Waterborne Eco-Sustainable Sol–Gel Coatings Based on Phytic Acid Intercalated Graphene Oxide for Corrosion Protection of Metallic Surfaces

In the past few years, corrosion protection of metal materials has become a global challenge, due to its great economic importance. For this reason, various methods have been developed to inhibit the corrosion process, such as surface treatment approaches, by employing corrosion inhibitors through t...

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Bibliographic Details
Published in:International journal of molecular sciences 2022-10, Vol.23 (19), p.12021
Main Authors: Sfameni, Silvia, Del Tedesco, Anna, Rando, Giulia, Truant, Fulvio, Visco, Annamaria, Plutino, Maria Rosaria
Format: Article
Language:English
Subjects:
Acids
Alkoxysilanes
Aluminum
Aminopropyltriethoxysilane
Cathodic protection
Chromate
Chromate coatings
Coatings
Corrosion
Corrosion prevention
Crosslinking
Economic importance
Graphene
Infrared spectroscopy
Mechanical properties
Nanocomposites
Nanomaterials
Phytic acid
Polymers
Protective coatings
Salt spray tests
Silanes
Sol-gel processes
Surface treatment
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Summary:In the past few years, corrosion protection of metal materials has become a global challenge, due to its great economic importance. For this reason, various methods have been developed to inhibit the corrosion process, such as surface treatment approaches, by employing corrosion inhibitors through the deposition of opportunely designed functional coatings, employed to preserve from corrosion damages metallic substrates. Recently, among these techniques and in order to avoid the toxic chromate-based pre-treatment coatings, silane-based coatings and films loaded with organic and inorganic corrosion inhibitors have been widely used in corrosion mitigation water-based surface treatment. In this study, the synthetic approach was devoted to create an embedded, hosted, waterborne, and eco-friendly matrix, obtained by use of the sol–gel technique, through the reaction of functional alkoxysilane cross-linking precursors, namely (3-glycidyloxypropyl)trimethoxysilane (GPTMS) and (3-aminopropyl)triethoxysilane (APTES), in the presence of graphene oxide (GO) intercalated with natural and non-toxic phytic acid (PA) molecules. As a matter of fact, all experimental results from FT-IR spectroscopy, UV–Vis analysis, and SEM confirmed that PA molecules were successfully decorated on GO. Furthermore, polarization measurements and a neutral salt spray test were used to evaluate the anticorrosive performance on aluminum and steel substrates, thus showing that the GO-PA nanofiller improved the barrier and corrosion protection properties of the developed functional silane-based coatings.
ISSN:1422-0067
1661-6596
1422-0067
DOI:10.3390/ijms231912021