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MWCNT modified Ni–Fe LDH/BiVO4 heterojunction: boosted visible-light-driven photoelectrochemical aptasensor for ofloxacin detection
Sensitivity and selectivity, which can be identified by the photosensitivity of materials and the identification of elements, are two important factors for a photoelectrochemical aptasensor (PEC aptasensor). Herein, a patent PEC aptasensor for specifically detecting ofloxacin (OFL) was exploited, an...
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Published in: | RSC advances 2022-08, Vol.12 (37), p.24269-24277 |
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creator | Qi, Xuejun Tao, Shuyan |
description | Sensitivity and selectivity, which can be identified by the photosensitivity of materials and the identification of elements, are two important factors for a photoelectrochemical aptasensor (PEC aptasensor). Herein, a patent PEC aptasensor for specifically detecting ofloxacin (OFL) was exploited, and a visible-light-active MWCNT/LDH/BiVO4 heterostructure was introduced as a photoactive material and identification elements, respectively. The combination of LDH with BiVO4 enhanced the photocurrent response, and MWCNT provided higher electron conductivity, which are advantageous for structuring PEC sensors. Furthermore, the two-pot synthesis of MWCNT/LDH/BiVO4 has the advantage of possessing an environmentally friendly character. Under optimal conditions, the photocurrent response of MWCNT/LDH/BiVO4 presents a linear trend with OFL concentration from 0.1 to 16 000 nM, and the limit of detection (S/N = 3) is as low as 0.03 nM. This new PEC sensing device afforded an ultra-sensitive sensor which has high selectivity and stability for detecting OFL. |
doi_str_mv | 10.1039/d2ra03981h |
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Herein, a patent PEC aptasensor for specifically detecting ofloxacin (OFL) was exploited, and a visible-light-active MWCNT/LDH/BiVO4 heterostructure was introduced as a photoactive material and identification elements, respectively. The combination of LDH with BiVO4 enhanced the photocurrent response, and MWCNT provided higher electron conductivity, which are advantageous for structuring PEC sensors. Furthermore, the two-pot synthesis of MWCNT/LDH/BiVO4 has the advantage of possessing an environmentally friendly character. Under optimal conditions, the photocurrent response of MWCNT/LDH/BiVO4 presents a linear trend with OFL concentration from 0.1 to 16 000 nM, and the limit of detection (S/N = 3) is as low as 0.03 nM. This new PEC sensing device afforded an ultra-sensitive sensor which has high selectivity and stability for detecting OFL.</description><identifier>EISSN: 2046-2069</identifier><identifier>DOI: 10.1039/d2ra03981h</identifier><language>eng</language><publisher>Cambridge: Royal Society of Chemistry</publisher><subject>Bismuth oxides ; Chemistry ; Electron conductivity ; Heterojunctions ; Heterostructures ; Photoelectric effect ; Photoelectric emission ; Photosensitivity ; Selectivity ; Vanadates</subject><ispartof>RSC advances, 2022-08, Vol.12 (37), p.24269-24277</ispartof><rights>Copyright Royal Society of Chemistry 2022</rights><rights>This journal is © The Royal Society of Chemistry 2022 The Royal Society of Chemistry</rights><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9412155/pdf/$$EPDF$$P50$$Gpubmedcentral$$Hfree_for_read</linktopdf><linktohtml>$$Uhttps://www.ncbi.nlm.nih.gov/pmc/articles/PMC9412155/$$EHTML$$P50$$Gpubmedcentral$$Hfree_for_read</linktohtml><link.rule.ids>230,314,724,777,781,882,27905,27906,53772,53774</link.rule.ids></links><search><creatorcontrib>Qi, Xuejun</creatorcontrib><creatorcontrib>Tao, Shuyan</creatorcontrib><title>MWCNT modified Ni–Fe LDH/BiVO4 heterojunction: boosted visible-light-driven photoelectrochemical aptasensor for ofloxacin detection</title><title>RSC advances</title><description>Sensitivity and selectivity, which can be identified by the photosensitivity of materials and the identification of elements, are two important factors for a photoelectrochemical aptasensor (PEC aptasensor). 