>Materials</jtitle><addtitle>Materials (Basel)</addtitle><date>2022-04-26</date><risdate>2022</risdate><volume>15</volume><issue>9</issue><spage>3117</spage><pages>3117-</pages><issn>1996-1944</issn><eissn>1996-1944</eissn><abstract>In this work, we studied the phases in a Mg-Ti-O system using a 1:1 formulation of MgO:TiO , mixing synthetic brucite of Mexican origin with TiO microparticles of high purity, with a heat treatment at 1100 °C for 1 h. Due to its valence electrons, TiO can contribute to the sintering process to improve density in MgO products. The raw materials and formulation by XPS and X-RD techniques were characterized. The results demonstrate the presence of different oxidation states in titania and the formation of different oxides in the Mg-Ti-O system when mixed and calcined at 1100 °C; additionally, we estimated the formation of vacancies in the crystal lattice during the transformation from hexagonal brucite to magnesia with a cubic structure centered on the faces. Its thermal behavior is indicated by the MgO-TiO phase diagram.</abstract><cop>Switzerland</cop><pub>MDPI AG</pub><pmid>35591451</pmid><doi>10.3390/ma15093117</doi><orcidid>https://orcid.org/0000-0001-6957-4764</orcidid><orcidid>https://orcid.org/0000-0002-8470-3584</orcidid><oa>free_for_read</oa></addata></record>
fulltext fulltext
identifier ISSN: 1996-1944
ispartof Materials, 2022-04, Vol.15 (9), p.3117
issn 1996-1944
1996-1944
language eng
recordid cdi_pubmedcentral_primary_oai_pubmedcentral_nih_gov_9100921
source Publicly Available Content Database; PubMed Central; Free Full-Text Journals in Chemistry
subjects Aqueous solutions
Brucite
Chemical reactions
Crystal lattices
Cubic lattice
Heat treatment
High temperature
Lattice vacancies
Magnesium hydroxide
Magnesium oxide
Microparticles
Nanoparticles
Oxidation
Phase diagrams
Raw materials
Roasting
Thermodynamic properties
Titanium
Titanium dioxide
title XPS Study on Calcining Mixtures of Brucite with Titania
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T13%3A30%3A10IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_pubme&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=XPS%20Study%20on%20Calcining%20Mixtures%20of%20Brucite%20with%20Titania&rft.jtitle=Materials&rft.au=S%C3%A1nchez-Zambrano,%20Karla%20Sof%C3%ADa&rft.date=2022-04-26&rft.volume=15&rft.issue=9&rft.spage=3117&rft.pages=3117-&rft.issn=1996-1944&rft.eissn=1996-1944&rft_id=info:doi/10.3390/ma15093117&rft_dat=%3Cproquest_pubme%3E2667795106%3C/proquest_pubme%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-c336t-cebea08d7f50d933e7f1de178205d9b7a322296f154964e63b1fa6334ccd9b893%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=2663073273&rft_id=info:pmid/35591451&rfr_iscdi=true