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This new PEC sensing device afforded an ultra-sensitive sensor which has high selectivity and stability for detecting OFL.</description><subject>Bismuth oxides</subject><subject>Chemistry</subject><subject>Electron conductivity</subject><subject>Heterojunctions</subject><subject>Heterostructures</subject><subject>Photoelectric effect</subject><subject>Photoelectric emission</subject><subject>Photosensitivity</subject><subject>Selectivity</subject><subject>Vanadates</subject><issn>2046-2069</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2022</creationdate><recordtype>article</recordtype><recordid>eNpdj81q3DAUhUUgkDDJJk8gyKYbN_oZa-wuAu00fzBNNmm7NLJ0FWuQJVeSh3SXTZ-gb9gnqZJmk164HC7n8HEPQieUvKeEt2eaRVm0ocMeOmRkKSpGRHuAjlPakjKipkzQQ_Try_f17T0eg7bGgsa39s_T70vAm8_XZ5_st7slHiBDDNvZq2yD_4D7EFIuyZ1NtndQOfsw5EpHuwOPpyHkAA5UjkENMFolHZZTlgl8ChGbssG48CiV9VgX9Av1CO0b6RIcv-oCfb28uF9fV5u7q5v1x001Mb7KFVsyzZtW1YaA5kL05TCyZtJozVlPKeXNqm_MquG8JyCNkk3pSWjNi8EJX6Dzf9xp7kfQCnyO0nVTtKOMP7sgbffW8XboHsKua5eU0bougHevgBh-zJByN9qkwDnpIcypYysqasab8skCnf4X3YY5-lLvOUWpaIXg_C_s-Ihs</recordid><startdate>20220822</startdate><enddate>20220822</enddate><creator>Qi, Xuejun</creator><creator>Tao, Shuyan</creator><general>Royal Society of Chemistry</general><general>The Royal Society of Chemistry</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope><scope>5PM</scope></search><sort><creationdate>20220822</creationdate><title>MWCNT modified Ni–Fe LDH/BiVO4 heterojunction: boosted visible-light-driven photoelectrochemical aptasensor for ofloxacin detection</title><author>Qi, Xuejun ; Tao, Shuyan</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p237t-242d389c5f0ed366b389fa52afdd32b111387b8f7833b0eafca85120153387303</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2022</creationdate><topic>Bismuth oxides</topic><topic>Chemistry</topic><topic>Electron conductivity</topic><topic>Heterojunctions</topic><topic>Heterostructures</topic><topic>Photoelectric effect</topic><topic>Photoelectric emission</topic><topic>Photosensitivity</topic><topic>Selectivity</topic><topic>Vanadates</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Qi, Xuejun</creatorcontrib><creatorcontrib>Tao, Shuyan</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><collection>PubMed Central (Full Participant titles)</collection><jtitle>RSC advances</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Qi, Xuejun</au><au>Tao, Shuyan</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>MWCNT modified Ni–Fe LDH/BiVO4 heterojunction: boosted visible-light-driven photoelectrochemical aptasensor for ofloxacin detection</atitle><jtitle>RSC advances</jtitle><date>2022-08-22</date><risdate>2022</risdate><volume>12</volume><issue>37</issue><spage>24269</spage><epage>24277</epage><pages>24269-24277</pages><eissn>2046-2069</eissn><abstract>Sensitivity and selectivity, which can be identified by the photosensitivity of materials and the identification of elements, are two important factors for a photoelectrochemical aptasensor (PEC aptasensor). Herein, a patent PEC aptasensor for specifically detecting ofloxacin (OFL) was exploited, and a visible-light-active MWCNT/LDH/BiVO4 heterostructure was introduced as a photoactive material and identification elements, respectively. The combination of LDH with BiVO4 enhanced the photocurrent response, and MWCNT provided higher electron conductivity, which are advantageous for structuring PEC sensors. Furthermore, the two-pot synthesis of MWCNT/LDH/BiVO4 has the advantage of possessing an environmentally friendly character. Under optimal conditions, the photocurrent response of MWCNT/LDH/BiVO4 presents a linear trend with OFL concentration from 0.1 to 16 000 nM, and the limit of detection (S/N = 3) is as low as 0.03 nM. 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subjects | Bismuth oxides Chemistry Electron conductivity Heterojunctions Heterostructures Photoelectric effect Photoelectric emission Photosensitivity Selectivity Vanadates |
title | MWCNT modified Ni–Fe LDH/BiVO4 heterojunction: boosted visible-light-driven photoelectrochemical aptasensor for ofloxacin detection |
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